The title ternary complex was synthesized in aqueous solution,and the crystal structure was determined by single crystal X-ray diffraction analysis.The crystal belongs to triclinic system with space group of Pī and t...The title ternary complex was synthesized in aqueous solution,and the crystal structure was determined by single crystal X-ray diffraction analysis.The crystal belongs to triclinic system with space group of Pī and the lattice parameters:a=12.969（2）?,b=14.508（2）?,c=14.706（3）?,α=98.99（1）°,β=111.07（1）°,γ=114.50（1）°,V=2192.5（8）?3,Z=2,Dc=1.668g/cm3.The title complex is a mononuclear molecule.The central metal ion Tb3+ is coordinated to four nitrogen atoms from two chelating 1,10-phenanthroline,to two oxygen atoms from monodentate carboxyl and to two oxygen atoms from coordinated water molecules.The coordination number is eight and the coordination geometry can be discribed as a distorted square antiprism.展开更多
文摘The title ternary complex was synthesized in aqueous solution,and the crystal structure was determined by single crystal X-ray diffraction analysis.The crystal belongs to triclinic system with space group of Pī and the lattice parameters:a=12.969（2）?,b=14.508（2）?,c=14.706（3）?,α=98.99（1）°,β=111.07（1）°,γ=114.50（1）°,V=2192.5（8）?3,Z=2,Dc=1.668g/cm3.The title complex is a mononuclear molecule.The central metal ion Tb3+ is coordinated to four nitrogen atoms from two chelating 1,10-phenanthroline,to two oxygen atoms from monodentate carboxyl and to two oxygen atoms from coordinated water molecules.The coordination number is eight and the coordination geometry can be discribed as a distorted square antiprism.
