Modifying agents 2,2-Bis(4-glycidyloxyphenyl)propane(2BPE)and dibutyl phthalate(DBP)were selected to enhance the compatibility.By using molecular simulation software(Materials Studio,MS),nine systems were constructed,...Modifying agents 2,2-Bis(4-glycidyloxyphenyl)propane(2BPE)and dibutyl phthalate(DBP)were selected to enhance the compatibility.By using molecular simulation software(Materials Studio,MS),nine systems were constructed,including molecular models of aged asphalt and WVO monomers with 2BPE and/or DBP.The solubility parameters,Flory-Huggins parameters,and interaction energies of these systems were calculated to determine the impact of 2BPE and DBP on the compatibility of WVO and aged asphalt.Results showed that the addition of 2BPE and DBP reduced the difference in the solubility parameters between WVO and aged asphalt,thus improving the compatibility between WVO and aged asphalt.Additionally,using a combination of 2BPE and DBP in both aged asphalt and rejuvenator was found to be more effective than using either 2BPE or DBP alone.Finally,it was determined that evaluating the compatibility of WVO and aged asphalt using Van der Waals potential and non-bonding energy as evaluation indicators was more accurate than using electrostatic potential energy.展开更多
In order to study the anti-fatigue performance of RCA modified asphalt (RMA),the performance of RMA and 90#matrix asphalt with different modifier content were measured by asphalt penetration,ductility,softening point,...In order to study the anti-fatigue performance of RCA modified asphalt (RMA),the performance of RMA and 90#matrix asphalt with different modifier content were measured by asphalt penetration,ductility,softening point,Brookfield viscosity,rheological index,infrared spectrum and dielectric constant test.This paper discusses the changes of asphalt basic indexes,fatigue properties and asphalt components based on dielectric properties under different modifier contents,and analyzes the grey correlation degree between components and asphalt pavement performance indexes.The results show that the optimum content of RCA modifier is 16.7%of the asphalt quality according to the penetration,ductility,softening point,Brockfield viscosity,viscosity temperature curve and fatigue life.In the phase angle-strain curve,there is disorder in the latter part of the curve.According to the strain (ε_(d)) corresponding to the disorder point,a new fatigue failure criterion is proposed and proved.Based on the new asphalt fatigue failure criterion,the fatigue prediction model of asphalt mixture is improved,and the fatigue life predicted by the improved fatigue model is compared with the fatigue life obtained by four-point bending fatigue test.The results show that the proposed new asphalt fatigue failure criterion is reasonable,and the fatigue life predicted by the improved asphalt mixture fatigue prediction model is accurate.The research method of classifying asphalt components based on dielectric properties is simple and effective,and the components have a high correlation with the road performance of base asphalt and modified asphalt.展开更多
In this study,the regenerative effects of different regenerants on aged SBS-modified asphalt from different perspectives were investigated,including their conventional properties,viscoelastic behavior,creep-related pr...In this study,the regenerative effects of different regenerants on aged SBS-modified asphalt from different perspectives were investigated,including their conventional properties,viscoelastic behavior,creep-related properties,and micromorphology.Base oils composed of different proportions of aromatic and saturated hydrocarbons as well as the styrene-butadiene-styrene(SBS)restorer were used to prepare the regenerants.The results showed that the components of the base oil of the regenerant played a crucial role in determining the characteristics and performance of the recycled SBSmodified asphalt.Regenerants containing a high proportion of aromatics dissolved the hard segment in the SBS restorer,thereby delaying the effect of a reduction in the regenerants on the performance of the aged asphalts at a high temperature.Regenerants containing a high proportion of saturates dissolved the soft segment in the SBS restorer to enhance the lowtemperature performance of the recycled asphalts.In addition,the stress sensitivity of the recycled asphalts increased with the fraction of aromatics in the regenerant.As the aromatic content of the base oil components of the regenerants increased and their saturate content decreased,the state of dispersion of the SBS phase in the recycled SBS-modified asphalts improved.The optimal content of aromatics in the base oil of the regenerants should be set in the range of 33%to 47%to ensure the adequate performance of the recycled asphalts and a high efficiency of the SBS restorer.展开更多
Pure bitumen is not suitable for heavy traffic loads;hence modifiers are used to improve the bitumen performance.Recently,cup lump rubber(CLR)has become a preferred modifier due to its outstanding performance and less...Pure bitumen is not suitable for heavy traffic loads;hence modifiers are used to improve the bitumen performance.Recently,cup lump rubber(CLR)has become a preferred modifier due to its outstanding performance and less cost.However,little is known about the interactions between CLR and bitumen.Thus,this study investigates the behavior of bitumen with CLR.Four percentages of CLR(2.5%,5.0%,7.5%,and 10.0%by weight of bitumen)were used to modify conventional 60/70 penetration grade bitumen.The modified bitumen was evaluated through different laboratory testing such as dynamic shear rheometer,rotational viscosity,softening point,bending beam rheometer,ductility,and elastic recovery.The testing results show that the addition of CLR increased the bitumen’s rutting resistance by 3 PG grades at high temperatures.At low pavement temperatures,the cup lump rubber modified bitumen(CMB)can withstand up to−34℃.Fourier Transform Infrared(FTIR)analysis shows that the Aromaticity index at 1600 cm^(−1) rose as the CLR percentage increased,indicating the formation of a binder with a compact structure.This is expected to improve the elasticity of bitumen throughπ-πinteractions.Atomic Force Microscopy(AFM)results showed the Catana phase increased in size and quantity at 5.0%and 7.5%CLR content.While contact angle measurement revealed that the binders are hydrophobic and tend to repel the dropped water on the bitumen surface.展开更多
基金Funded by the National Natural Science Foundation of China(No.52008069)。
文摘Modifying agents 2,2-Bis(4-glycidyloxyphenyl)propane(2BPE)and dibutyl phthalate(DBP)were selected to enhance the compatibility.By using molecular simulation software(Materials Studio,MS),nine systems were constructed,including molecular models of aged asphalt and WVO monomers with 2BPE and/or DBP.The solubility parameters,Flory-Huggins parameters,and interaction energies of these systems were calculated to determine the impact of 2BPE and DBP on the compatibility of WVO and aged asphalt.Results showed that the addition of 2BPE and DBP reduced the difference in the solubility parameters between WVO and aged asphalt,thus improving the compatibility between WVO and aged asphalt.Additionally,using a combination of 2BPE and DBP in both aged asphalt and rejuvenator was found to be more effective than using either 2BPE or DBP alone.Finally,it was determined that evaluating the compatibility of WVO and aged asphalt using Van der Waals potential and non-bonding energy as evaluation indicators was more accurate than using electrostatic potential energy.
基金Funded by Natural Science Foundation of Inner Mongolia,China (No. 2019MS05033)。
文摘In order to study the anti-fatigue performance of RCA modified asphalt (RMA),the performance of RMA and 90#matrix asphalt with different modifier content were measured by asphalt penetration,ductility,softening point,Brookfield viscosity,rheological index,infrared spectrum and dielectric constant test.This paper discusses the changes of asphalt basic indexes,fatigue properties and asphalt components based on dielectric properties under different modifier contents,and analyzes the grey correlation degree between components and asphalt pavement performance indexes.The results show that the optimum content of RCA modifier is 16.7%of the asphalt quality according to the penetration,ductility,softening point,Brockfield viscosity,viscosity temperature curve and fatigue life.In the phase angle-strain curve,there is disorder in the latter part of the curve.According to the strain (ε_(d)) corresponding to the disorder point,a new fatigue failure criterion is proposed and proved.Based on the new asphalt fatigue failure criterion,the fatigue prediction model of asphalt mixture is improved,and the fatigue life predicted by the improved fatigue model is compared with the fatigue life obtained by four-point bending fatigue test.The results show that the proposed new asphalt fatigue failure criterion is reasonable,and the fatigue life predicted by the improved asphalt mixture fatigue prediction model is accurate.The research method of classifying asphalt components based on dielectric properties is simple and effective,and the components have a high correlation with the road performance of base asphalt and modified asphalt.
基金the National Key R&D Program of China(2021YFB2601200)the Science and Technology Project of Department of Communication of Zhejiang Province(2021043).
文摘In this study,the regenerative effects of different regenerants on aged SBS-modified asphalt from different perspectives were investigated,including their conventional properties,viscoelastic behavior,creep-related properties,and micromorphology.Base oils composed of different proportions of aromatic and saturated hydrocarbons as well as the styrene-butadiene-styrene(SBS)restorer were used to prepare the regenerants.The results showed that the components of the base oil of the regenerant played a crucial role in determining the characteristics and performance of the recycled SBSmodified asphalt.Regenerants containing a high proportion of aromatics dissolved the hard segment in the SBS restorer,thereby delaying the effect of a reduction in the regenerants on the performance of the aged asphalts at a high temperature.Regenerants containing a high proportion of saturates dissolved the soft segment in the SBS restorer to enhance the lowtemperature performance of the recycled asphalts.In addition,the stress sensitivity of the recycled asphalts increased with the fraction of aromatics in the regenerant.As the aromatic content of the base oil components of the regenerants increased and their saturate content decreased,the state of dispersion of the SBS phase in the recycled SBS-modified asphalts improved.The optimal content of aromatics in the base oil of the regenerants should be set in the range of 33%to 47%to ensure the adequate performance of the recycled asphalts and a high efficiency of the SBS restorer.
基金The authors received funding for this research work through the Project No.(IFP-2020-89)from the Deputyship for Research&Innovation,Ministry of Education in Saudi Arabia.
文摘Pure bitumen is not suitable for heavy traffic loads;hence modifiers are used to improve the bitumen performance.Recently,cup lump rubber(CLR)has become a preferred modifier due to its outstanding performance and less cost.However,little is known about the interactions between CLR and bitumen.Thus,this study investigates the behavior of bitumen with CLR.Four percentages of CLR(2.5%,5.0%,7.5%,and 10.0%by weight of bitumen)were used to modify conventional 60/70 penetration grade bitumen.The modified bitumen was evaluated through different laboratory testing such as dynamic shear rheometer,rotational viscosity,softening point,bending beam rheometer,ductility,and elastic recovery.The testing results show that the addition of CLR increased the bitumen’s rutting resistance by 3 PG grades at high temperatures.At low pavement temperatures,the cup lump rubber modified bitumen(CMB)can withstand up to−34℃.Fourier Transform Infrared(FTIR)analysis shows that the Aromaticity index at 1600 cm^(−1) rose as the CLR percentage increased,indicating the formation of a binder with a compact structure.This is expected to improve the elasticity of bitumen throughπ-πinteractions.Atomic Force Microscopy(AFM)results showed the Catana phase increased in size and quantity at 5.0%and 7.5%CLR content.While contact angle measurement revealed that the binders are hydrophobic and tend to repel the dropped water on the bitumen surface.
