Photoluminescence Enhancement of Aluminum Ion Intercalated MoS_(2)Quantum Dots

Low photolumines-cence(PL)quantum yield of molybdenum disulfide(MoS_(2))quan-tum dots(QDs)has lim-ited practical applica-tion as potential fluores-cent materials.Here,we report the intercalation of aluminum ion(Al^(3+))to enhance the PL of MoS_(2)QDs and the un-derlying mechanism.With detailed characterization and exciton dynamics study,we suggest that additional surface states including new emission centers have been effectively introduced to MoS_(2)QDs by the Al^(3+)intercalation.The synergy of new radiative pathway for exciton re-combination and the passivation of non-radiative surface traps is responsible for the en-hanced fluorescence of MoS_(2)QDs.Our findings demonstrate an efficient strategy to improve the optical properties of MoS_(2)QDs and are important for understanding the regulation effect of surface states on the emission of two dimensional sulfide QDs.

A Mathematical Model of Multi-Hop HF Radio Propagation

It is an eternal topic to study the minimum loss under the maximum transmission distance and the practicality of radio propagation in the navigation of ships. The transmission loss by dividing it to Median medium attenuation and Media attenuation correction factor is discussed. The Longley-Rice Model is introduced and improved;the correlation proportion of our model is work out. Then the reflection correction factor is calculated in the case of silent and turbulent ocean, which comes to the total loss and strength of the first reflection. The signal to noise ratio is explained and the relationship between various angle of incidence and correction factor are explored. According to fixed signal to noise ratio 14, the highest bounce frequency is got.

Highly efficient multiplex base editing:One-shot deactivation of eight genes in Shewanella oneidensis MR-1

Obtaining electroactive microbes capable of efficient extracellular electron transfer is a large undertaking for the scalability of bio-electrochemical systems.Inevitably,researchers need to pursue the co-modification of multiple genes rather than expecting that modification of a single gene would make a significant contribution to improving extracellular electron transfer rates.Base editing has enabled highly-efficient gene deactivation in model electroactive microbe Shewanella oneidensis MR-1.Since multiplexed application of base editing is still limited by its low throughput procedure,we thus here develop a rapid and efficient multiplex base editing system in S.oneidensis.Four approaches to express multiple gRNAs were assessed firstly,and transcription of each gRNA cassette into a monocistronic unit was validated as a more favorable option than transcription of multiple gRNAs into a polycistronic cluster.Then,a smart scheme was designed to deliver one-pot assembly of multiple gRNAs.3,5,and 8 genes were deactivated using this system with editing efficiency of 83.3%,100%and 12.5%,respectively.To offer some nonrepetitive components as alternatives genetic parts of sgRNA cassette,different promoters,handles,and terminators were screened.This multiplex base editing tool was finally adopted to simultaneously deactivate eight genes that were identified as significantly downregulated targets in transcriptome analysis of riboflavin-overproducing strain and control strain.The maximum power density of the multiplex engineered strain HRF(8BE)in microbial fuel cells was 1108.1 mW/m2,which was 21.67 times higher than that of the wild-type strain.This highly efficient multiplexed base editing tool elevates our ability of genome manipulation and combinatorial engineering in Shewanella,and may provide valuable insights in fundamental and applied research of extracellular electron transfer.

Electrochemical synthesis of selenocyanated imidazo[1,5-a]quinolines under metal catalyst-and chemical oxidant-free conditions

Reported herein is the first example of electrochemical selenocyanation of imidazo[1,5-a]quinolines with KSeCN under metal catalyst-and chemical oxidant-free conditions.This sustainable strategy shows a broad scope and great compatibility with functional groups,and affords synthetically and biologically important selenocyanated imidazo[1,5-a]quinolines in good to excellent yields with cheap graphite and Ni plates as the electrodes.The gram-scale synthesis was also successfully conducted,which might demonstrate the potential value of this electrochemical protocol.

DNA barcoding for the identification of Limonia crane flies(Diptera:Limoniidae)from China,including a new species and a newly recorded species

The genus Limonia Meigen,1803 is globally distributed with 216 known species/subspecies,of which 30 are recorded from China.In this study,we firstly use DNA barcodes(mt COI)to identify specimens of Limonia from China,result in a discovery of three species.Considering the morphological data,these species were identified as L.albiterminalis Lü,Ren&Zhang,sp.nov.,L.juvenca Alexander,1935(new record in China),and L.macrostigma(Schummel,1829),respectively.Six COI sequences of the three species were provided,analyzed with other 24 COI sequences from Limonia species.The result indicates that intraspecific distances in the genus are generally less than 2.2%,interspecific distances range from 7.9%to 17.2%,and there is no overlap between intra-and interspecific distances.Redescription and illustrations of L.juvenca and illustration of male hypopygium of L.macrostigma,as well as the key to the Chinese Limonia crane flies,are all provided.