Ni-45.5Al-9Mo （mole fraction,%） alloy was directionally solidified with a constant temperature gradient （GL=334 K/cm） and growth rates ranging from 2 to 300 μm/s using a Bridgman type crystal growing facility wit...Ni-45.5Al-9Mo （mole fraction,%） alloy was directionally solidified with a constant temperature gradient （GL=334 K/cm） and growth rates ranging from 2 to 300 μm/s using a Bridgman type crystal growing facility with liquid metal cooling （LMC） technique. The effect of growth rate （v） on the solidified microstructures such as rod spacing （λ）, rod size （d） and rod volume fraction was experimentally investigated. Two types of the solidified interfaces, planar and cellular, were identified. On the condition of both planar and cellular eutectic microstructures, the relationships between λ, d and v were given as： λv1/2=5.90 μm·μm1/2·s1/2 and dv1/2=2.18μm·μm1/2·s1/2, respectively. It was observed that the volume fraction of Mo phase could be adjusted in a certain range. The variation of phase volume fraction was attributed to undercooling increase and the growth characteristics of the individual constituent phases during the eutectic growth.展开更多
The effects of different structures of 2:1 layer minerals, layer charge location, and changes of structure and charge during the weathering process on the fixation and release of interlayer cations are reviewed. It co...The effects of different structures of 2:1 layer minerals, layer charge location, and changes of structure and charge during the weathering process on the fixation and release of interlayer cations are reviewed. It could be concluded that the fixation capacity is determined by the total amount of interlayer charge originating from both octahedral and tetrahedral sheets. The relationship between interlayer cation fixation and octahedral structure of the secondary minerals may be different from that of the primary minerals. The oxidation and reduction of cations with variable valence can greatly influence the cation-fixation capacity.展开更多
Four waste materials, paper, wood, textile and kitchen garbage, in municipal solid waste were gasified separately with oxygen in a fixed bed reactor. The yields of products char. tar and gas, the composition of gas co...Four waste materials, paper, wood, textile and kitchen garbage, in municipal solid waste were gasified separately with oxygen in a fixed bed reactor. The yields of products char. tar and gas, the composition of gas components H2, CO, CO2 and CH4, and the lower heating value （LHV） were examined at temperatures between 700 and 900 ℃ and equivalence ratio （ER） between 0.14 and 0.32. Characteristics of gas evolution during gasification were inves- tigated. Results show that a higher temperature improves the formation of H2 and CO while lowers the yield of CO2 and CH4. The LHV of syngas increases with temperature and varies in the range of 6-10 MJ. m-3 reaching the maximum at 800 ℃ or above. As ER increases, both combustible gas component and LHV of syngas decrease while the yield of CO2 rises linearly. The appropriate ER for obtaining high quality gas is in the range of 0.18-0.23. Temperature and ER have significant effects on the product distribution. Higher temperature and ER are favorable for higher gas yield and lower yield of char and tar in the gasification of textile and kitchen garbage. At 800 ℃, the gas evolution may be divided into two regions. In the first region, the flow rate of gas increases and then de- creases ranidlv, while in the second reuion the flow rate decreases monotonically to lower level.展开更多
This paper contributes to the Industrial Ecology Concept by using a common urban solid waste, i.e., coffee residues, to clean industrial wastewaters polluted by basic dyes, e.g., Methylene Blue. For the data from the ...This paper contributes to the Industrial Ecology Concept by using a common urban solid waste, i.e., coffee residues, to clean industrial wastewaters polluted by basic dyes, e.g., Methylene Blue. For the data from the continuous fixed-bed column system, two common models, namely （a） Bohart and Adams and （b） Clark were implemented. The Bohart and Adams capacity was up to N = 46,166 mg.L-1 or q0 = 104.5 mg.g-1 for bed-depth 15 cm, initial dye concentration 800 mg.g-1 and flow rate 20 mL.min-1. The results revealed that the Methylene Blue is fairly adsorbed on coffee residues. Consequently, this process can be applied as a low cost technique for cleaning basic dyes from the aquatic environment.展开更多
Bali Tourism Development Corporation＇s lagoon （BTDC lagoon） has been used for treating wastewaters that come from all facilities available in the Nusa Dua Resort tourist area. Reuse of the lagoon effluent is limite...Bali Tourism Development Corporation＇s lagoon （BTDC lagoon） has been used for treating wastewaters that come from all facilities available in the Nusa Dua Resort tourist area. Reuse of the lagoon effluent is limited for some applications due to salt and suspended solid contents. Application of an integrated membrane system for improving the water quality of the lagoon effluent which is suitable for various uses is under consideration. In this work an ultraflltration （UF） pilot performance for possible pretreatment of Reverse Osmosis （RO） was investigated. The results showed that permeate quality was stable （less than 0.5 NTU）, regardless of concentrating and diluting retentate in each cycle and fouling for a long duration of operation. However, the water quality obtained with this membrane was not enough to be directly used. The permeate quality obtained from the UF system fulfils the requirement for the optimal operation of reverse osmosis. Moreover, appropriate intermittent-backwash operation was fairly effective to maintain the fluxes at a reasonable level.展开更多
According to the uncertainties in the results and the wide diversity of how to approach the subject, a new concept for energy is proposed： Energy is an exchange between two different concentrations, the concentration...According to the uncertainties in the results and the wide diversity of how to approach the subject, a new concept for energy is proposed： Energy is an exchange between two different concentrations, the concentration of time in space outside what we call matter and the concentrated phase of time in matter space which is the matter itself. The concept of motion for energy is replaced by time-space interactions with time taken as solid matter. Motion enhances the exchange between the mass and its surrounding time in space, annihilation and creation are special forms of this exchange. During the motion of a mass, it increases as a result of this dissolution. Time concentration in Fock space is responsible for the collision phenomena in physics. In this paper, a new mathematical operator （the equal operator） is introduced.展开更多
The effect of mixed oxide support on the performance of Ni/ZnO in the reactive adsorption desulfurization(RADS) reaction was investigated in a fixed bed reactor by using thiophene as the sulfur-containing compound in ...The effect of mixed oxide support on the performance of Ni/ZnO in the reactive adsorption desulfurization(RADS) reaction was investigated in a fixed bed reactor by using thiophene as the sulfur-containing compound in the model gasoline. A series of oxide supports for Ni/ZnO were synthesized by the co-precipitation method and characterized by XRD, N_2-adsorption, TPR and NH_3-TPD techniques. It was found that the desulfurization capacity of Ni/ZnO was enhanced greatly when active components were supported on the proper mixed oxide. Ni/ZnO supported on oxides exhibited much higher desulfurization efficiency and sulfur adsorption capacity than the unsupported Ni/ZnO and the synthesized Ni/ZnO-SA adsorbent exhibited the highest efficiency for thiophene removal. The higher desulfurization activity and sulfur capacity of Ni/ZnO supported on SiO_2-Al_2O_3 with small particle size, high specific surface area and large pore volume could promote the high dispersion of active metal phase and the transfer of sulfur to ZnO with lower mass transfer resistance. γ-Al_2O_3 species could weaken the interaction of active phases and SiO_2 as well as could increase greatly the amount of weak acids. Therefore, these oxides could impose a great influence on the structure and chemical properties of the catalyst.展开更多
The cases of cholera in Mariupol and adjacent areas which were observed within the period of May-August, 2011 are investigated. Thirty-two diseased and 22 vibriocarriers were found on the territory of the city in the ...The cases of cholera in Mariupol and adjacent areas which were observed within the period of May-August, 2011 are investigated. Thirty-two diseased and 22 vibriocarriers were found on the territory of the city in the course of epidemic. The potential sources of infection are specified. The ways to avoid similar situations in the future are suggested. The analysis of the locations of the cholera contamination sources results in the obvious conclusion that most of them are connected with the place where the river Kalmius meets the Azov Sea. Waste flow from the residential solid waste landfill brings a considerable harm to the river Kalmius and the Azov Sea.展开更多
Rising fuel prices, increasing emission levels and impending environmental regulations made shipping industry to find an alternate for internal combustion engine in 21st century. Fuel cell is a sustainable, emerging t...Rising fuel prices, increasing emission levels and impending environmental regulations made shipping industry to find an alternate for internal combustion engine in 21st century. Fuel cell is a sustainable, emerging technology with negligible pollution. More significantly for a research ship, emission levels need to be substantially low to have quality measurements. A feasibility study is carried-out First time in the world, to drive an ice class multi-disciplinary ORV （Oceanography Research Vessel） Sagarnidbi, using hydrogen powered fuel cell. Sagamidhi is equipped with special equipments viz., Deep Sea winch, specially designed cranes for Launching and retrieval of ROV （Remotely Operable Vehicle）, DSMC （Deep Sea Mining Crawler）, Tsunami systems, manned/unmanned submersible and ACS （Autonomous Coring System） and other facilities that support research in Indian, International and Antarctic waters. Beside this, the propulsion system along with DP （Dynamic Positioning）, centralized air conditioning and special equipments require enormous electrical power. The combustion of diesel oil in an engine, that coupled with an alternator generates electrical power required, along with NOx （Nitrous Oxides）, SOx （Sulphur Oxides） and PM （Particulate Matter） emissions. Shipping industry is the fourth largest contributor to air pollution and carbon emissions, particularly in coastal areas, and the growth rate makes the problem even more critical. Stringent international air pollution regulation and increasing fuel price paves the way for an alternative ＂green emission technology＂. Various fuel cells were analyzed with different combination of fuel, electrolyte and electrodes. From the analysis, it has been found that SOFC （Solid Oxide Fuel Cell） is most suitable for the present scenario. A fuel cell designed with hydrogen as fuel, zirconium oxides stabilized with yttrium oxide as electrolyte and zirconium electrodes is used for 1.5 MW power output and 0.5 MW through regenerator. Volume required for storage of hydrogen is in line with volume of fuel and a high standard safety measures were taken using sensors. The present system saves 3000 MT/annum of diesel oil costing 3,000,000 USD approximately.展开更多
Biomass in the form of nutshell, hay of catkin, wheat straw and linseed residue in particles have been pyrolyzed in laboratory scale fixed bed reactor which yielded liquid oil, solid char and gas. The variation of oil...Biomass in the form of nutshell, hay of catkin, wheat straw and linseed residue in particles have been pyrolyzed in laboratory scale fixed bed reactor which yielded liquid oil, solid char and gas. The variation of oil yield for different biomass feedstock with reactor bed temperature and feed size is presented in this paper. A maximum liquid yield of 55 wt% of dry feedstock is obtained at an optimum temperature of 500℃ for a feed size of 300-600μm with a running time of 55 min for nutshell as the feedstock while the minimum liquid oil yield is found to be 30 wt% of feedstock at an optimum temperature of 400℃ for a feed size of 2.36 mm with a running time of 65 min for linseed residue as the feedstock. A comparison on the product yields is highlighted in this study. The pyrolysis liquid products are characterized and compared for some of the fuel properties like HHV （higher heating value）, viscosity, density and specific gravity.展开更多
基金Project (51074128) supported by the National Natural Science Foundation of ChinaProject (2007ZF53067) supported by the Aeronautical Science Foundation of China+1 种基金Project (2010JM6002) supported by the Natural Science Foundation of Shaanxi Province of ChinaProjec t(2012NCL004) supported by the Innovation Foundation of Inner Mongolia University of Science and Technology
文摘Ni-45.5Al-9Mo （mole fraction,%） alloy was directionally solidified with a constant temperature gradient （GL=334 K/cm） and growth rates ranging from 2 to 300 μm/s using a Bridgman type crystal growing facility with liquid metal cooling （LMC） technique. The effect of growth rate （v） on the solidified microstructures such as rod spacing （λ）, rod size （d） and rod volume fraction was experimentally investigated. Two types of the solidified interfaces, planar and cellular, were identified. On the condition of both planar and cellular eutectic microstructures, the relationships between λ, d and v were given as： λv1/2=5.90 μm·μm1/2·s1/2 and dv1/2=2.18μm·μm1/2·s1/2, respectively. It was observed that the volume fraction of Mo phase could be adjusted in a certain range. The variation of phase volume fraction was attributed to undercooling increase and the growth characteristics of the individual constituent phases during the eutectic growth.
基金Project(No.39770427)supported by the National Natural Science Foundation of China.
文摘The effects of different structures of 2:1 layer minerals, layer charge location, and changes of structure and charge during the weathering process on the fixation and release of interlayer cations are reviewed. It could be concluded that the fixation capacity is determined by the total amount of interlayer charge originating from both octahedral and tetrahedral sheets. The relationship between interlayer cation fixation and octahedral structure of the secondary minerals may be different from that of the primary minerals. The oxidation and reduction of cations with variable valence can greatly influence the cation-fixation capacity.
基金Supported by the National Basic Research Program of China(2011CB201505)the National Natural Science Foundation of China(51006023)
文摘Four waste materials, paper, wood, textile and kitchen garbage, in municipal solid waste were gasified separately with oxygen in a fixed bed reactor. The yields of products char. tar and gas, the composition of gas components H2, CO, CO2 and CH4, and the lower heating value （LHV） were examined at temperatures between 700 and 900 ℃ and equivalence ratio （ER） between 0.14 and 0.32. Characteristics of gas evolution during gasification were inves- tigated. Results show that a higher temperature improves the formation of H2 and CO while lowers the yield of CO2 and CH4. The LHV of syngas increases with temperature and varies in the range of 6-10 MJ. m-3 reaching the maximum at 800 ℃ or above. As ER increases, both combustible gas component and LHV of syngas decrease while the yield of CO2 rises linearly. The appropriate ER for obtaining high quality gas is in the range of 0.18-0.23. Temperature and ER have significant effects on the product distribution. Higher temperature and ER are favorable for higher gas yield and lower yield of char and tar in the gasification of textile and kitchen garbage. At 800 ℃, the gas evolution may be divided into two regions. In the first region, the flow rate of gas increases and then de- creases ranidlv, while in the second reuion the flow rate decreases monotonically to lower level.
文摘This paper contributes to the Industrial Ecology Concept by using a common urban solid waste, i.e., coffee residues, to clean industrial wastewaters polluted by basic dyes, e.g., Methylene Blue. For the data from the continuous fixed-bed column system, two common models, namely （a） Bohart and Adams and （b） Clark were implemented. The Bohart and Adams capacity was up to N = 46,166 mg.L-1 or q0 = 104.5 mg.g-1 for bed-depth 15 cm, initial dye concentration 800 mg.g-1 and flow rate 20 mL.min-1. The results revealed that the Methylene Blue is fairly adsorbed on coffee residues. Consequently, this process can be applied as a low cost technique for cleaning basic dyes from the aquatic environment.
文摘Bali Tourism Development Corporation＇s lagoon （BTDC lagoon） has been used for treating wastewaters that come from all facilities available in the Nusa Dua Resort tourist area. Reuse of the lagoon effluent is limited for some applications due to salt and suspended solid contents. Application of an integrated membrane system for improving the water quality of the lagoon effluent which is suitable for various uses is under consideration. In this work an ultraflltration （UF） pilot performance for possible pretreatment of Reverse Osmosis （RO） was investigated. The results showed that permeate quality was stable （less than 0.5 NTU）, regardless of concentrating and diluting retentate in each cycle and fouling for a long duration of operation. However, the water quality obtained with this membrane was not enough to be directly used. The permeate quality obtained from the UF system fulfils the requirement for the optimal operation of reverse osmosis. Moreover, appropriate intermittent-backwash operation was fairly effective to maintain the fluxes at a reasonable level.
文摘According to the uncertainties in the results and the wide diversity of how to approach the subject, a new concept for energy is proposed： Energy is an exchange between two different concentrations, the concentration of time in space outside what we call matter and the concentrated phase of time in matter space which is the matter itself. The concept of motion for energy is replaced by time-space interactions with time taken as solid matter. Motion enhances the exchange between the mass and its surrounding time in space, annihilation and creation are special forms of this exchange. During the motion of a mass, it increases as a result of this dissolution. Time concentration in Fock space is responsible for the collision phenomena in physics. In this paper, a new mathematical operator （the equal operator） is introduced.
基金financially supported by the National Natural Science Foundation of China(No.21276086)
文摘The effect of mixed oxide support on the performance of Ni/ZnO in the reactive adsorption desulfurization(RADS) reaction was investigated in a fixed bed reactor by using thiophene as the sulfur-containing compound in the model gasoline. A series of oxide supports for Ni/ZnO were synthesized by the co-precipitation method and characterized by XRD, N_2-adsorption, TPR and NH_3-TPD techniques. It was found that the desulfurization capacity of Ni/ZnO was enhanced greatly when active components were supported on the proper mixed oxide. Ni/ZnO supported on oxides exhibited much higher desulfurization efficiency and sulfur adsorption capacity than the unsupported Ni/ZnO and the synthesized Ni/ZnO-SA adsorbent exhibited the highest efficiency for thiophene removal. The higher desulfurization activity and sulfur capacity of Ni/ZnO supported on SiO_2-Al_2O_3 with small particle size, high specific surface area and large pore volume could promote the high dispersion of active metal phase and the transfer of sulfur to ZnO with lower mass transfer resistance. γ-Al_2O_3 species could weaken the interaction of active phases and SiO_2 as well as could increase greatly the amount of weak acids. Therefore, these oxides could impose a great influence on the structure and chemical properties of the catalyst.
文摘The cases of cholera in Mariupol and adjacent areas which were observed within the period of May-August, 2011 are investigated. Thirty-two diseased and 22 vibriocarriers were found on the territory of the city in the course of epidemic. The potential sources of infection are specified. The ways to avoid similar situations in the future are suggested. The analysis of the locations of the cholera contamination sources results in the obvious conclusion that most of them are connected with the place where the river Kalmius meets the Azov Sea. Waste flow from the residential solid waste landfill brings a considerable harm to the river Kalmius and the Azov Sea.
文摘Rising fuel prices, increasing emission levels and impending environmental regulations made shipping industry to find an alternate for internal combustion engine in 21st century. Fuel cell is a sustainable, emerging technology with negligible pollution. More significantly for a research ship, emission levels need to be substantially low to have quality measurements. A feasibility study is carried-out First time in the world, to drive an ice class multi-disciplinary ORV （Oceanography Research Vessel） Sagarnidbi, using hydrogen powered fuel cell. Sagamidhi is equipped with special equipments viz., Deep Sea winch, specially designed cranes for Launching and retrieval of ROV （Remotely Operable Vehicle）, DSMC （Deep Sea Mining Crawler）, Tsunami systems, manned/unmanned submersible and ACS （Autonomous Coring System） and other facilities that support research in Indian, International and Antarctic waters. Beside this, the propulsion system along with DP （Dynamic Positioning）, centralized air conditioning and special equipments require enormous electrical power. The combustion of diesel oil in an engine, that coupled with an alternator generates electrical power required, along with NOx （Nitrous Oxides）, SOx （Sulphur Oxides） and PM （Particulate Matter） emissions. Shipping industry is the fourth largest contributor to air pollution and carbon emissions, particularly in coastal areas, and the growth rate makes the problem even more critical. Stringent international air pollution regulation and increasing fuel price paves the way for an alternative ＂green emission technology＂. Various fuel cells were analyzed with different combination of fuel, electrolyte and electrodes. From the analysis, it has been found that SOFC （Solid Oxide Fuel Cell） is most suitable for the present scenario. A fuel cell designed with hydrogen as fuel, zirconium oxides stabilized with yttrium oxide as electrolyte and zirconium electrodes is used for 1.5 MW power output and 0.5 MW through regenerator. Volume required for storage of hydrogen is in line with volume of fuel and a high standard safety measures were taken using sensors. The present system saves 3000 MT/annum of diesel oil costing 3,000,000 USD approximately.
文摘Biomass in the form of nutshell, hay of catkin, wheat straw and linseed residue in particles have been pyrolyzed in laboratory scale fixed bed reactor which yielded liquid oil, solid char and gas. The variation of oil yield for different biomass feedstock with reactor bed temperature and feed size is presented in this paper. A maximum liquid yield of 55 wt% of dry feedstock is obtained at an optimum temperature of 500℃ for a feed size of 300-600μm with a running time of 55 min for nutshell as the feedstock while the minimum liquid oil yield is found to be 30 wt% of feedstock at an optimum temperature of 400℃ for a feed size of 2.36 mm with a running time of 65 min for linseed residue as the feedstock. A comparison on the product yields is highlighted in this study. The pyrolysis liquid products are characterized and compared for some of the fuel properties like HHV （higher heating value）, viscosity, density and specific gravity.
