Moleculardeviceswith highswitchingperformance and/or the perfect spin filtering effect have always been the pursuit with the development of molecular electronics.Hereb,yusingthe 2001.0V nonequilibrium.Green's func...Moleculardeviceswith highswitchingperformance and/or the perfect spin filtering effect have always been the pursuit with the development of molecular electronics.Hereb,yusingthe 2001.0V nonequilibrium.Green's function method in combination with the density functionaltheory,the switching performance and spin filtering properties of dimethyldihydropyrene(DHP)/cyclophanediene(CPD)photoswitchable molecule connected by carbon atomic chains(CACs)to two zigzag graphene nanoribbon electrodes have been theoretically investigated.The results show that DHP is more conductive than CPD and therefore an evident switching effect is demonstrated,and the switching ratio(RON/OFF)can reach 4.5×103.It is further revealed that the RoON/OF of DHP/CPD closely depends on the length of CACs.More specifically,the RoN/OFF values of DHP/CPD with odd-numbered CACs are larger than those with even-numbered CACs.More interestingly,a high or even perfect spin filtering effect can be obtained in these investigated DHP/CPD single-molecule devices.Our study is helpful for future design of single-molecule switches and spin filters and provides a way to optimize their performance by means of varying the length of bridging CACs.展开更多
This study was conducted to investigate the distribution and accumulation of major elements of 5-year-old Eucalyptus grandis forests with the densities of 556 trees/hm2 and 1 667 trees/hm2. The results showed that： ...This study was conducted to investigate the distribution and accumulation of major elements of 5-year-old Eucalyptus grandis forests with the densities of 556 trees/hm2 and 1 667 trees/hm2. The results showed that： （1） The distribution of ma- jor nutrient element contents in various organs of the E. grandis with the 2 densi- ties was nearly the same, and the ranked order was leaf〉tree trunk〉branch or branchlet〉fruit〉bark. （2） From the distribution of nutrient elements and organic mat- ter in the trunk, P, K, Mg and Ca contents presented basically a trend of increasing with the trunk height increasing. And the organic matter content increased with the trunk height increasing in the low density stand, while the result was opposite in the high density stand. Furthermore, N content increased with the trunk height increas- ing in the low density stand, but the content in the high density stand exhibited a trend of decreasing at first, increasing then and increasing at the last. （3） From the distribution of biomass, the ranked order was tree trunk〉bark or branch〉branchlet〉 leaf〉fruit. And （4） The accumulated amounts of major nutrient elements in various organs under the 2 stand densities was nearly same. Ca content was the highest in the 2 kinds of plantations, followed by N, K, Mg and P contents. Ca content was 601.78 kg/hm2 in the low density stand and 1 204. 43 kg/hm2 in the high density stand.展开更多
Radial variation in sap flux density (SFD) as a function of sapwood thickness is of importance in accurately estimating sap flux through sapwood area which, in turn, decides the precision of heat pulse application. Ho...Radial variation in sap flux density (SFD) as a function of sapwood thickness is of importance in accurately estimating sap flux through sapwood area which, in turn, decides the precision of heat pulse application. However, until now, only a few studies have evaluated the magnitude and significance of sampling errors associated with radial gradients in SFD, which were based on the small monitoring measurement data from a few trees. Based on one year of heat pulse observation of two 3 - 4 years old Eucalyptus urophylla S. T.,P Blake plantations in Leizhou Peninsula, Guangdong Province, China, a way of data processing was developed to treat with the lots of SFD data measured from 39 trees. It was found that the radial variation in SFD as a function of sapwood thickness in the two eucalyptus plantation sites could be expressed as y = 3. 667 5x(3) - 7.295 5x(2) + 3.682 6x + 0. 567 4 (R-2 = 0. 939 1, n = 80, P = 0.01), where y is the ratio of SFD of a sensor to the average of four data in different depths, x is the ratio of a sensor depth to tire radial sapwood thickness. It was the same (as in the following equation) in Jijia site, y = 5.006 2x(3) - 9.116 1x(2) + 4. 454 4x + 0.463 4 (R-2 = 0. 806 9, n = 72, P = 0.01) in Hetou site. From cambium to heartwood, SFD showed some increases at first and then decreases continuously. However, because die trees were very young, the maximum SFD was only 0. 33 - 0. 36 times more than the minimum.展开更多
基金This work is supported by the National Natural Sci-ence Foundation China(No.22173052 of and No.11974217).
文摘Moleculardeviceswith highswitchingperformance and/or the perfect spin filtering effect have always been the pursuit with the development of molecular electronics.Hereb,yusingthe 2001.0V nonequilibrium.Green's function method in combination with the density functionaltheory,the switching performance and spin filtering properties of dimethyldihydropyrene(DHP)/cyclophanediene(CPD)photoswitchable molecule connected by carbon atomic chains(CACs)to two zigzag graphene nanoribbon electrodes have been theoretically investigated.The results show that DHP is more conductive than CPD and therefore an evident switching effect is demonstrated,and the switching ratio(RON/OFF)can reach 4.5×103.It is further revealed that the RoON/OF of DHP/CPD closely depends on the length of CACs.More specifically,the RoN/OFF values of DHP/CPD with odd-numbered CACs are larger than those with even-numbered CACs.More interestingly,a high or even perfect spin filtering effect can be obtained in these investigated DHP/CPD single-molecule devices.Our study is helpful for future design of single-molecule switches and spin filters and provides a way to optimize their performance by means of varying the length of bridging CACs.
基金Supported by Sichuan Science and Technology Plan Project(2014NZ0033)~~
文摘This study was conducted to investigate the distribution and accumulation of major elements of 5-year-old Eucalyptus grandis forests with the densities of 556 trees/hm2 and 1 667 trees/hm2. The results showed that： （1） The distribution of ma- jor nutrient element contents in various organs of the E. grandis with the 2 densi- ties was nearly the same, and the ranked order was leaf〉tree trunk〉branch or branchlet〉fruit〉bark. （2） From the distribution of nutrient elements and organic mat- ter in the trunk, P, K, Mg and Ca contents presented basically a trend of increasing with the trunk height increasing. And the organic matter content increased with the trunk height increasing in the low density stand, while the result was opposite in the high density stand. Furthermore, N content increased with the trunk height increas- ing in the low density stand, but the content in the high density stand exhibited a trend of decreasing at first, increasing then and increasing at the last. （3） From the distribution of biomass, the ranked order was tree trunk〉bark or branch〉branchlet〉 leaf〉fruit. And （4） The accumulated amounts of major nutrient elements in various organs under the 2 stand densities was nearly same. Ca content was the highest in the 2 kinds of plantations, followed by N, K, Mg and P contents. Ca content was 601.78 kg/hm2 in the low density stand and 1 204. 43 kg/hm2 in the high density stand.
文摘Radial variation in sap flux density (SFD) as a function of sapwood thickness is of importance in accurately estimating sap flux through sapwood area which, in turn, decides the precision of heat pulse application. However, until now, only a few studies have evaluated the magnitude and significance of sampling errors associated with radial gradients in SFD, which were based on the small monitoring measurement data from a few trees. Based on one year of heat pulse observation of two 3 - 4 years old Eucalyptus urophylla S. T.,P Blake plantations in Leizhou Peninsula, Guangdong Province, China, a way of data processing was developed to treat with the lots of SFD data measured from 39 trees. It was found that the radial variation in SFD as a function of sapwood thickness in the two eucalyptus plantation sites could be expressed as y = 3. 667 5x(3) - 7.295 5x(2) + 3.682 6x + 0. 567 4 (R-2 = 0. 939 1, n = 80, P = 0.01), where y is the ratio of SFD of a sensor to the average of four data in different depths, x is the ratio of a sensor depth to tire radial sapwood thickness. It was the same (as in the following equation) in Jijia site, y = 5.006 2x(3) - 9.116 1x(2) + 4. 454 4x + 0.463 4 (R-2 = 0. 806 9, n = 72, P = 0.01) in Hetou site. From cambium to heartwood, SFD showed some increases at first and then decreases continuously. However, because die trees were very young, the maximum SFD was only 0. 33 - 0. 36 times more than the minimum.
