A kind of highly fluorinated bisphenol monomer was synthesized. It was characterized by FTIR, 1H NMR and MS. 6F PEEK and 6F PEEKK were prepared via aromatic nucleophilic substitution, based on [3,5 di(trifluoromethyl)...A kind of highly fluorinated bisphenol monomer was synthesized. It was characterized by FTIR, 1H NMR and MS. 6F PEEK and 6F PEEKK were prepared via aromatic nucleophilic substitution, based on [3,5 di(trifluoromethyl)] phenylhydroquinone and difluoro monomers. The T gs of 6F PEEK and 6F PEEKK are 423 and 436 K, respectively. The 6F polymers exhibit a high thermal stability and good solubility. The flexible, creasable and transparent thin films were easily obtained by compression moulding and solution casting.展开更多
A fluorine containing monomer was synthesized and its polymer was prepared by aromatic nucleophilic substitution polycondensation of the monomer and 4,4′ difluorobenzophenone using potassium carbonate as the catalyst...A fluorine containing monomer was synthesized and its polymer was prepared by aromatic nucleophilic substitution polycondensation of the monomer and 4,4′ difluorobenzophenone using potassium carbonate as the catalyst and tetramethylene sulfone as solvent. The polymer properties were characterized by FTIR, NMR, DSC and the results showed that the T g of the polymer is 141 ℃ and the solubility of the polymer was obviously improved due to the introduction of (3 trifluoromethyl)phenyl group.展开更多
We synthesized a series of polymers: poly(ether ether ketone ketone) (PEEKK),poly (ether biphenyl ether ketone ketone) (PEBEKK) and their copolymer by polycondensation. We also prepared a series of PEEKK-PEBEKK blends...We synthesized a series of polymers: poly(ether ether ketone ketone) (PEEKK),poly (ether biphenyl ether ketone ketone) (PEBEKK) and their copolymer by polycondensation. We also prepared a series of PEEKK-PEBEKK blends. By using DSC method, we found that Tg of the copolymers and the blends rose with the increasing of biphenyl contents in the polymers. Tc of the copolymers and the blends is higher than the corresponding homopolymer. From the results, we think that PEEKK-PEBEKK copolymer and blends are miscible and the copolymer is random.展开更多
Two novel poly(aryl ether ketone)s based on (3 methyl)phenylhydroquinone were synthesized via aromatic nucleophilic substitution reaction. The high molecular polymers were easily obtained because of the high reaction ...Two novel poly(aryl ether ketone)s based on (3 methyl)phenylhydroquinone were synthesized via aromatic nucleophilic substitution reaction. The high molecular polymers were easily obtained because of the high reaction activity of bisphenol monomer. The traces of DSC showed that the T gs of m TPEEK and m TPEEKK were 421 and 432 K, respectively. The two polymers exhibit a high thermal stability and good solubility. The transparent and flexible films were readily prepared with chloroform solution. The film of m TPEEK had a low dielectric constant( ε =2 7).展开更多
A novel crosslinkable fluorinated poly(ether ether ketone) with acetylenylbenzene end groups was prepared by solution condensation. The chemical structure of such polymer was confirmed by FTIR and 1H NMR. The crosslin...A novel crosslinkable fluorinated poly(ether ether ketone) with acetylenylbenzene end groups was prepared by solution condensation. The chemical structure of such polymer was confirmed by FTIR and 1H NMR. The crosslinking behavior and thermal stability were investigated by DSC and TGA respectively. The DSC thermogram for the first heating run shows a glass transition of 6F-PEEK at about 395 K and a exothermic peak correspongding to the self-crosslinking reaction of fluorinated poly(ether ether ketong) at about 700 K. For the second heating run, the exothermic peak disappered and the glass transition shifted to a higher temperature. The crosslinked polymer shown excelent thermal stability and solvent-resistence. The temperature for 5% weight loss was 774 K and the self-crosslinked polymer was no more disolved by polar solvents, which disolved in before crosslinking, such as DMF, DMAc and NMP. This kind of polymer may be a potential material used as electro-optical devices.展开更多
A kind of high Fluorine-containing poly(aryl ether) without side reaction was synthesized in a two-step synthesis. Its structure was confirmed by FTIR, 1H NMR and 19F NMR. The polymer shows an excellent thermal stabil...A kind of high Fluorine-containing poly(aryl ether) without side reaction was synthesized in a two-step synthesis. Its structure was confirmed by FTIR, 1H NMR and 19F NMR. The polymer shows an excellent thermal stability, good solubility, low water absorption, low dielectric constant and low refractive index. Flexible and transparant thin film can be easily obtained by compression moulding or solution casting. The polymer would be a promising material used for microelectronics and waveguide devices.展开更多
The crosslinkable trifluoromethylated poly(aryl ethers) terminated with phenylethynyl moieties(11F-PAE-PEP)s were prepared in two step syntheses. The structure of 11F-PAE-PEP was confirmed by FTIR and 1H NMR. The cros...The crosslinkable trifluoromethylated poly(aryl ethers) terminated with phenylethynyl moieties(11F-PAE-PEP)s were prepared in two step syntheses. The structure of 11F-PAE-PEP was confirmed by FTIR and 1H NMR. The crosslinking behavior was studied by DSC. There is a remarkable increase of T g after crosslinking of the poly(aryl ethers). The T g values of crosslinked polymers were 437 and 446 K, respectively. The crosslinked polymers could not be soluble in common organic solvents, such as N,N-dimethylformamide, N,N-dimethylacetamide, N-methyl-2-pyrrolidinone, chloroform, and tetrahydrofuran. The temperatures at a 5% mass loss of the crosslinked polymers in air were above 789 K. They showed a good optical property, too. This kind of polymers will be the promising materials used as the microelectronics and optical waveguide devices.展开更多
文摘A kind of highly fluorinated bisphenol monomer was synthesized. It was characterized by FTIR, 1H NMR and MS. 6F PEEK and 6F PEEKK were prepared via aromatic nucleophilic substitution, based on [3,5 di(trifluoromethyl)] phenylhydroquinone and difluoro monomers. The T gs of 6F PEEK and 6F PEEKK are 423 and 436 K, respectively. The 6F polymers exhibit a high thermal stability and good solubility. The flexible, creasable and transparent thin films were easily obtained by compression moulding and solution casting.
文摘A fluorine containing monomer was synthesized and its polymer was prepared by aromatic nucleophilic substitution polycondensation of the monomer and 4,4′ difluorobenzophenone using potassium carbonate as the catalyst and tetramethylene sulfone as solvent. The polymer properties were characterized by FTIR, NMR, DSC and the results showed that the T g of the polymer is 141 ℃ and the solubility of the polymer was obviously improved due to the introduction of (3 trifluoromethyl)phenyl group.
文摘We synthesized a series of polymers: poly(ether ether ketone ketone) (PEEKK),poly (ether biphenyl ether ketone ketone) (PEBEKK) and their copolymer by polycondensation. We also prepared a series of PEEKK-PEBEKK blends. By using DSC method, we found that Tg of the copolymers and the blends rose with the increasing of biphenyl contents in the polymers. Tc of the copolymers and the blends is higher than the corresponding homopolymer. From the results, we think that PEEKK-PEBEKK copolymer and blends are miscible and the copolymer is random.
文摘Two novel poly(aryl ether ketone)s based on (3 methyl)phenylhydroquinone were synthesized via aromatic nucleophilic substitution reaction. The high molecular polymers were easily obtained because of the high reaction activity of bisphenol monomer. The traces of DSC showed that the T gs of m TPEEK and m TPEEKK were 421 and 432 K, respectively. The two polymers exhibit a high thermal stability and good solubility. The transparent and flexible films were readily prepared with chloroform solution. The film of m TPEEK had a low dielectric constant( ε =2 7).
文摘A novel crosslinkable fluorinated poly(ether ether ketone) with acetylenylbenzene end groups was prepared by solution condensation. The chemical structure of such polymer was confirmed by FTIR and 1H NMR. The crosslinking behavior and thermal stability were investigated by DSC and TGA respectively. The DSC thermogram for the first heating run shows a glass transition of 6F-PEEK at about 395 K and a exothermic peak correspongding to the self-crosslinking reaction of fluorinated poly(ether ether ketong) at about 700 K. For the second heating run, the exothermic peak disappered and the glass transition shifted to a higher temperature. The crosslinked polymer shown excelent thermal stability and solvent-resistence. The temperature for 5% weight loss was 774 K and the self-crosslinked polymer was no more disolved by polar solvents, which disolved in before crosslinking, such as DMF, DMAc and NMP. This kind of polymer may be a potential material used as electro-optical devices.
文摘A kind of high Fluorine-containing poly(aryl ether) without side reaction was synthesized in a two-step synthesis. Its structure was confirmed by FTIR, 1H NMR and 19F NMR. The polymer shows an excellent thermal stability, good solubility, low water absorption, low dielectric constant and low refractive index. Flexible and transparant thin film can be easily obtained by compression moulding or solution casting. The polymer would be a promising material used for microelectronics and waveguide devices.
文摘The crosslinkable trifluoromethylated poly(aryl ethers) terminated with phenylethynyl moieties(11F-PAE-PEP)s were prepared in two step syntheses. The structure of 11F-PAE-PEP was confirmed by FTIR and 1H NMR. The crosslinking behavior was studied by DSC. There is a remarkable increase of T g after crosslinking of the poly(aryl ethers). The T g values of crosslinked polymers were 437 and 446 K, respectively. The crosslinked polymers could not be soluble in common organic solvents, such as N,N-dimethylformamide, N,N-dimethylacetamide, N-methyl-2-pyrrolidinone, chloroform, and tetrahydrofuran. The temperatures at a 5% mass loss of the crosslinked polymers in air were above 789 K. They showed a good optical property, too. This kind of polymers will be the promising materials used as the microelectronics and optical waveguide devices.
