Datong coal was extracted with CS2, n-hexane, benzene, methanol, acetone, tetrahydro-furan（THF） and THF/methanol（1：3,v/v） mixed solvent sequentially. The extracts were analyzed with GC/MS. It is presented that gr...Datong coal was extracted with CS2, n-hexane, benzene, methanol, acetone, tetrahydro-furan（THF） and THF/methanol（1：3,v/v） mixed solvent sequentially. The extracts were analyzed with GC/MS. It is presented that group seperation of soluble organic compounds in the coal can be achieved by fractionated extraction using different solvents. The results show that CS2 was effective for extracting arenes from the coal sample, n-Hexane extractable fraction from Datong coal mainly consists of n-alkanes. A great variety of oxygen-containing compounds are dominant in the components of methanol-soluble fraction. Acyclic isoprenoids, pentecyclic triterpanes and a series of cyclohexanes with long-chain alkyl-substitutes are detected in acetone-soluble fraction. Dicyclic aramatic hydrocarbons are identified in benzene-soluble fraction and 4-6 cyclic condensed aramatic hydrocarbons are identified in THF-soluble fraction. The molecular structures detection of 1,2-dichlorobenzene, 2,4-dibromophnol, 2,4,6-tribromophenol and 4-chlorobenzophenone firstly provide information for existence form of bromine and chlorine in coal.展开更多
Additive manufacturing technology has been developed in Xi＇ an Jiaotong University for almost 20 years. Up to now~ it is still attracting the attentions of the researchers or manufacturers all over the world. Some in...Additive manufacturing technology has been developed in Xi＇ an Jiaotong University for almost 20 years. Up to now~ it is still attracting the attentions of the researchers or manufacturers all over the world. Some in- novative processes and frontier application research are all being conducted here to catch up with the new develop- ment of this technology. In the paper, newly developed processes, such as ultraviolet-light emitting diode （UV- LED） stereolithography, ceramic stereolithography, and direct metal forming, were described. Some results of the frontier application researches, such as indirect fabrication of ceramic casting mould, wind-tunnel-testing models, photonic crystals and metamatcrials, were also briefly reviewed.展开更多
基金Projects 20076051, G1999022101, and 98029016 supported by National Natural Science Foundation of China, the Special Found for Major State BasicResearch Project, and Research Found for the Doctoral Program of Higher Education
文摘Datong coal was extracted with CS2, n-hexane, benzene, methanol, acetone, tetrahydro-furan（THF） and THF/methanol（1：3,v/v） mixed solvent sequentially. The extracts were analyzed with GC/MS. It is presented that group seperation of soluble organic compounds in the coal can be achieved by fractionated extraction using different solvents. The results show that CS2 was effective for extracting arenes from the coal sample, n-Hexane extractable fraction from Datong coal mainly consists of n-alkanes. A great variety of oxygen-containing compounds are dominant in the components of methanol-soluble fraction. Acyclic isoprenoids, pentecyclic triterpanes and a series of cyclohexanes with long-chain alkyl-substitutes are detected in acetone-soluble fraction. Dicyclic aramatic hydrocarbons are identified in benzene-soluble fraction and 4-6 cyclic condensed aramatic hydrocarbons are identified in THF-soluble fraction. The molecular structures detection of 1,2-dichlorobenzene, 2,4-dibromophnol, 2,4,6-tribromophenol and 4-chlorobenzophenone firstly provide information for existence form of bromine and chlorine in coal.
文摘Additive manufacturing technology has been developed in Xi＇ an Jiaotong University for almost 20 years. Up to now~ it is still attracting the attentions of the researchers or manufacturers all over the world. Some in- novative processes and frontier application research are all being conducted here to catch up with the new develop- ment of this technology. In the paper, newly developed processes, such as ultraviolet-light emitting diode （UV- LED） stereolithography, ceramic stereolithography, and direct metal forming, were described. Some results of the frontier application researches, such as indirect fabrication of ceramic casting mould, wind-tunnel-testing models, photonic crystals and metamatcrials, were also briefly reviewed.
