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Improvement in Structural and Magnetic Properties of Electrospun Ni<sub>1-x</sub>Cu<sub>x</sub>Fe<sub>2</sub>O<sub>4</sub>Nanofibers

Improvement in Structural and Magnetic Properties of Electrospun Ni<sub>1-x</sub>Cu<sub>x</sub>Fe<sub>2</sub>O<sub>4</sub>Nanofibers
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摘要 A series of Ni1-xCuxFe2O4 (0.0 ≤ x ≤ 1.0) nanofibers have been synthesized employing electrospinning method at 650°C. The effect of Cu substitution on structural, morphology and magnetic properties of NiFe2O4 nanofibers is reported. The XRD analysis showed the formation of single-phase cubic spinel Ni-Cu ferrite and an increasing behavior of lattice constant. The surface morphology is characterized by SEM, it is investigated that nanofibers have uniform and continuous morphology. The VSM results showed Cu substitution played an important role in magnetic properties of Ni1-xCuxFe2O4. The saturation magnetization (Ms) decreases linearly with increasing Cu2+ content, while coercivity (Hc) has slowly decreased before x ≤ 0.5, and then sharply increased to 723.9 Oe for x = 1.0. The magnetic properties of Ni1-xCuxFe2O4 can be explained in Neel’s model, cation distribution and shape anisotropy. A series of Ni1-xCuxFe2O4 (0.0 ≤ x ≤ 1.0) nanofibers have been synthesized employing electrospinning method at 650°C. The effect of Cu substitution on structural, morphology and magnetic properties of NiFe2O4 nanofibers is reported. The XRD analysis showed the formation of single-phase cubic spinel Ni-Cu ferrite and an increasing behavior of lattice constant. The surface morphology is characterized by SEM, it is investigated that nanofibers have uniform and continuous morphology. The VSM results showed Cu substitution played an important role in magnetic properties of Ni1-xCuxFe2O4. The saturation magnetization (Ms) decreases linearly with increasing Cu2+ content, while coercivity (Hc) has slowly decreased before x ≤ 0.5, and then sharply increased to 723.9 Oe for x = 1.0. The magnetic properties of Ni1-xCuxFe2O4 can be explained in Neel’s model, cation distribution and shape anisotropy.
出处 《Soft Nanoscience Letters》 2017年第2期17-26,共10页 软纳米科学报(英文)
关键词 NiCu Ferrite Electrospinning MAGNETIC Properties Nanostructures NiCu Ferrite Electrospinning Magnetic Properties Nanostructures
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