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Competition of Aromatic Bromination and Nitration in Concentrated Sulfuric Acid

Competition of Aromatic Bromination and Nitration in Concentrated Sulfuric Acid
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摘要 Composition of bromine and nitric acid in concentrated sulfuric acid is effective for bromination of strongly deactivated aromatic compounds and for nitration and bromination of moderately deactivated compounds in one stage. The question why brominating agent is more reactive than nitrating agent in relation to strongly deactivated aromatic compounds and is less reactive in relation to moderate deactivated ones is discussed. Composition of bromine and nitric acid in concentrated sulfuric acid is effective for bromination of strongly deactivated aromatic compounds and for nitration and bromination of moderately deactivated compounds in one stage. The question why brominating agent is more reactive than nitrating agent in relation to strongly deactivated aromatic compounds and is less reactive in relation to moderate deactivated ones is discussed.
出处 《Open Journal of Synthesis Theory and Applications》 2013年第1期46-50,共5页 合成理论与应用(英文)
关键词 BROMINATION NITRATION AROMATIC Compounds 5-Bromo-1 3-dinitrobenzene 5-Bromo-2 4 7-trinitrofluorenone 4-Bromo-2 7-dinitrophenanthrenquinone Bromination Nitration Aromatic Compounds 5-Bromo-1 3-dinitrobenzene 5-Bromo-2 4 7-trinitrofluorenone 4-Bromo-2 7-dinitrophenanthrenquinone
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