In order to obtain and master the surface thermal deformation of paraboloid antennas,a fast iterative closest point( FICP) algorithm based on design coordinate guidance is proposed,which can satisfy the demands of rap...In order to obtain and master the surface thermal deformation of paraboloid antennas,a fast iterative closest point( FICP) algorithm based on design coordinate guidance is proposed,which can satisfy the demands of rapid detection for surface thermal deformation. Firstly,the basic principle of the ICP algorithm for registration of a free surface is given,and the shortcomings of the ICP algorithm in the registration of surface are analysed,such as its complex computation,long calculation time,low efficiency,and relatively strict initial registration position. Then an improved FICP algorithm based on design coordinate guidance is proposed. Finally,the FICP algorithm is applied to the fast registration test for the surface thermal deformation of a paraboloid antenna. Results indicate that the approach offers better performance with regard to fast surface registration and the algorithm is more simple,efficient,and easily realized in practical engineering application.展开更多
Mesoporous CeO2 was first synthesized by hydrothermal method,and then used to synthesize different contents of CuO)x/CeO2(x:molar ratio of Cu to Ce) by deposition-precipitation method.These materials were characterize...Mesoporous CeO2 was first synthesized by hydrothermal method,and then used to synthesize different contents of CuO)x/CeO2(x:molar ratio of Cu to Ce) by deposition-precipitation method.These materials were characterized by X-ray diffraction(XRD),N2 adsorption and desorption,H2 temperature programmed reduction(H2-TPR) and O2 temperature programmed desorption(O2-TPD) to study the crystal structure,surface area,and the mechanism of CO oxidation.The results show that,on XRD patterns,no evidence of CuO diffraction peaks is present until Cu loading is increased to 20%.The BET surface area decreases noticeably with the increase of Cu content.Compared with other samples,the better reducibility and activity oxygen species of(CuO)10%/CeO2coincide with its better catalytic activity.展开更多
The Gaussian mixture model (GMM), k-nearest neighbor (k-NN), quadratic discriminant analysis (QDA), and linear discriminant analysis (LDA) were compared to classify wrist motions using surface electromyogram (EMG). Ef...The Gaussian mixture model (GMM), k-nearest neighbor (k-NN), quadratic discriminant analysis (QDA), and linear discriminant analysis (LDA) were compared to classify wrist motions using surface electromyogram (EMG). Effect of feature selection in EMG signal processing was also verified by comparing classification accuracy of each feature, and the enhancement of classification accuracy by normalization was confirmed. EMG signals were acquired from two electrodes placed on the forearm of twenty eight healthy subjects and used for recognition of wrist motion. Features were extracted from the obtained EMG signals in the time domain and were applied to classification methods. The difference absolute mean value (DAMV), difference absolute standard deviation value (DASDV), mean absolute value (MAV), root mean square (RMS) were used for composing 16 double features which were combined of two channels. In the classification methods, the highest accuracy of classification showed in the GMM. The most effective combination of classification method and double feature was (MAV, DAMV) of GMM and its classification accuracy was 96.85%. The results of normalization were better than those of non-normalization in GMM, k-NN, and LDA.展开更多
The free surface flow generated by twin-cylinders in forced motion submerged beneath the free surface is studied based on the boundary element method. Two relative locations, namely, horizontal and vertical, are exami...The free surface flow generated by twin-cylinders in forced motion submerged beneath the free surface is studied based on the boundary element method. Two relative locations, namely, horizontal and vertical, are examined for the twin cylinders. In both cases, the twin cylinders are starting from rest and ultimately moving with the same constant speed through an accelerating process. Assuming that the fluid is inviscid and incompressible and the flow to be irrotational, the integral Laplace equation can be discretized based on the boundary element method. Fully-nonlinear boundary conditions are satisfied on the unknown free surface and the moving body surface. The free surface is traced by a Lagrangian technique. Regriding and remeshing are applied, which is crucial to quality of the numerical results. Single circular cylinder and elliptical cylinder are calculated by linear method and fully nonlinear method for accuracy checking and then fully nonlinear method is conducted on the twin cylinder cases, respectively. The generated wave elevation and the resultant force are analysed to discuss the influence of the gap between the two cylinders as well as the water depth. It is found that no matter the kind of distribution, when the moving cylinders are close to each other, they suffer hydrodynamic force with large absolute value in the direction of motion. The trend of force varying with the increase of gap can be clearly seen from numerical analysis. The vertically distributed twin cylinders seem to attract with each other while the horizontally distributed twin cylinders are opposite when they are close to each other.展开更多
The sea surface temperature (SST) in the In- dian Ocean affects the regional climate over the Asian continent mostly through a modulation of the monsoon system. It is still difficult to provide an a priori indicatio...The sea surface temperature (SST) in the In- dian Ocean affects the regional climate over the Asian continent mostly through a modulation of the monsoon system. It is still difficult to provide an a priori indication of the seasonal variability over the Indian Ocean. It is widely recognized that the warm and cold events of SST over the tropical Indian Ocean are strongly linked to those of the equatorial eastern Pacific. In this study, a statistical prediction model has been developed to predict the monthly SST over the tropical Indian Ocean. This model is a linear regression model based on the lag relationship between the SST over the tropical Indian Ocean and the Nino3.4 (5°S-5°N, 170°W-120°W) SST Index. The pre- dictor (i.e., Nino3.4 SST Index) has been operationally predicted by a large size ensemble E1 Nifio and the Southern Oscillation (ENSO) forecast system with cou- pled data assimilation (Leefs_CDA), which achieves a high predictive skill of up to a 24-month lead time for the equatorial eastern Pacific SST. As a result, the prediction skill of the present statistical model over the tropical In- dian Ocean is better than that of persistence prediction for January 1982 through December 2009.展开更多
The surface and interface electronic states of tris (8 hydroxyquinoline) aluminum (Alq 3)/indium tin oxide (ITO) were measured and analyzed by X ray photoelectron spectroscopy (XPS). The results indicated that, in Alq...The surface and interface electronic states of tris (8 hydroxyquinoline) aluminum (Alq 3)/indium tin oxide (ITO) were measured and analyzed by X ray photoelectron spectroscopy (XPS). The results indicated that, in Alq 3 molecule, the binding energy ( E b) of Al atoms is 70.7 eV and 75.1 eV, corresponding to Al(O) and Al(Ⅲ), respectively; The binding energy of C is 285.8 eV, 286.3 eV, and 286.8 eV, corresponding to C of C-C group, C-O, and C-N bond, respectively. N is the main peak locating at 401.0 eV, corresponding to N atom of C-N=C. O atoms mainly bond to H atom, with the binding energy of 533.2 eV. As the sputtering time of Ar + ion beam increases, Al 2p , C 1s , N 1s , O 1s , In 3d 5/2 and Sn 3d 5/2 peaks slightly shift towards lower binding energy, and Al 2p , C 1s and N 1s peaks get weaker, which contributes to diffusing the oxygen, indium and tin in ITO into Alq 3 layer.展开更多
The target products were prepared by homogeneous precipitation method using SDS and PEG 800, respectively, as surfactant at a reaction temperature of 95 ℃ for 3 h, followed by calcination at 400 ~C for 3 h. The sampl...The target products were prepared by homogeneous precipitation method using SDS and PEG 800, respectively, as surfactant at a reaction temperature of 95 ℃ for 3 h, followed by calcination at 400 ~C for 3 h. The samples were charac- terized and analyzed by XRD, SEM, FTIR and zeta potential measurements. The products were modified with different sur- factants to improve their dispersion stability, both the amount and the best zeta potential values of which were identified in this work. The surface-modified nano-particles were added at a mass fraction of 1.0%, 2.0%, 3.0%, and 4.0%, respectively, into the base oil. It was showed that the additive in base oil has good oil solubility without detectable corrosion of copper stripe, and had excellent behavior in terms of anti-wear performance and lower friction coefficient.展开更多
A simple approach has been developed to functionalize various substrates, such as gold and polyvinylchloride, with dopamine methacrylamide—a molecule with adhesive properties that mimic those of mussels—to produce a...A simple approach has been developed to functionalize various substrates, such as gold and polyvinylchloride, with dopamine methacrylamide—a molecule with adhesive properties that mimic those of mussels—to produce a versatile and general platform for subsequent surface modification. With active double bonds on the surface, various polymers, such as poly([2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) ammonium hydroxide(PMEDSAH) and poly(N-vinylpyrrolidone)(PVP), can be grafted by conventional radical polymerization. Double bond surface functionalization and subsequent polymer grafting have been verified by static water contact angle, Fourier transform infrared–attenuated total reflectance(FTIR-ATR) spectroscopy and X-ray photoelectron spectroscopy(XPS) measurements. Protein adsorption assays showed that the polymermodified substrates have good protein-resistant properties. Considering the advantages of facility, versatility and substrate- independence, this method should be useful in designing functional interfaces for bioengineering applications.展开更多
YMn2O5nanorods were synthesized through a modified polyacrylamide gel route.The synthesis strategy in this work is based on a sol-gel process using a polyacrylamide gel method in which oxalic acid,citric acid or tarta...YMn2O5nanorods were synthesized through a modified polyacrylamide gel route.The synthesis strategy in this work is based on a sol-gel process using a polyacrylamide gel method in which oxalic acid,citric acid or tartaric acid is employed as the chelating agent.In the gel routes,oxalic acid was used as a carboxyl chelating agent,while citric acid or tartaric acid was a carboxyl and hydroxyl chelating agent.The as-prepared samples were characterized by means of techniques such as X-ray powder diffraction(XRD)measurement,thermogravimetric analysis(TG),differential scanning calorimetry analysis(DSC),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),thermal expansion measurement and field-emission scanning electron microscopy(SEM)investigations.It was found that oxalic acid is the best chelating agent with Y(NO3)3·6H2O and Mn(CH3COO)2·4H2O as precursors to prepare a single orthorhombic YMn2O5nanorods at 1000°C.Scanning electron microscope observation shows that the morphology of YMn2O5powders is significantly dependent on the chelating agent.The peaks(single orthorhombic YMn2O5nanorods)at 642,600,573,546,521,493,486,468,448 and 400cm?1were observed from FTIR spectra.The phase,surface morphology and chelation mechanisms of YMn2O5samples have been discussed on the basis of the experimental results.展开更多
Due to the property of water repellence, biomimetic superhydrophobic surfaces have been widely applied to green technologies, in turn inducing wider and deeper investigations on superhydrophobic surfaces. Theoretical,...Due to the property of water repellence, biomimetic superhydrophobic surfaces have been widely applied to green technologies, in turn inducing wider and deeper investigations on superhydrophobic surfaces. Theoretical, experimental and numerical studies on wetting transitions have been carried out by researchers, but the mechanism of wetting transitions between Cassie-Baxter state and Wenzel state, which is crucial to develop a stable superhydrophobic surface, is still not fully understood. In this paper, the flee energy curves based on the transition processes are presented and discussed in detail. The exis- tence of energy barriers with or without consideration of the gravity effect, and the irreversibility of wet- ting transition are discussed based on the presented energy curves. The energy curves show that different routes of the Cassie-to-Wenzel transition and the reverse transition are the main reason for the irre- versibility. Numerical simulations are implemented via a phase field lattice Boltzmann method of large density ratio, and the simulation results show good consistency with the theoretical analysis.展开更多
The oxidation characteristics of boron particles, boron-A with the diameter of 2.545 μm and boron-B with the diameter of 10.638 μm, at low temperature(1500 K) have been investigated by thermogravimetry(TG) coupl...The oxidation characteristics of boron particles, boron-A with the diameter of 2.545 μm and boron-B with the diameter of 10.638 μm, at low temperature(1500 K) have been investigated by thermogravimetry(TG) coupled with simultaneous differential scanning calorimetry(DSC), infrared and mass spectra. A rapid oxidation stage of boron particles, followed by a slow oxidation stage of sintered particles, is found from the TG and DSC curves. The onset temperatures of the oxidation process of boron-A particles are in the range of 806–889 K, which are at least 105 K lower than those of boron-B at the same condition. As the partial pressure of oxygen increases from 5% to 35%, the onset temperature of boron-A or boron-B particles decreases. However, when the partial pressure of oxygen is above 35%, the onset temperature becomes constant, implying a saturation effect of oxygen on the reaction rate. It indicates that the chemical adsorption of oxygen, i.e. chemical reaction, on the particle surface is the rate-limited step at the beginning of the rapid oxidation stage. Therefore, the first-order chemical reaction model is used to simulate the oxidation of boron particles, even that of the sinter. The average activation energies of the particles are 291.3 kJ/mol for boron-A and 338.4 k J/mol for boron-B. While the average activation energies of the sintered particles are 36.35 k J/mol for boron-A and 31.87 kJ/mol for boron-B. The pre-exponential factor of the particles is -10^4, while that of the sinter is 10^-1. The oxidation rate constant of boron is qualitatively mainly affected by the specific surface of the sample and the thickness of the oxide layer.展开更多
The interaction of three conormal waves for semi-linear strictly hyperbolic equations of third order is considered. Let Σi, i = 1, 2, 3, be smooth characteristic surfaces for P= Da(D_t ̄2 -△) intersecting transversa...The interaction of three conormal waves for semi-linear strictly hyperbolic equations of third order is considered. Let Σi, i = 1, 2, 3, be smooth characteristic surfaces for P= Da(D_t ̄2 -△) intersecting transversally at the origin. Suppose that the solution u to Pu = f(t, x ,y)D u), ≤2 is conormal to Σi, i = 1, 2, 3, for t < 0. The author uses Bony's second microlocajization techniques and commutator arguments to conclude that the new singularities a short time after the triple interaction lie on the surface of the light cone Γ over the origin plus the surfaces obtained by flow-outs of the lines of intersection Γ ∩ Σi and Σi∩ Σj, i, j = 1, 2, 3.展开更多
基金Supported by the National Natural Science Foundation of China(No.51474217,41501562)the Open Fund Program of Henan Engineering Laboratory of Pollution Control and Coal Chemical Resources Comprehensive Utilization(No.502002-B07,502002-A04)
文摘In order to obtain and master the surface thermal deformation of paraboloid antennas,a fast iterative closest point( FICP) algorithm based on design coordinate guidance is proposed,which can satisfy the demands of rapid detection for surface thermal deformation. Firstly,the basic principle of the ICP algorithm for registration of a free surface is given,and the shortcomings of the ICP algorithm in the registration of surface are analysed,such as its complex computation,long calculation time,low efficiency,and relatively strict initial registration position. Then an improved FICP algorithm based on design coordinate guidance is proposed. Finally,the FICP algorithm is applied to the fast registration test for the surface thermal deformation of a paraboloid antenna. Results indicate that the approach offers better performance with regard to fast surface registration and the algorithm is more simple,efficient,and easily realized in practical engineering application.
基金Project(2011FZ030)supported by the Natural Science Foundation of Yunnan Province,ChinaProjects(2011144,2011221)supported by Analysis and Test Foundation of Kunming University of Science and Technology,China
文摘Mesoporous CeO2 was first synthesized by hydrothermal method,and then used to synthesize different contents of CuO)x/CeO2(x:molar ratio of Cu to Ce) by deposition-precipitation method.These materials were characterized by X-ray diffraction(XRD),N2 adsorption and desorption,H2 temperature programmed reduction(H2-TPR) and O2 temperature programmed desorption(O2-TPD) to study the crystal structure,surface area,and the mechanism of CO oxidation.The results show that,on XRD patterns,no evidence of CuO diffraction peaks is present until Cu loading is increased to 20%.The BET surface area decreases noticeably with the increase of Cu content.Compared with other samples,the better reducibility and activity oxygen species of(CuO)10%/CeO2coincide with its better catalytic activity.
基金Project(NIPA-2012-H0401-12-1007) supported by the MKE(The Ministry of Knowledge Economy), Korea, supervised by the NIPAProject(2010-0020163) supported by Key Research Institute Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology, Korea
文摘The Gaussian mixture model (GMM), k-nearest neighbor (k-NN), quadratic discriminant analysis (QDA), and linear discriminant analysis (LDA) were compared to classify wrist motions using surface electromyogram (EMG). Effect of feature selection in EMG signal processing was also verified by comparing classification accuracy of each feature, and the enhancement of classification accuracy by normalization was confirmed. EMG signals were acquired from two electrodes placed on the forearm of twenty eight healthy subjects and used for recognition of wrist motion. Features were extracted from the obtained EMG signals in the time domain and were applied to classification methods. The difference absolute mean value (DAMV), difference absolute standard deviation value (DASDV), mean absolute value (MAV), root mean square (RMS) were used for composing 16 double features which were combined of two channels. In the classification methods, the highest accuracy of classification showed in the GMM. The most effective combination of classification method and double feature was (MAV, DAMV) of GMM and its classification accuracy was 96.85%. The results of normalization were better than those of non-normalization in GMM, k-NN, and LDA.
基金Foundation item: Supported by the Lloyd's Register Foundation, the Fundamental Research Funds for the Central Universities (Gram No. HEUCF140115), the National Natural Science Foundation of China (11102048, 11302057), the Research Funds for State Key Laboratory of Ocean Engineering in Shanghai Jiao Tong University (Grant No. 1310), and the Specialized Research Fund for the Doctoral Program of Higher Education of China (20132304120028).
文摘The free surface flow generated by twin-cylinders in forced motion submerged beneath the free surface is studied based on the boundary element method. Two relative locations, namely, horizontal and vertical, are examined for the twin cylinders. In both cases, the twin cylinders are starting from rest and ultimately moving with the same constant speed through an accelerating process. Assuming that the fluid is inviscid and incompressible and the flow to be irrotational, the integral Laplace equation can be discretized based on the boundary element method. Fully-nonlinear boundary conditions are satisfied on the unknown free surface and the moving body surface. The free surface is traced by a Lagrangian technique. Regriding and remeshing are applied, which is crucial to quality of the numerical results. Single circular cylinder and elliptical cylinder are calculated by linear method and fully nonlinear method for accuracy checking and then fully nonlinear method is conducted on the twin cylinder cases, respectively. The generated wave elevation and the resultant force are analysed to discuss the influence of the gap between the two cylinders as well as the water depth. It is found that no matter the kind of distribution, when the moving cylinders are close to each other, they suffer hydrodynamic force with large absolute value in the direction of motion. The trend of force varying with the increase of gap can be clearly seen from numerical analysis. The vertically distributed twin cylinders seem to attract with each other while the horizontally distributed twin cylinders are opposite when they are close to each other.
基金supported by the National Basic Research Program of China (Grant No. 2012CB417404)the National Natural Science Foundation of China (Grant Nos.41075064 and 41176014)
文摘The sea surface temperature (SST) in the In- dian Ocean affects the regional climate over the Asian continent mostly through a modulation of the monsoon system. It is still difficult to provide an a priori indication of the seasonal variability over the Indian Ocean. It is widely recognized that the warm and cold events of SST over the tropical Indian Ocean are strongly linked to those of the equatorial eastern Pacific. In this study, a statistical prediction model has been developed to predict the monthly SST over the tropical Indian Ocean. This model is a linear regression model based on the lag relationship between the SST over the tropical Indian Ocean and the Nino3.4 (5°S-5°N, 170°W-120°W) SST Index. The pre- dictor (i.e., Nino3.4 SST Index) has been operationally predicted by a large size ensemble E1 Nifio and the Southern Oscillation (ENSO) forecast system with cou- pled data assimilation (Leefs_CDA), which achieves a high predictive skill of up to a 24-month lead time for the equatorial eastern Pacific SST. As a result, the prediction skill of the present statistical model over the tropical In- dian Ocean is better than that of persistence prediction for January 1982 through December 2009.
文摘The surface and interface electronic states of tris (8 hydroxyquinoline) aluminum (Alq 3)/indium tin oxide (ITO) were measured and analyzed by X ray photoelectron spectroscopy (XPS). The results indicated that, in Alq 3 molecule, the binding energy ( E b) of Al atoms is 70.7 eV and 75.1 eV, corresponding to Al(O) and Al(Ⅲ), respectively; The binding energy of C is 285.8 eV, 286.3 eV, and 286.8 eV, corresponding to C of C-C group, C-O, and C-N bond, respectively. N is the main peak locating at 401.0 eV, corresponding to N atom of C-N=C. O atoms mainly bond to H atom, with the binding energy of 533.2 eV. As the sputtering time of Ar + ion beam increases, Al 2p , C 1s , N 1s , O 1s , In 3d 5/2 and Sn 3d 5/2 peaks slightly shift towards lower binding energy, and Al 2p , C 1s and N 1s peaks get weaker, which contributes to diffusing the oxygen, indium and tin in ITO into Alq 3 layer.
基金supported by the Liaoning Provincial Office of Education for Innovation Team (2006T001)Liaoning Province of Key Laboratory Project (2008403001)
文摘The target products were prepared by homogeneous precipitation method using SDS and PEG 800, respectively, as surfactant at a reaction temperature of 95 ℃ for 3 h, followed by calcination at 400 ~C for 3 h. The samples were charac- terized and analyzed by XRD, SEM, FTIR and zeta potential measurements. The products were modified with different sur- factants to improve their dispersion stability, both the amount and the best zeta potential values of which were identified in this work. The surface-modified nano-particles were added at a mass fraction of 1.0%, 2.0%, 3.0%, and 4.0%, respectively, into the base oil. It was showed that the additive in base oil has good oil solubility without detectable corrosion of copper stripe, and had excellent behavior in terms of anti-wear performance and lower friction coefficient.
基金supported by the National Science Fund for Distinguished Young Scholars(21125418)the National Natural Science Foundation of China(21174098,21304062 and 21334004)+1 种基金the Natural Science Foundation of Jiangsu Higher Education Institutions of China(13KJB430020)the China Postdoctoral Science Foundation(2013M541714)
文摘A simple approach has been developed to functionalize various substrates, such as gold and polyvinylchloride, with dopamine methacrylamide—a molecule with adhesive properties that mimic those of mussels—to produce a versatile and general platform for subsequent surface modification. With active double bonds on the surface, various polymers, such as poly([2-(methacryloyloxy)ethyl]dimethyl-(3-sulfopropyl) ammonium hydroxide(PMEDSAH) and poly(N-vinylpyrrolidone)(PVP), can be grafted by conventional radical polymerization. Double bond surface functionalization and subsequent polymer grafting have been verified by static water contact angle, Fourier transform infrared–attenuated total reflectance(FTIR-ATR) spectroscopy and X-ray photoelectron spectroscopy(XPS) measurements. Protein adsorption assays showed that the polymermodified substrates have good protein-resistant properties. Considering the advantages of facility, versatility and substrate- independence, this method should be useful in designing functional interfaces for bioengineering applications.
基金supported by the Joint Fund of the National Natural Science Foundation of China and the China Academy of Engineering Physics(11076008)the National Natural Science Foundation of China(61178018,51202024)+1 种基金the Ph.D.Funding Support Program of Education Ministry of China(20110185110007)the Fundamental Research Funds for the Central Universities(2672012ZYGX2012J048)
文摘YMn2O5nanorods were synthesized through a modified polyacrylamide gel route.The synthesis strategy in this work is based on a sol-gel process using a polyacrylamide gel method in which oxalic acid,citric acid or tartaric acid is employed as the chelating agent.In the gel routes,oxalic acid was used as a carboxyl chelating agent,while citric acid or tartaric acid was a carboxyl and hydroxyl chelating agent.The as-prepared samples were characterized by means of techniques such as X-ray powder diffraction(XRD)measurement,thermogravimetric analysis(TG),differential scanning calorimetry analysis(DSC),Fourier transform infrared spectroscopy(FTIR),X-ray photoelectron spectroscopy(XPS),thermal expansion measurement and field-emission scanning electron microscopy(SEM)investigations.It was found that oxalic acid is the best chelating agent with Y(NO3)3·6H2O and Mn(CH3COO)2·4H2O as precursors to prepare a single orthorhombic YMn2O5nanorods at 1000°C.Scanning electron microscope observation shows that the morphology of YMn2O5powders is significantly dependent on the chelating agent.The peaks(single orthorhombic YMn2O5nanorods)at 642,600,573,546,521,493,486,468,448 and 400cm?1were observed from FTIR spectra.The phase,surface morphology and chelation mechanisms of YMn2O5samples have been discussed on the basis of the experimental results.
基金financial support of this work by the doctoral degree scholarship of China Scholarship Council and the University of Nottingham,UK
文摘Due to the property of water repellence, biomimetic superhydrophobic surfaces have been widely applied to green technologies, in turn inducing wider and deeper investigations on superhydrophobic surfaces. Theoretical, experimental and numerical studies on wetting transitions have been carried out by researchers, but the mechanism of wetting transitions between Cassie-Baxter state and Wenzel state, which is crucial to develop a stable superhydrophobic surface, is still not fully understood. In this paper, the flee energy curves based on the transition processes are presented and discussed in detail. The exis- tence of energy barriers with or without consideration of the gravity effect, and the irreversibility of wet- ting transition are discussed based on the presented energy curves. The energy curves show that different routes of the Cassie-to-Wenzel transition and the reverse transition are the main reason for the irre- versibility. Numerical simulations are implemented via a phase field lattice Boltzmann method of large density ratio, and the simulation results show good consistency with the theoretical analysis.
基金supported by the National Natural Science Foundation of China(Grant No.51206089)Postdoctoral Science Foundation of China(Grant No.2012M510438)the National Basic Research Program of China("973"Project)(Grant No.2013CB228502)
文摘The oxidation characteristics of boron particles, boron-A with the diameter of 2.545 μm and boron-B with the diameter of 10.638 μm, at low temperature(1500 K) have been investigated by thermogravimetry(TG) coupled with simultaneous differential scanning calorimetry(DSC), infrared and mass spectra. A rapid oxidation stage of boron particles, followed by a slow oxidation stage of sintered particles, is found from the TG and DSC curves. The onset temperatures of the oxidation process of boron-A particles are in the range of 806–889 K, which are at least 105 K lower than those of boron-B at the same condition. As the partial pressure of oxygen increases from 5% to 35%, the onset temperature of boron-A or boron-B particles decreases. However, when the partial pressure of oxygen is above 35%, the onset temperature becomes constant, implying a saturation effect of oxygen on the reaction rate. It indicates that the chemical adsorption of oxygen, i.e. chemical reaction, on the particle surface is the rate-limited step at the beginning of the rapid oxidation stage. Therefore, the first-order chemical reaction model is used to simulate the oxidation of boron particles, even that of the sinter. The average activation energies of the particles are 291.3 kJ/mol for boron-A and 338.4 k J/mol for boron-B. While the average activation energies of the sintered particles are 36.35 k J/mol for boron-A and 31.87 kJ/mol for boron-B. The pre-exponential factor of the particles is -10^4, while that of the sinter is 10^-1. The oxidation rate constant of boron is qualitatively mainly affected by the specific surface of the sample and the thickness of the oxide layer.
文摘The interaction of three conormal waves for semi-linear strictly hyperbolic equations of third order is considered. Let Σi, i = 1, 2, 3, be smooth characteristic surfaces for P= Da(D_t ̄2 -△) intersecting transversally at the origin. Suppose that the solution u to Pu = f(t, x ,y)D u), ≤2 is conormal to Σi, i = 1, 2, 3, for t < 0. The author uses Bony's second microlocajization techniques and commutator arguments to conclude that the new singularities a short time after the triple interaction lie on the surface of the light cone Γ over the origin plus the surfaces obtained by flow-outs of the lines of intersection Γ ∩ Σi and Σi∩ Σj, i, j = 1, 2, 3.