Traditional Chinese architecture in the narrative of a system has existed more than 3,000 years. As the core values of the enlightenment function of social ethics, traditional architecture externalizes symbol of ＂st...Traditional Chinese architecture in the narrative of a system has existed more than 3,000 years. As the core values of the enlightenment function of social ethics, traditional architecture externalizes symbol of ＂state＂ sensual ethical echo. So metaphorical rules in architecture can combine with the normal life. Traditional architectural form as famous communication home Marshall McLuhan＇s ＂human extension＂, leads the order and the rules in the form of elevation. The spread of universal ethics, traditional architectural symmetry axis ceremony, and the adornment of the mythical thinking component, are traditional Chinese ethics of society to describe the core of creation through three points sequence structure constraint. The wisdom of metaphor in these ideas is the life gene of Chinese culture. In the construction of the contemporary social upheaval spreading vision, recognition of traditional architecture ethics through righteousness obviously has been recasting social ethics of ＂treatment＂.展开更多
A synthetic method for a new unsymmetrical Schiff base and its Ln(Ⅲ)complexes including multi > C = N — groups is reported. The complexes are characterized byelemental analysis, IR spectra, ~1H and ^(13)C NMR, es...A synthetic method for a new unsymmetrical Schiff base and its Ln(Ⅲ)complexes including multi > C = N — groups is reported. The complexes are characterized byelemental analysis, IR spectra, ~1H and ^(13)C NMR, especially 2D-COSY ~1H, ~1H NMR spectra. Thegeneral formula of the obtained complexes is [Ln_3(TBLY)(NO_3)_3] · nH_2O (Ln = La, n = 3; Ln = Nd,n=5; Ln = Gd, Dy, Yb, Y, n = 7), where TBLY = tetraglycol aldehyde-2,4-dihydroxy benzaldehydebis-lysine Schiff base. In addition, the evidence for existence of > C = CH — NH — group issupported by the AM1 method. The complexes obtained may be used as a catalyst. Conversion rate of80% with the viscosity-average molecular weight 220000 for the polymerization of methyl methacrylate(MMA) without addition of any cocatalyst has been obtained.展开更多
文摘Traditional Chinese architecture in the narrative of a system has existed more than 3,000 years. As the core values of the enlightenment function of social ethics, traditional architecture externalizes symbol of ＂state＂ sensual ethical echo. So metaphorical rules in architecture can combine with the normal life. Traditional architectural form as famous communication home Marshall McLuhan＇s ＂human extension＂, leads the order and the rules in the form of elevation. The spread of universal ethics, traditional architectural symmetry axis ceremony, and the adornment of the mythical thinking component, are traditional Chinese ethics of society to describe the core of creation through three points sequence structure constraint. The wisdom of metaphor in these ideas is the life gene of Chinese culture. In the construction of the contemporary social upheaval spreading vision, recognition of traditional architecture ethics through righteousness obviously has been recasting social ethics of ＂treatment＂.
基金This work was supported by the National Natural Science Foundation of China (Grant No. 29671026) Natural Science Foundation of Zhejiang Province (Grant No. 296062) and the Laboratory of MRAMP (Grant No. 971502). References
文摘A synthetic method for a new unsymmetrical Schiff base and its Ln(Ⅲ)complexes including multi > C = N — groups is reported. The complexes are characterized byelemental analysis, IR spectra, ~1H and ^(13)C NMR, especially 2D-COSY ~1H, ~1H NMR spectra. Thegeneral formula of the obtained complexes is [Ln_3(TBLY)(NO_3)_3] · nH_2O (Ln = La, n = 3; Ln = Nd,n=5; Ln = Gd, Dy, Yb, Y, n = 7), where TBLY = tetraglycol aldehyde-2,4-dihydroxy benzaldehydebis-lysine Schiff base. In addition, the evidence for existence of > C = CH — NH — group issupported by the AM1 method. The complexes obtained may be used as a catalyst. Conversion rate of80% with the viscosity-average molecular weight 220000 for the polymerization of methyl methacrylate(MMA) without addition of any cocatalyst has been obtained.
