<正> The ESR spectra of some [Cp2Ti(L)X] complexes (Cp: C5H5, MeC5H4; L: phosphane,isocyanide, pyridine, amine and carbon monoxide; X: F, Cl, Br, I) have been obtained.When X is Cl, Br or I, the linear relat...<正> The ESR spectra of some [Cp2Ti(L)X] complexes (Cp: C5H5, MeC5H4; L: phosphane,isocyanide, pyridine, amine and carbon monoxide; X: F, Cl, Br, I) have been obtained.When X is Cl, Br or I, the linear relationships between the g value and hyperfine couplingcoustant a(Ti) are explained in terms of the electron character of the L ligand and the ESRspectral trends of the complexes are studied.展开更多
文摘<正> The ESR spectra of some [Cp2Ti(L)X] complexes (Cp: C5H5, MeC5H4; L: phosphane,isocyanide, pyridine, amine and carbon monoxide; X: F, Cl, Br, I) have been obtained.When X is Cl, Br or I, the linear relationships between the g value and hyperfine couplingcoustant a(Ti) are explained in terms of the electron character of the L ligand and the ESRspectral trends of the complexes are studied.