In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect ...In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect of coefficient of spontaneous radiation. Taking three layers CdS/HgS spherical nanometer system as an example, the influence of the electric field and layer-to- layer interaction energy is explored on Stark effect and spectrum. The results show that in the Stark effect system, the energy level is split based on 1, 3, ..., （2n-1）, when it is in the electric field only, similar to the hydrogen atoms; and in the electric field and layer-to-layer interaction, it is split based on 1, 4, ~ -., n2; with the quantum transition, the frequency of the spectrum decreases with the increasing size of the system; apart from a few spectral lines, the intensity of most spectral lines will decreased as the size increases; while the coefficient of spontaneous radiation will increase with the increasing size; the electric field will cause the changes of spectrum frequency; its spectrum frequency shift is proportional to the square of the electric field intensity; apart from a few spectral lines, the frequency shift of spectral lines that is caused by the electric field and layer-to-layer interaction will decrease as the size increases; the interaction will make the level of electronic energy level lower slightly （the order of magnitude is between 10-7-10-9 eV）, the slightly increased spectrum intensity and the slightly increased value of coefficient of spontaneous radiation, but it will not influence the frequency of spectrum, intensity, and the trend that coefficient of spontaneous radiation changes with the size; when the size is smaller, the layer-to-layer interaction effect will be significant.展开更多
萨慕思岛（the island of Samos）位于爱情海东部。它是众神之母赫拉（Hera）神庙的所在地,是提出著名的勾股定律（the Pythagorean theorem）的数学之父毕达哥拉斯（Pythagoras）的故乡。是伟大哲学家伊比鸠鲁（Epicurus）的家乡,是人...萨慕思岛（the island of Samos）位于爱情海东部。它是众神之母赫拉（Hera）神庙的所在地,是提出著名的勾股定律（the Pythagorean theorem）的数学之父毕达哥拉斯（Pythagoras）的故乡。是伟大哲学家伊比鸠鲁（Epicurus）的家乡,是人类历史上第一个提出地球绕太阳公转理论的伟大天文学家阿利斯塔克斯（Aristarchus）的诞生地,是属于《伊索寓言》的作者伊索（Aesop）的小岛。萨慕思（SAMOS）,闪烁着古老历史和高度文明之光,而萨慕思（Samos）出产的高品质美酒将使你亲身感受古老文明的灿烂辉煌!展开更多
The potential （E）-dependent vibrational behavior of a saturated CO adlayer on Au-core Pd-shell nanoparticle film electrodes was investigated over a wide potential range, in acidic, neutral, and basic solutions, usin...The potential （E）-dependent vibrational behavior of a saturated CO adlayer on Au-core Pd-shell nanoparticle film electrodes was investigated over a wide potential range, in acidic, neutral, and basic solutions, using in situ surface-enhanced Raman spectroscopy （SERS）. Over the whole of the examined potential region （-1.5 to 0.55 V vs. NHE）, the peak frequencies of both the C-OM and the Pd-COM band （here, M denotes the multiply-bonded configuration） displayed three distinct linear regions： dvc oM/dE decreased from -185-207 （from -1.5 to -1.2 V） to -83-84 cm-1/V （-1.2 to -0.15 V）, and then to 43 cm-1/V （-0.2 to 0.55 V）; on the other hand, dvpd coM/dE changed from -10 to -8 cm I/V （from -1.5 to -1.2 V） to ^-31 to -30 cm-1/V （-1.2 to -0.15 V）, and then to -15 cm-1/V （-0.2 to 0.55 V）. The simultaneously recorded cyclic voltammograms revealed that at E 〈 -1.2 V, a hydro- gen evolution reaction （HER） occurred. With the help of periodic density functional theory calcula- tions using two different （2 × 2）-3CO slab models with Pd（111）, the unusually high dvc-oM/dE and the small dVPd-CoM/dE in the HER region were explained as being due to the conversion of COad from bridge to hollow sites, which was induced by the co-adsorbed hydrogen atoms formed from dissociated water at negative potentials.展开更多
Preparation of a high flux of hydrogen molecules in a specific vibrationally excited state is the major prerequisite and challenge in scattering experiments that use vibrationally excited hydrogen molecules as the tar...Preparation of a high flux of hydrogen molecules in a specific vibrationally excited state is the major prerequisite and challenge in scattering experiments that use vibrationally excited hydrogen molecules as the target. The widely used scheme of stimulated Raman pumping suffers from coherent population return which severely limits the excitation efficiency. Re- cently we successfully transferred D2 molecules in the molecular beam from （v=0, J=0） to （v=1, J=0） level, with the scheme of Stark-induced adiabatic Raman passage. As high as 75% of the excitation efficiency was achieved. This excitation technique promise to be a unique tool for crossed beam and beam-surface scattering experiments which aim to reveal the role of vibrational excitation of hydrogen molecules in the chemical reaction.展开更多
Myoglobin has important biological functions in storing and transporting small diatomic molecules in human body. Two possible orientations of carbon monoxide （CO） in the heme distal pocket （named as BI and B2 state...Myoglobin has important biological functions in storing and transporting small diatomic molecules in human body. Two possible orientations of carbon monoxide （CO） in the heme distal pocket （named as BI and B2 states） of myoglobin have been experimentally indicated. In this study, ab initio quantum mechanics/molecular mechanics （QM/MM） molecular dynamics simulation of CO in myoglobin was carried out to investigate the two possible B states. Our results demonstrate that the B1 and B2 states correspond to Fe... CO （with carbon atom closer to iron center of heme） and Fe... OC （with oxygen atom closer to Fe）, by comparing with the experimental infrared spectrum. QM electrostatic polarization effect on CO brought from the protein and solvent environment is the main driving force, which anchors CO in two distinctive orientations and hinders its rotation. The calculated vibrational frequency shift between the state B1 and B2 is 13.1 cm-1, which is in good agreement with experimental value of 11.5 cm-1. This study also shows that the electric field produced by the solvent plays an important role in assisting protein functions by exerting directional electric field at the active site of the protein, From residue-based electric field decomposition, several residues were found to have most contributions to the total electric field at the CO center, including a few charged residues and three adjacent uncharged polar residues （namely, HIS64, ILE107, and PHE43）. This study provides new physical insights on rational design of enzyme with higher electric field at the active site.展开更多
The development strategy, focused on the promotion of the efficient and prospective production sectors required for effectively solving social, economic and other problems becomes very important in resource allocation...The development strategy, focused on the promotion of the efficient and prospective production sectors required for effectively solving social, economic and other problems becomes very important in resource allocation decision making process of developing countries. The structural hierarchy, comprising social, economic, technological and environmental aspects, which is involved in the selection of sectors constructed according to the hierarchical system of objectives. The Fuzzy Multi-attribute Decision Making method is used to rank the sectors by indicating the degree to which an alternative satisfies the global objectives of criteria obtained by aggregation operations in fuzzy environment. By applying the developed approach to defining and identifying the key sectors of an economy, we can rank the aggregated 17 sectors of the Tajikistan economy according to their degree of achievement in satisfying key criteria.展开更多
The B-spline expansion technique is applied to study the anticrossings for potassium Rydberg states in a static electric field. The results of our calculation indicate that the antierossings are caused mainly by the c...The B-spline expansion technique is applied to study the anticrossings for potassium Rydberg states in a static electric field. The results of our calculation indicate that the antierossings are caused mainly by the core interaction or by the fine structure interaction. Our results for the positions and the widths of the anticrossings are in good agreement with experimental data.展开更多
We derive a formula for double-pulse spectra from closed-orbit theory. We then calculate the double-pulse photodetachment spectra of H<SUP>?</SUP> in the presence of parallel electric and magnetic fields. ...We derive a formula for double-pulse spectra from closed-orbit theory. We then calculate the double-pulse photodetachment spectra of H<SUP>?</SUP> in the presence of parallel electric and magnetic fields. We analyze the spectra in terms of closed-orbits of the system. We suggest a method for the measurement of a phase associated with each closed-orbit.展开更多
The ground-state and lowest excited-state binding energies of a hydrogenic impurity in GaAs parabolic quantum-well wires （Q WWs） subjected to external electric and magnetic fields are investigated using the finite-d...The ground-state and lowest excited-state binding energies of a hydrogenic impurity in GaAs parabolic quantum-well wires （Q WWs） subjected to external electric and magnetic fields are investigated using the finite-difference method within the quasi-one-dimensional effective potential model. We define an effective radius Pen of a cylindrical QWW, which can describe the strength of the lateral confinement. For the ground state, the position of the largest probability density of electron in x-y plane is located at a point, while for the lowest excited state, is located on a circularity whose radius is Pen. The point and circularity are pushed along the left haft of the center axis of the quantum-well wire by the electric field dire ted along the right half. When an impurity is located at the point or within the circularity, the ground-state or lowest excited-state binding energies are the largest; when the impurity is apart from the point or circularity, the ground-state or lowest excited-state binding energies start to decrease.展开更多
As in the other countries around the world, banking systems in Eurasian economies, comprised of Armenia, Azerbaijan, Georgia, Kazakhstan, the Kyrgyz Republic, Tajikistan, Turkmenistan and Uzbekistan, were adversely af...As in the other countries around the world, banking systems in Eurasian economies, comprised of Armenia, Azerbaijan, Georgia, Kazakhstan, the Kyrgyz Republic, Tajikistan, Turkmenistan and Uzbekistan, were adversely affected by the 2008 global crisis. A common challenge across most economies is to revive private-sector credit growth. Compared with the high increases of 80 percent in the period immediately prior to the crisis, credit growth has slowed sharply and even turned negative in real terms in a number of economies. Governments in many countries have taken measures to address banking sector stress. The measures for restoring credit growth and thus a high economic growth will be discussed in a part of our work. In the short run, such measures include aiding banks to repair balance sheets and also providing liquidity. In the medium term, measures should promote de-dollarization and the development of local debt markets.展开更多
An extended harmonic inversion method is analytically continued to approach bifurcation region of the dosed orbits thus to obtain highly resolved spectra of lithium atom in external field. The suitable band-limited si...An extended harmonic inversion method is analytically continued to approach bifurcation region of the dosed orbits thus to obtain highly resolved spectra of lithium atom in external field. The suitable band-limited signal is generated by a semielassieal uniform approximation. By decimating the selected signal window and solving the algebraic set of nonlinear equations the quantum eigenvalues are properly fitted, which reveal the fine resonance structure hidden in low resolution spectrum. The study is made at the sealed energy ε= -2.7, relevant bifurcation effects and corescattered impacts have to be taken into account. It is demonstrated that the present method is a useful technique for the semiclassieal quantization of system with mixed regular-chaotic classical dynamics.展开更多
The time evolution of the linear entropy of an taking into consideration Stark shift and Kerr-like medium. atom in k-photon daynes-Cummings model is investigated The effect of both the Stark shift and Kerr-like medium...The time evolution of the linear entropy of an taking into consideration Stark shift and Kerr-like medium. atom in k-photon daynes-Cummings model is investigated The effect of both the Stark shift and Kerr-like medium on the linear entropy is analyzed using a numerical technique for the field initially in coherent state and in even coherent state. The results show that the presence of the Kerr-like medium and Stark shift has an important effect on the properties of the entropy and entanglement. It is also shown that the setting of the initial state plays a significant role in the evolution of the linear entropy and entanglement.展开更多
The invention and development of television art is closely connected with scientific research. The historic facts have witnessed the influence of scientific research progress on the development of television art. In t...The invention and development of television art is closely connected with scientific research. The historic facts have witnessed the influence of scientific research progress on the development of television art. In this paper, the author intends to reveal some phenomenal facts which are known by very few people, namely, the first ever appearance of electronic television in Uzbekistan. This paper gives us some authentic and valuable historic materials for the invention and development of television set in the world.展开更多
文摘In the electric field and layer-to-layer interaction energy, the law of split-level of high-level Stark effect of spherical nanometer system is explored as well as the frequency of spectrum, intensity and size effect of coefficient of spontaneous radiation. Taking three layers CdS/HgS spherical nanometer system as an example, the influence of the electric field and layer-to- layer interaction energy is explored on Stark effect and spectrum. The results show that in the Stark effect system, the energy level is split based on 1, 3, ..., （2n-1）, when it is in the electric field only, similar to the hydrogen atoms; and in the electric field and layer-to-layer interaction, it is split based on 1, 4, ~ -., n2; with the quantum transition, the frequency of the spectrum decreases with the increasing size of the system; apart from a few spectral lines, the intensity of most spectral lines will decreased as the size increases; while the coefficient of spontaneous radiation will increase with the increasing size; the electric field will cause the changes of spectrum frequency; its spectrum frequency shift is proportional to the square of the electric field intensity; apart from a few spectral lines, the frequency shift of spectral lines that is caused by the electric field and layer-to-layer interaction will decrease as the size increases; the interaction will make the level of electronic energy level lower slightly （the order of magnitude is between 10-7-10-9 eV）, the slightly increased spectrum intensity and the slightly increased value of coefficient of spontaneous radiation, but it will not influence the frequency of spectrum, intensity, and the trend that coefficient of spontaneous radiation changes with the size; when the size is smaller, the layer-to-layer interaction effect will be significant.
文摘萨慕思岛（the island of Samos）位于爱情海东部。它是众神之母赫拉（Hera）神庙的所在地,是提出著名的勾股定律（the Pythagorean theorem）的数学之父毕达哥拉斯（Pythagoras）的故乡。是伟大哲学家伊比鸠鲁（Epicurus）的家乡,是人类历史上第一个提出地球绕太阳公转理论的伟大天文学家阿利斯塔克斯（Aristarchus）的诞生地,是属于《伊索寓言》的作者伊索（Aesop）的小岛。萨慕思（SAMOS）,闪烁着古老历史和高度文明之光,而萨慕思（Samos）出产的高品质美酒将使你亲身感受古老文明的灿烂辉煌!
基金supported by the National Natural Science Foundation of China(21473175)the National Instrumentation Program(2011YQ03012416)the National Basic Reserarch Program of China(973 Program,2015CB932301)
文摘The potential （E）-dependent vibrational behavior of a saturated CO adlayer on Au-core Pd-shell nanoparticle film electrodes was investigated over a wide potential range, in acidic, neutral, and basic solutions, using in situ surface-enhanced Raman spectroscopy （SERS）. Over the whole of the examined potential region （-1.5 to 0.55 V vs. NHE）, the peak frequencies of both the C-OM and the Pd-COM band （here, M denotes the multiply-bonded configuration） displayed three distinct linear regions： dvc oM/dE decreased from -185-207 （from -1.5 to -1.2 V） to -83-84 cm-1/V （-1.2 to -0.15 V）, and then to 43 cm-1/V （-0.2 to 0.55 V）; on the other hand, dvpd coM/dE changed from -10 to -8 cm I/V （from -1.5 to -1.2 V） to ^-31 to -30 cm-1/V （-1.2 to -0.15 V）, and then to -15 cm-1/V （-0.2 to 0.55 V）. The simultaneously recorded cyclic voltammograms revealed that at E 〈 -1.2 V, a hydro- gen evolution reaction （HER） occurred. With the help of periodic density functional theory calcula- tions using two different （2 × 2）-3CO slab models with Pd（111）, the unusually high dvc-oM/dE and the small dVPd-CoM/dE in the HER region were explained as being due to the conversion of COad from bridge to hollow sites, which was induced by the co-adsorbed hydrogen atoms formed from dissociated water at negative potentials.
文摘Preparation of a high flux of hydrogen molecules in a specific vibrationally excited state is the major prerequisite and challenge in scattering experiments that use vibrationally excited hydrogen molecules as the target. The widely used scheme of stimulated Raman pumping suffers from coherent population return which severely limits the excitation efficiency. Re- cently we successfully transferred D2 molecules in the molecular beam from （v=0, J=0） to （v=1, J=0） level, with the scheme of Stark-induced adiabatic Raman passage. As high as 75% of the excitation efficiency was achieved. This excitation technique promise to be a unique tool for crossed beam and beam-surface scattering experiments which aim to reveal the role of vibrational excitation of hydrogen molecules in the chemical reaction.
文摘Myoglobin has important biological functions in storing and transporting small diatomic molecules in human body. Two possible orientations of carbon monoxide （CO） in the heme distal pocket （named as BI and B2 states） of myoglobin have been experimentally indicated. In this study, ab initio quantum mechanics/molecular mechanics （QM/MM） molecular dynamics simulation of CO in myoglobin was carried out to investigate the two possible B states. Our results demonstrate that the B1 and B2 states correspond to Fe... CO （with carbon atom closer to iron center of heme） and Fe... OC （with oxygen atom closer to Fe）, by comparing with the experimental infrared spectrum. QM electrostatic polarization effect on CO brought from the protein and solvent environment is the main driving force, which anchors CO in two distinctive orientations and hinders its rotation. The calculated vibrational frequency shift between the state B1 and B2 is 13.1 cm-1, which is in good agreement with experimental value of 11.5 cm-1. This study also shows that the electric field produced by the solvent plays an important role in assisting protein functions by exerting directional electric field at the active site of the protein, From residue-based electric field decomposition, several residues were found to have most contributions to the total electric field at the CO center, including a few charged residues and three adjacent uncharged polar residues （namely, HIS64, ILE107, and PHE43）. This study provides new physical insights on rational design of enzyme with higher electric field at the active site.
文摘The development strategy, focused on the promotion of the efficient and prospective production sectors required for effectively solving social, economic and other problems becomes very important in resource allocation decision making process of developing countries. The structural hierarchy, comprising social, economic, technological and environmental aspects, which is involved in the selection of sectors constructed according to the hierarchical system of objectives. The Fuzzy Multi-attribute Decision Making method is used to rank the sectors by indicating the degree to which an alternative satisfies the global objectives of criteria obtained by aggregation operations in fuzzy environment. By applying the developed approach to defining and identifying the key sectors of an economy, we can rank the aggregated 17 sectors of the Tajikistan economy according to their degree of achievement in satisfying key criteria.
基金The project supported by National Natural Science Foundation of China under Grant No. 10274063 and the Foundation of Science and Technology Research of the Ministry of Education of China under Grant No. 03126
文摘The B-spline expansion technique is applied to study the anticrossings for potassium Rydberg states in a static electric field. The results of our calculation indicate that the antierossings are caused mainly by the core interaction or by the fine structure interaction. Our results for the positions and the widths of the anticrossings are in good agreement with experimental data.
文摘We derive a formula for double-pulse spectra from closed-orbit theory. We then calculate the double-pulse photodetachment spectra of H<SUP>?</SUP> in the presence of parallel electric and magnetic fields. We analyze the spectra in terms of closed-orbits of the system. We suggest a method for the measurement of a phase associated with each closed-orbit.
文摘The ground-state and lowest excited-state binding energies of a hydrogenic impurity in GaAs parabolic quantum-well wires （Q WWs） subjected to external electric and magnetic fields are investigated using the finite-difference method within the quasi-one-dimensional effective potential model. We define an effective radius Pen of a cylindrical QWW, which can describe the strength of the lateral confinement. For the ground state, the position of the largest probability density of electron in x-y plane is located at a point, while for the lowest excited state, is located on a circularity whose radius is Pen. The point and circularity are pushed along the left haft of the center axis of the quantum-well wire by the electric field dire ted along the right half. When an impurity is located at the point or within the circularity, the ground-state or lowest excited-state binding energies are the largest; when the impurity is apart from the point or circularity, the ground-state or lowest excited-state binding energies start to decrease.
文摘As in the other countries around the world, banking systems in Eurasian economies, comprised of Armenia, Azerbaijan, Georgia, Kazakhstan, the Kyrgyz Republic, Tajikistan, Turkmenistan and Uzbekistan, were adversely affected by the 2008 global crisis. A common challenge across most economies is to revive private-sector credit growth. Compared with the high increases of 80 percent in the period immediately prior to the crisis, credit growth has slowed sharply and even turned negative in real terms in a number of economies. Governments in many countries have taken measures to address banking sector stress. The measures for restoring credit growth and thus a high economic growth will be discussed in a part of our work. In the short run, such measures include aiding banks to repair balance sheets and also providing liquidity. In the medium term, measures should promote de-dollarization and the development of local debt markets.
基金The project supported by National Natural Science Foundation of China under Grant Nos.10774093 and 10374061
文摘An extended harmonic inversion method is analytically continued to approach bifurcation region of the dosed orbits thus to obtain highly resolved spectra of lithium atom in external field. The suitable band-limited signal is generated by a semielassieal uniform approximation. By decimating the selected signal window and solving the algebraic set of nonlinear equations the quantum eigenvalues are properly fitted, which reveal the fine resonance structure hidden in low resolution spectrum. The study is made at the sealed energy ε= -2.7, relevant bifurcation effects and corescattered impacts have to be taken into account. It is demonstrated that the present method is a useful technique for the semiclassieal quantization of system with mixed regular-chaotic classical dynamics.
基金Supported by the National Natural Science Foundation of China under Grant Nos. 10674038, 10604042National Basic Research Program of China under Grant No. 2006CB302901
文摘The time evolution of the linear entropy of an taking into consideration Stark shift and Kerr-like medium. atom in k-photon daynes-Cummings model is investigated The effect of both the Stark shift and Kerr-like medium on the linear entropy is analyzed using a numerical technique for the field initially in coherent state and in even coherent state. The results show that the presence of the Kerr-like medium and Stark shift has an important effect on the properties of the entropy and entanglement. It is also shown that the setting of the initial state plays a significant role in the evolution of the linear entropy and entanglement.
文摘The invention and development of television art is closely connected with scientific research. The historic facts have witnessed the influence of scientific research progress on the development of television art. In this paper, the author intends to reveal some phenomenal facts which are known by very few people, namely, the first ever appearance of electronic television in Uzbekistan. This paper gives us some authentic and valuable historic materials for the invention and development of television set in the world.
