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英语时制的体貌功能分析——基于二维几何表征的分析框架 被引量:3
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作者 卞京 张辉 《外语研究》 CSSCI 北大核心 2015年第4期1-7,12,共8页
以往有关时制与体貌的关系研究认为过去时对应完整体,为观察动貌提供了一个外部视角;现在时对应惯常体,为动貌提供了重复观察的视角。但是,本文在使用Croft提出的二维几何表征对不同动貌类型的动词进行体貌的二维表征分析时发现,英语时... 以往有关时制与体貌的关系研究认为过去时对应完整体,为观察动貌提供了一个外部视角;现在时对应惯常体,为动貌提供了重复观察的视角。但是,本文在使用Croft提出的二维几何表征对不同动貌类型的动词进行体貌的二维表征分析时发现,英语时制不仅能为不同类型的动貌提供不同的观察视点,并且能够同时改变动词所表征的原始动貌。 展开更多
关键词 时制 视点功能 动貌转换功能 二维几何表征
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Microstructures and mechanical properties of Mg-Al-Sm series heat-resistant magnesium alloys 被引量:7
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作者 黄正华 戚文军 +1 位作者 徐静 蔡畅 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第1期22-29,共8页
The microstructures and phase compositions of the as-cast and die-cast Mg-6.02Al-1.03 Sm, Mg-6.05Al-0.98Sm-0.56 Bi and Mg-5.95Al-1.01Sm-0.57 Zn alloys were investigated. Meanwhile, the tensile mechanical and flow prop... The microstructures and phase compositions of the as-cast and die-cast Mg-6.02Al-1.03 Sm, Mg-6.05Al-0.98Sm-0.56 Bi and Mg-5.95Al-1.01Sm-0.57 Zn alloys were investigated. Meanwhile, the tensile mechanical and flow properties were tested. The results show that the as-cast microstructure of Mg-6.02Al-1.03 Sm alloy is composed of δ-Mg matrix, discontinuous δ-Mg17Al12 phase and small block Al2 Sm phase with high thermal stability. Rod Mg3Bi2 phase precipitates when Bi is added, while the added metal Zn dissolves into δ-Mg matrix and δ-Mg17Al12 phase. The as-cast alloys exhibit the excellent tensile mechanical property. The tensile strength(δb) and elongation(δ) can reach 205-235 MPa and 8.5%-16.0% at ambient temperature, respectively. Meanwhile, they can also exceed 160 MPa and 14.0% at 423 K, respectively. The die-cast microstructures are refined obviously, and meanwhile the broken second phases distribute dispersedly. The die-cast alloys exhibit better tensile mechanical properties with the values of δb and δ of 240-285 MPa and 8.5%-16.5% at ambient temperature, respectively, and excellent flow property with the flow length of 1870-2420 mm. The die-cast tensile fractures at ambient temperature exhibit a typical character of ductile fracture. 展开更多
关键词 heat-resistant magnesium alloy Mg-Al-Sm alloy MICROSTRUCTURE mechanical property flow property fracture morphology
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Simulation and experimental validation of three-dimensional dendrite growth 被引量:1
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作者 石玉峰 许庆彦 柳百成 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第11期2756-2761,共6页
A three-dimensional (3-D) modified cellular automaton (MCA) method was developed for simulating the dendrite morphology of cubic system alloys. Two-dimensional (2-D) equations of growth velocities of the dendrit... A three-dimensional (3-D) modified cellular automaton (MCA) method was developed for simulating the dendrite morphology of cubic system alloys. Two-dimensional (2-D) equations of growth velocities of the dendrite tip, interface curvature and anisotropy of the surface energy were extended to 3-D system in the model. Therefore, the model was able to describe the morphology evolution of 3-D dendrites. Then, the model was applied to simulate the mechanism of spacing adjustment for 3-D columnar dendrite growth, and the competitive growth of columnar dendrites with different preferred growth orientations under constant temperature gradient and pulling velocity. Directional solidification experiments of NH4Cl-H2O transparent alloy were performed. It was found that the simulated results compared well with the experimental results. Therefore, the model was reliable for simulating the 3-D dendrite growth of cubic system alloys. 展开更多
关键词 modified cellular automation 3-D dendrite morphology dendrite growth directional solidification NH4Cl-H2O transparent alloy
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Environmentally assisted cracking resistance of Al-Cu-Li alloy AA2195 using slow strain rate test in 3.5% NaCl solution 被引量:1
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作者 R.GHOSH A.VENUGOPAL +2 位作者 P.RAMESH NARAYANAN S.C.SHARMA P.V.VENKITAKRISHNAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第2期241-249,共9页
The general corrosion and environmental cracking resistances of Al-Cu-Li alloy AA2195 were investigated in 3.5% NaCl environment and compared with those of another high strength alloy AA2219. The general corrosion re... The general corrosion and environmental cracking resistances of Al-Cu-Li alloy AA2195 were investigated in 3.5% NaCl environment and compared with those of another high strength alloy AA2219. The general corrosion resistance of these alloys was examined using immersion corrosion and potentiodynamic polarization tests, while the stress corrosion cracking (SCC) resistance was evaluated by slow strain rate test (SSRT) method. The tested samples were further characterized by SEM-EDS and optical profilometry to study the change in corrosion morphology, elemental content and depth of corrosion attack. The reduction in ductility was used as a parameter to evaluate the SCC susceptibility of the alloys. The results indicated that the corrosion resistance of AA2195 alloy was better than that of AA2219 alloy as it exhibited lower corrosion rate, along with lower pit depth and density. However, the SCC index (εNaCl/εair) measured was greater than 0.90, indicating good environmental cracking resistance of both the alloys. Detailed fractography of the failed samples under SEM?EDS, in general, revealed a typical ductile cracking morphology for both the alloys. 展开更多
关键词 Al-Cu-Li alloy stress corrosion cracking FRACTOGRAPHY potentiodynamic polarization
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Analysis of pressure pulsation mechanism and dynamic characteristics of axial piston pump 被引量:3
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作者 ZHAO Baojian GU Lichen +4 位作者 LIU Jiamin GENG Baolong SHI Yuan WU Haoyu YANG Sha 《Journal of Measurement Science and Instrumentation》 CAS CSCD 2022年第1期21-30,共10页
The pressure pulsation of axial piston pump is not only an important cause of rotation speed fluctuation,vibration noise and output stability of the hydraulic system,but also the main information source for obtaining ... The pressure pulsation of axial piston pump is not only an important cause of rotation speed fluctuation,vibration noise and output stability of the hydraulic system,but also the main information source for obtaining fault information.Hydraulic system is characterized by strong noise interference,which leads to low signal-to-noise ratio(SNR)of detection signals.Therefore,it is necessary to dig deep into the system operating state information carried by pressure signals.Firstly,based on flow loss mechanism of the plunger pump,the mapping relationship between flow pulsation and pressure pulsation is analyzed.After that,the pressure signal is filtered and reconstructed based on standard Gabor transform.Finally,according to the time-domain waveform morphology of pressure signal,four characteristic indicators are proposed to analyze the characteristics of pressure fluctuations under different working conditions.The experimental results show that the standard Gabor transform can accurately extract high-order harmonics and phase frequencies of the signal.The reconstructed time-domain waveform of pressure pulsation of the axial piston pump contains a wealth of operating status information,and the characteristics of pulsation changes under various working conditions can provide a new theoretical basis and a method support for fault diagnosis and health assessment of hydraulic pumps,motors and key components. 展开更多
关键词 axial piston pump pressure pulsation standard Gabor transform appearance characteristics operating conditions
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Effect of landform on aerodynamic performance of high-speed trains in cutting under cross wind 被引量:18
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作者 刘堂红 张洁 《Journal of Central South University》 SCIE EI CAS 2013年第3期830-836,共7页
The effects of the different landforms of the cutting leeward on the aerodynamic performance of high-speed trains were analyzed based on the three-dimensional, steady, and incompressible Navier-Stokes equation and k-e... The effects of the different landforms of the cutting leeward on the aerodynamic performance of high-speed trains were analyzed based on the three-dimensional, steady, and incompressible Navier-Stokes equation and k-e double-equation turbulent model. Results show that aerodynamic forces increase with the cutting leeward slope decreasing. The maximum adding value of lateral force, lift force, and overturning moment are 147%, 44.3%, and 107%, respectively, when the slope varies from 0.67 to -0.67, and the changes in the cutting leeward landform have more effects on the aerodynamic performance when the train is running in the line No. 2 than in the line No. 1. The aerodynamic forces, except the resistance force, sharply increase with the slope depth decreasing. By comparing the circumstance of the cutting depth H=-8 m with that of H=8 m, the resistance force, lateral force, lift force, and overturning moment increase by 26.0%, 251%, 67.3% and 177%, respectively. With the wind angle increasing, the resistance force is nonmonotonic, whereas other forces continuously rise. Under three special landforms, the changes in the law of aerodynamic forces with the wind angle are almost similar to one another. 展开更多
关键词 high-speed train cross wind special landform aerodynamic performance
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Examination and Research of the Surface Topography of Ultrasonic Vibration Honing Nd-Fe-B
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作者 祝锡晶 陆志猛 +1 位作者 王建青 成全 《Journal of Measurement Science and Instrumentation》 CAS 2010年第2期201-204,共4页
The mechanism of ultrasonic vibration honing Nd-Fe-B has been briefly elaborated after the introduction of the strategic significance of processing Nd-Fe-B. Based on the formation principle of Scanning Electrtmic Micr... The mechanism of ultrasonic vibration honing Nd-Fe-B has been briefly elaborated after the introduction of the strategic significance of processing Nd-Fe-B. Based on the formation principle of Scanning Electrtmic Microscope (SEM), and at the examination with the aid of SEM to the ultrasonic vibration honing Nd-Fe-B material's superficial microscopic topography, the paper discusses the new processing nechanism according to the SEM examination picture. The research indicates that as a result of supersonic high frequency vibration, the path of the abrasion extends at the same time, and the supersonic cavitation effect forms the intense shock-wave, knpacting Nd-Fe-B material's intemal surface, providing the supersonic energy for the superticial abrasive dust's dimination, which directly explain that the honing processing efficiency is enhanced, and the processing surface roughness is high. 展开更多
关键词 SEM ultrasonic processing HONING Nd- Fe- B ultra- sonic cavitation
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Nomenclature for lunar features at the Chang'e-3 landing site
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作者 Zhoubin Zhang Chunlai Li +1 位作者 Wei Zuo Xingguo Zeng 《Acta Geochimica》 EI CAS CSCD 2017年第2期213-223,共11页
Nomenclatures for lunar features always accompany the progresses of human lunar exploration,which has an important dual meaning in culture and science. The naming of lunar features not only can commemorate the outstan... Nomenclatures for lunar features always accompany the progresses of human lunar exploration,which has an important dual meaning in culture and science. The naming of lunar features not only can commemorate the outstanding contributions of academics,masters in various fields, and popularize the traditional cultures of ethnic groups all over the world, but also have a critical function of providing accurate indicative information on features with special morphology, origin, nature and scientific value. However, nomenclature for features at the Chang'e-3 landing site, which has a more arbitrary form without many constrains posed by a uniformed system, is unlike the features for other morphological units.This paper originated from the actual needs for the description of scientific exploration activities, interpretation of scientific research and dissemination of scientific results. Some prominent morphological units with great scientific importance and identification purpose were chosen from the images taken by the terrain camera, panorama cameras and landing camera onboard the Chang'e lander and Yutu rover. A nomenclature system was established under the three enclosures, four quadrants and twenty-eight lunar lodges' system of the Chinese ancient sky division method. Finally, a standard feature names set waspublished after some necessary approval procedures by the International Astronomical Union. 展开更多
关键词 MOON Chang'e-3 Landing site Lunarfeature nomenclature
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Numerical simulation of solidification morphologies of Cu-0.6Cr casting alloy using modified cellular automaton model 被引量:9
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作者 TSAI De-chang HWANG Weng-sing 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2010年第6期1072-1077,共6页
The purpose of this study is to predict the morphologies in the solidification process for Cu-0.6Cr(mass fraction,%)alloy by vacuum continuous casting(VCC)and verify its accuracy by the observed experimental results.I... The purpose of this study is to predict the morphologies in the solidification process for Cu-0.6Cr(mass fraction,%)alloy by vacuum continuous casting(VCC)and verify its accuracy by the observed experimental results.In numerical simulation aspect, finite difference(FD)method and modified cellular automaton(MCA)model were used to simulate the macro-temperature field, micro-concentration field,nucleation and grain growth of Cu-0.6Cr alloy using real data from actual casting operations.From the observed casting experiment,the preliminary grain morphologies are the directional columnar grains by the VCC process.The solidification morphologies by MCAFD model are in agreement with the result of actual casting experiment well. 展开更多
关键词 Cu-Cr alloy vacuum continuous casting solidification morphology simulation modified cellular automaton model finite difference method
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Effects of Electrolyte Concentration, Temperature, Flow Velocity and Current Density on Zn Deposit Morphology
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作者 Aleksandra Gavrilovic-Wohlmuther Andreas Laskos +2 位作者 Christian Zelger Bernhard Gollas AdamHarding Whitehead 《Journal of Energy and Power Engineering》 2015年第11期1019-1028,共10页
The most critical disadvantages of the Zn-air flow battery system are corrosion of the zinc, which appears as a high self-discharge current density and a short cycle life due to the non-uniform, dendritic, zinc electr... The most critical disadvantages of the Zn-air flow battery system are corrosion of the zinc, which appears as a high self-discharge current density and a short cycle life due to the non-uniform, dendritic, zinc electrodeposition that can lead to internal short-circuit. In our efforts to find a dendrite-free Zn electrodeposition which can be utilized in the Zn-air flow battery, the surface morphology of the electrolytic Zn deposits on a polished polymer carbon composite anode in alkaline, additive-free solutions was studied. Experiments were carried out with 0.1 M, 0.2 M and 0.5 M zincate concentrations in 8 M KOH. The effects of different working conditions such as: elevated temperatures, different current densities and different flow velocities, on current efficiency and dendrite formation were investigated. Specially designed test flow-cell with a central transparent window was employed. The highest Coulombic efficiencies of 80%-93% were found for 0.5 M ZnO in 8 M KOH, at increased temperatures (50-70 ℃), current densities of up to 100 mA.cm2 and linear electrolyte flow velocities higher than 6.7 cm.s1. 展开更多
关键词 DENDRITE ELECTROCHEMISTRY flow battery ZINC zinc morphology.
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现代汉语体貌系统研究述评 被引量:1
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作者 周莹 李明晶 《汉字文化》 2020年第21期54-58,共5页
文章通过对国内外有关现代汉语体貌系统研究的文献著作进行梳理和述评,在此基础上探讨现代汉语体貌系统中的动词分类,并对前人提出的无体貌动词这类特殊动词进行未来研究展望。
关键词 现代汉语 系统 动貌 无体
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Internal Pressure Sculpting and Speleogenesis in Autogenic Karst
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作者 Bryan Booth 《Journal of Earth Science and Engineering》 2013年第7期461-476,共16页
Understanding the ongoing speleogenic processes that produce sinkholes and control the vital drinking water supplies of Florida and much else of the world is necessary research. This article (and the associated poste... Understanding the ongoing speleogenic processes that produce sinkholes and control the vital drinking water supplies of Florida and much else of the world is necessary research. This article (and the associated poster presentation) discusses theoretical processes that may act in addition to mass dissolution kinetics in producing voids, conduits and caves in autogenic karst landforms. Possible theoretical factors that affect these speleogenic processes are: microscopic mixing corrosion (low constant flow, low constant flow against current, temperature-induced mixing corrosion, and pressure-induced mixing corrosion in karst matrix), random dissolution models, simulation of gravity-induced microscopic breakdown, and storm surge effects. Finally, a theoretical model is discussed that unifies these various microscopic processes into a macro-scale process, called internal pressure sculpting. Computer models were designed to illustrate these theoretical processes: Non-calibrated computer models simulating each process discussed in this paper are presented for illustration, as well as the preliminary results of calibrated models depicting random dissolution, mechanical breakdown, and storm surge effects. The theoretical processes discussed and simulated may have major effects on cave morphology. Computer simulations appear to accurately portray the shape and form of some cave features with dissolutional morphologies. Theoretical discussion concludes with a general discussion of possible improvements to the presented models as well as the ability to generalize theoretical processes to hypogenic, halogenic, and autogenic speleogenesis. 展开更多
关键词 Cave development in limestone mixing corrosion KARST computer modeling solutional widening rate speleogenesis.
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The Spatio-temporal Patterns of Macro Benthos Functional Groups and the Associated Factors Affecting Them after Wetland Restoration 被引量:1
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作者 WANG Maoqiu HU Yang +7 位作者 HE Ning WU Mingxuan WU Pengling WANG Qinyi ZHANG Bolun ZHANG Shengle GAO Meihua FANG Shubo 《Journal of Resources and Ecology》 CSCD 2022年第6期1152-1164,共13页
This study examines how the spatiotemporal patterns of functional groups of macro benthos responded to coastal wetland restoration projects. Compared with the traditional single-species approach, methods for identifyi... This study examines how the spatiotemporal patterns of functional groups of macro benthos responded to coastal wetland restoration projects. Compared with the traditional single-species approach, methods for identifying functional groups of macro benthos more comprehensively reflect the states of the wetland, i.e., spatiotemporal patterns and the related influencing factors. In this study, the macro benthos samples, soil samples, and plant samples were collected at each same sample site in April, July, and October of 2017 and January of 2018. After classification of the macro benthos functional groups according to some traits, the factors influencing the functional groups were examined by a linear stepwise regression. The results showed that all macro benthos were classified into 11 different functional groups based on their traits of forms of locomotion, feeding habits, and food gathering methods. The semi-mobile suspensivores(FDX), semi-mobile surface detritivores(SDX), and Jawed mobile carnivores(CMJ) were the main groups observed in a year. Regression analysis showed that particle size,moisture content, and plant height were important common factors influencing most groups. The main influencing factor of FDX was particle size(P=0.020). Moisture content(P=0.004), plant cover degree(P=0.008), and particle size(P=0.032) comprised the main restrictions of SDX in summer. Soil salinity(P=0.040) and plant height(P=0.011)were the factors influencing CMJ in autumn and winter. This study shows the changing characteristics of macro benthos functional groups to promote coastal wetland restoration and future biogeomorphological studies. 展开更多
关键词 functional groups macro benthos spatiotemporal patterns biogeomorphological index wetlands restoration
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Seasonal Effect of Geomorphological Chronosequence Features on Soil Biota Dynamics 被引量:1
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作者 S.PEN-MOURATOV N.GENZER +2 位作者 N.SHUKUROV J.PLAKHT Y.STEINBERGER 《Pedosphere》 SCIE CAS CSCD 2010年第6期761-770,共10页
Numerous studies have been devoted to the physical-chemical weathering processes leading to the creation of unique soil formations having their own history that induce soil-biotic diversity.However,the extent to which... Numerous studies have been devoted to the physical-chemical weathering processes leading to the creation of unique soil formations having their own history that induce soil-biotic diversity.However,the extent to which unique geomorphic formations influence soil biotic seasonal variation is not clear.Our aim was to define seasonal variations of soil biota in soils of different-aged terraces of the Makhtesh Ramon anticline erosional cirque in southern Israel.The strong effect of Makhtesh Ramon (Ramon crater) erosional fluvial terrace age initiated by climatic changes during the Late Pleistocene- Early Holocene period on seasonal variations in both soil properties and the abundance and composition of soil biota were demonstrated.However,age dependence was not constant and values for observed soil properties and microbial activity were negligible between younger and older terraces for certain seasons,while free-living nematodes along with bacterial-feeding group were strongly dependent on the geomorphic features of the ages throughout the study period. 展开更多
关键词 geomorphic formation Makhtesh Ramon microbial biomass nematode community trophic group
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Activity of the Lenglongling fault system and seismotectonics of the 2016 MS6.4 Menyuan earthquake 被引量:20
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作者 GUO Peng HAN ZhuJun +3 位作者 AN YanFen JIANG WenLiang MAO ZeBin FENG Wei 《Science China Earth Sciences》 SCIE EI CAS CSCD 2017年第5期929-942,共14页
The MS6.4 Menyuan earthquake occurred on the northern side of the Lenglongling fault(LLLF) in the mid-western of the Qilian-Haiyuan fault zone on January 21, 2016. The earthquake epicenter was distant from the Minle-D... The MS6.4 Menyuan earthquake occurred on the northern side of the Lenglongling fault(LLLF) in the mid-western of the Qilian-Haiyuan fault zone on January 21, 2016. The earthquake epicenter was distant from the Minle-Damaying and Huangcheng-Shuangta faults, eastern of the Northern Qilian Shan fault zone. A near northwest-striking rupture plane intersects the two faults at a certain angle. The focal mechanism solution shows that this was a thrust-type earthquake, slightly different from the strike-slip movement with a thrust component of the LLLF. Field geological mapping, tectonic geomorphology analysis, trench excavation and 14 C dating reveal that(1) the LLLF has been obviously active since the Holocene, and may behave with characteristic slip behavior and produce M_W7.3–7.5 earthquakes;(2) the LLLF appears as a flower structure in terms of structure style, and dips NNE at a steep angle; and(3) the most recent earthquake event occurred after 1815–1065 a BP. An associated fault, the Northern Lenglongling fault(NLLLF), is located at the northwestern end of the LLLF. Consequently, the NLLLF was continually subject to tectonic pushing effects from the left-lateral shear at the end of the LLLF, and, accordingly, it bent and rotated outward tectonically.Subsequently, the fault deviated from the dominant rupture azimuth and activity weakened. In the late Quaternary, it behaved as a thrust fault with no obvious deformation at the surface. This is indicated by the arc shape, with a micro-protrusion northeastward,and no geologic or geomorphic signs of surface rupturing since the late Quaternary. However, such faults could still rupture at depth, producing moderate-strong earthquakes. The geometric and kinematic properties of the NLLLF are in good agreement with the occurrence and kinematic properties of nodal plane 2, and with the distribution characteristics of the aftershocks and seismic intensity. Therefore, the NLLLF is a more suitable seismogenic structure for the MS 6.4 Menyuan earthquake. In addition, the thrust movement of the NLLLF accommodates subsequent movement of the LLLF. During the historical evolution of the NLLLF,the LLLF and the NLLLF have affected the local topography through tectonic uplift. 展开更多
关键词 MS6 4 Mengyuan earthquake Seismogenic structure Tectonic environment Lenglongling fault Northern Lenglongling fault
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Channel flow of the lower crust and its relation to large-scale tectonic geomorphology of the eastern Tibetan Plateau 被引量:7
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作者 WANG XiaoFang HE JianKun 《Science China Earth Sciences》 SCIE EI CAS 2012年第8期1383-1390,共8页
The Tibetan Plateau is a large-scale tectonic geomorphologic unit formed by the interactions of plates.It has been commonly believed that convective removal of the thickened Tibetan lithosphere,or lateral flow of the ... The Tibetan Plateau is a large-scale tectonic geomorphologic unit formed by the interactions of plates.It has been commonly believed that convective removal of the thickened Tibetan lithosphere,or lateral flow of the lower crust beneath the Tibetan plateau plays a crucial role in the formation of the large-scale tectonic geomorphologic features.Recent geological and geo-physical observations have provided important evidence in support of the lower crustal channel flow model.However,it re-mains unclear as how the geometry of lower crustal channel and the lateral variation of crustal rheology within the lower crust channel may have affected spatio-temporal evolution of the tectonic geomorphologic unit of the Tibetan Plateau.Here,we use numerical methods to explore the mechanical relations between the lower crustal channel flow and the tectonic geomorpho-logic formation around the eastern Tibetan plateau,by deriving a series of governing equations from fluid mechanics theory.From numerous tests,our results show that the viscosity of the channeled lower crust is about(1-5)×1018 to(1-4)×1020 Pa s(Pa.s) beneath the margin of the eastern Tibetan Plateau,and increases to about 1022 Pa s beneath the Sichuan Basin and the southern region of Yunnan Province.Numerical tests also indicate that if channel flows of the lower crust exist,the horizontal propagation and the vertical uplifting rate of the eastern Tibetan Plateau margin could be accelerated with the time.Thus,the present results could be useful to constrain the rheological structure of the crust beneath the eastern Tibetan plateau,and to understand the possible mechanics of rapid uplift of the eastern Tibetan Plateau margin,especially since its occurrence at 8Ma as revealed by numerous geological observations. 展开更多
关键词 channel flow rheology of the lower crust tectonic geomorphology eastern margin of the Tibetan Plateau
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Synergistic electronic and morphological modulation on ternary Co_(1-x)V_(x)P nanoneedle arrays for hydrogen evolution reaction with large current density 被引量:3
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作者 Mingyang Yang Chaoqun Shang +8 位作者 Feifei Li Chen Liu Zhenyu Wang Shuai Gu Di Liu Lujie Cao Junjun Zhang Zhouguang Lu Hui Pan 《Science China Materials》 SCIE EI CAS CSCD 2021年第4期880-891,共12页
It is a great challenge to prepare non-noble metal electrocatalysts toward hydrogen evolution reaction(HER)with large current density.Synergistic electronic and morphological structures of the catalyst have been consi... It is a great challenge to prepare non-noble metal electrocatalysts toward hydrogen evolution reaction(HER)with large current density.Synergistic electronic and morphological structures of the catalyst have been considered as an effective method to improve the catalytic performance,due to the enhanced intrinsic activity and enlarged accessible active sites.Herein,we present novel ternary Co_(1-x)V_(x)P nanoneedle arrays with modulated electronic and morphological structures as an electrocatalyst for highly efficient HER in alkaline solution.The NF@Co1-xVxP catalyst shows a remarkable catalytic ability with low overpotentials of 46 and 226 mV at current densities of 10 and 400 mA cm^(-2),respectively,as well as a small Tafel slope and superior stability.Combining the experimental and computational study,the excellent catalytic performance was attributed to the improved physical and chemical properties(conductivity and surface activity),large active surface area,and fast reaction kinetics.Furthermore,the assembled Co–V based electrolyzer(NF@Co_(1-x)V_(x)–HNNs(+)||NF@Co_(1-x)V_(x)P(-))delivers small full-cell voltages of 1.58,1.75,and 1.92 V at 10,100,and 300 mA cm^(-2),respectively.Our findings provide a systematic understanding on the V–incorporation strategy to promote highly efficient ternary electrocatalysts via synergistic control of morphology and electronic structures. 展开更多
关键词 modulated morphology and electronic structures ternary Co1-xVxP hydrogen evolution reaction overall water splitting
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