The structures,mechanical properties and electronic structures of M metals(M=Ti,V,Cr,Mn and Fe)dopedβ-Si_(3)N_(4) were investigated by First-principles calculations within CASTEP.The calculated lattice parameters of...The structures,mechanical properties and electronic structures of M metals(M=Ti,V,Cr,Mn and Fe)dopedβ-Si_(3)N_(4) were investigated by First-principles calculations within CASTEP.The calculated lattice parameters ofβ-Si_(3)N_(4) were consistent with previous date.The cohesive energy and formation enthalpy show that initialβ-Si_(3)N_(4) has the highest structural stability.The calculated elastic constant and the Voigt-Reuss-Hill approximation indicate that elastic moduli ofβ-Si_(3)N_(4) are slightly reduced by M doping.Based on Poisson’s and Pugh’s ratio,β-Si_(3)N_(4) is a ductile material and the toughness ofβ-Si_(3)N_(4) increases with M doping,and Fe doping exhibited the best toughness.The results of density of states,charge distributions and overlapping populations indicate thatβ-Si_(3)N_(4) has the strong covalent and ionic bond strength between N and Si.展开更多
盾构施工过程中土体大部分区域处于小应变状态,与常用的本构模型的土体性质有所不同。因此,为研究济南济泺路穿黄隧道区域内典型粉质黏土的的静动力行为特性及工程适用性,通过室内基础土工试验、侧限固结试验、标准三轴固结试验以及动...盾构施工过程中土体大部分区域处于小应变状态,与常用的本构模型的土体性质有所不同。因此,为研究济南济泺路穿黄隧道区域内典型粉质黏土的的静动力行为特性及工程适用性,通过室内基础土工试验、侧限固结试验、标准三轴固结试验以及动三轴试验,确定了粉质黏土基本物理性质参数以及切线刚度E_(oed)^(ref)、割线模量E_(50)^(ref)、卸载/重加载参考刚度E_(ur)^(ref),并将所得参数应用于济南济泺路穿黄隧道工程下穿北岸大堤沉降分析中,同时通过对比应用硬化土小应变硬化(hardening soil model with small strain stiffness,HSS)本构模型、摩尔库伦(M-C)本构模型的模拟结果与现场实测结果,验证了HSS本构模型在该地区变形分析中的准确性。结果表明:围压一定时,该地区粉质黏土试样竖向应变以塑性应变为主,且随动应力的增加,土体达到稳定所需时间越长;循环荷载一定时,增大土体围压可提高土体的稳定性;基于室内试验获取的HSS本构模型参数模拟的济南济泺路穿黄隧道下穿大堤工程地层变形结果与现场实测值吻合良好,验证了基于所提出的室内试验获取岩土小应变相关参数方法的适用性。研究成果可以丰富济南黄河地区粉质黏土地层参数研究,并为该地区岩土工程数值模拟分析的本构模型与地层参数选取提供参考。展开更多
提出一种从整体到局部优化的风格迁移(global-local based style transfer,G-LST)模型.首先,利用广泛的源端数据进行迭代优化来自动构建高质量的伪平行数据,并通过联合训练来提升模型对整体风格的语义感知;随后,利用常识性知识修正词级...提出一种从整体到局部优化的风格迁移(global-local based style transfer,G-LST)模型.首先,利用广泛的源端数据进行迭代优化来自动构建高质量的伪平行数据,并通过联合训练来提升模型对整体风格的语义感知;随后,利用常识性知识修正词级的细粒度风格来增强局部风格的表现,同时兼顾整体与局部风格,提高风格转换的准确度.基于GYAFC数据集的实验结果表明,相较于目前表现最佳的文本风格迁移模型,G-LST模型在E&M与F&R两个领域数据上的风格转换准确率分别提高了2.70%和4.47%,内容保留与风格准确率的综合指标分别提升了1.18%和1.95%.展开更多
In order to better understand the specific substituent effects on the electrochemical oxidation process of β-O-4 bond, a series of methoxyphenyl type β-O-4 dimer model compounds with different localized methoxyl gro...In order to better understand the specific substituent effects on the electrochemical oxidation process of β-O-4 bond, a series of methoxyphenyl type β-O-4 dimer model compounds with different localized methoxyl groups, including 2-(2-methoxyphenoxy)-1-phenylethanone, 2-(2-methoxyphenoxy)-1-phenylethanol, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanol, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanol have been selected and their electrochemical properties have been studied experimentally by cyclic voltammetry, and FT-IR spectroelectrochemistry. Combining with electrolysis products distribution analysis and density functional theory calculations, oxidation mechanisms of all six model dimers have been explored. In particular, a total effect from substituents of both para-methoxy(on the aryl ring closing to Cα) and Cα-OH on the oxidation mechanisms has been clearly observed, showing a significant selectivity on the Cα-Cβbond cleavage induced by electrochemical oxidations.展开更多
文摘The structures,mechanical properties and electronic structures of M metals(M=Ti,V,Cr,Mn and Fe)dopedβ-Si_(3)N_(4) were investigated by First-principles calculations within CASTEP.The calculated lattice parameters ofβ-Si_(3)N_(4) were consistent with previous date.The cohesive energy and formation enthalpy show that initialβ-Si_(3)N_(4) has the highest structural stability.The calculated elastic constant and the Voigt-Reuss-Hill approximation indicate that elastic moduli ofβ-Si_(3)N_(4) are slightly reduced by M doping.Based on Poisson’s and Pugh’s ratio,β-Si_(3)N_(4) is a ductile material and the toughness ofβ-Si_(3)N_(4) increases with M doping,and Fe doping exhibited the best toughness.The results of density of states,charge distributions and overlapping populations indicate thatβ-Si_(3)N_(4) has the strong covalent and ionic bond strength between N and Si.
文摘盾构施工过程中土体大部分区域处于小应变状态,与常用的本构模型的土体性质有所不同。因此,为研究济南济泺路穿黄隧道区域内典型粉质黏土的的静动力行为特性及工程适用性,通过室内基础土工试验、侧限固结试验、标准三轴固结试验以及动三轴试验,确定了粉质黏土基本物理性质参数以及切线刚度E_(oed)^(ref)、割线模量E_(50)^(ref)、卸载/重加载参考刚度E_(ur)^(ref),并将所得参数应用于济南济泺路穿黄隧道工程下穿北岸大堤沉降分析中,同时通过对比应用硬化土小应变硬化(hardening soil model with small strain stiffness,HSS)本构模型、摩尔库伦(M-C)本构模型的模拟结果与现场实测结果,验证了HSS本构模型在该地区变形分析中的准确性。结果表明:围压一定时,该地区粉质黏土试样竖向应变以塑性应变为主,且随动应力的增加,土体达到稳定所需时间越长;循环荷载一定时,增大土体围压可提高土体的稳定性;基于室内试验获取的HSS本构模型参数模拟的济南济泺路穿黄隧道下穿大堤工程地层变形结果与现场实测值吻合良好,验证了基于所提出的室内试验获取岩土小应变相关参数方法的适用性。研究成果可以丰富济南黄河地区粉质黏土地层参数研究,并为该地区岩土工程数值模拟分析的本构模型与地层参数选取提供参考。
文摘提出一种从整体到局部优化的风格迁移(global-local based style transfer,G-LST)模型.首先,利用广泛的源端数据进行迭代优化来自动构建高质量的伪平行数据,并通过联合训练来提升模型对整体风格的语义感知;随后,利用常识性知识修正词级的细粒度风格来增强局部风格的表现,同时兼顾整体与局部风格,提高风格转换的准确度.基于GYAFC数据集的实验结果表明,相较于目前表现最佳的文本风格迁移模型,G-LST模型在E&M与F&R两个领域数据上的风格转换准确率分别提高了2.70%和4.47%,内容保留与风格准确率的综合指标分别提升了1.18%和1.95%.
基金The authors gratefully acknowledge the financial support of the Natural Science Foundation of China,China(Grant No.21975082 and 21736003)the Guangdong Basic and Applied Basic Research Foundation(Grant Number:2019A1515011472 and 2022A1515011341)the Science and Technology Program of Guangzhou(Grant Number:202102080479).
文摘In order to better understand the specific substituent effects on the electrochemical oxidation process of β-O-4 bond, a series of methoxyphenyl type β-O-4 dimer model compounds with different localized methoxyl groups, including 2-(2-methoxyphenoxy)-1-phenylethanone, 2-(2-methoxyphenoxy)-1-phenylethanol, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanol, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanol have been selected and their electrochemical properties have been studied experimentally by cyclic voltammetry, and FT-IR spectroelectrochemistry. Combining with electrolysis products distribution analysis and density functional theory calculations, oxidation mechanisms of all six model dimers have been explored. In particular, a total effect from substituents of both para-methoxy(on the aryl ring closing to Cα) and Cα-OH on the oxidation mechanisms has been clearly observed, showing a significant selectivity on the Cα-Cβbond cleavage induced by electrochemical oxidations.
