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基于无序色散成像光谱仪的实验教学设计
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作者 唐瑾 杨涛 +2 位作者 江玉翠 叶尚辉 周馨慧 《实验技术与管理》 CAS 北大核心 2024年第2期235-243,共9页
论文以无序色散成像光谱仪的制备与性能测试为例,研究了如何将新型的上、下转换发光材料和成像光谱仪器件相结合实现宽波段测量范围的超光谱成像,并将其应用于材料物理专业本科生“光电子器件与工艺”课程的实践教学中去。该实践教学包... 论文以无序色散成像光谱仪的制备与性能测试为例,研究了如何将新型的上、下转换发光材料和成像光谱仪器件相结合实现宽波段测量范围的超光谱成像,并将其应用于材料物理专业本科生“光电子器件与工艺”课程的实践教学中去。该实践教学包括前置器件、色散器件、转换器件、探测器件等部件的设计与制备,以及光谱复原数学优化算法的学习和大型实验仪器的使用。该实验教学设计,改变了传统材料专业学生对光电子技术不够了解的状况,扩大了材料物理专业学生在光电子学领域的知识面,提高了综合素养,促进了多元化就业。 展开更多
关键词 教学改革 成像光谱仪 超光谱成像 光谱复原
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金属-有机骨架(MOFs)的最新研究进展 被引量:15
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作者 周馨慧 李洪辉 《南京邮电大学学报(自然科学版)》 北大核心 2012年第3期100-110,共11页
作为一种新型的多功能分子基材料,金属-有机骨架化合物因其有机-无机杂化特性、结构上的有序性和可裁剪性、微孔性、特殊的光电磁性质及工业上的潜在运用而备受关注。它作为多孔材料,与无机或有机的多孔材料相比具有特殊的优势,是目前... 作为一种新型的多功能分子基材料,金属-有机骨架化合物因其有机-无机杂化特性、结构上的有序性和可裁剪性、微孔性、特殊的光电磁性质及工业上的潜在运用而备受关注。它作为多孔材料,与无机或有机的多孔材料相比具有特殊的优势,是目前新功能材料研究领域的一个热点。文中概述了近些年发展起来的新兴领域:金属-有机骨架薄膜,发光金属-有机骨架材料及纳米级金属-有机骨架材料,对它们的研究进展及设计合成进行了总结。 展开更多
关键词 金属-有机骨架 薄膜 发光 纳米
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一个双核镍配合物[Ni_2(Htda)_2(H_2O)_6]·4H_2O的合成、晶体结构和性质(英文) 被引量:2
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作者 周馨慧 《无机化学学报》 SCIE CAS CSCD 北大核心 2010年第5期801-806,共6页
双核金属配合物对于生物化学和磁化学都是非常重要的。在本文中,1,2,3-三氮唑-4,5-二羧酸(H3tda)配体和硝酸镍在常温常压下反应得到了1个三氮唑桥联的双核镍配合物[Ni2(Htda)2(H2O)6]·4H2O(1),并通过元素分析、红外光谱、X-射线单... 双核金属配合物对于生物化学和磁化学都是非常重要的。在本文中,1,2,3-三氮唑-4,5-二羧酸(H3tda)配体和硝酸镍在常温常压下反应得到了1个三氮唑桥联的双核镍配合物[Ni2(Htda)2(H2O)6]·4H2O(1),并通过元素分析、红外光谱、X-射线单晶衍射、热重分析以及超导量子干涉仪(SQUID)对其晶体结构和磁、热性质进行了表征。晶体数据表明该配合物属三斜晶系,空间群为P1。在配合物1中,2个1,2,3-三氮唑-4,5-二羧酸配体利用2个相邻的氮原子桥联2个金属镍离子形成一个双桥的双核镍配合物。这些双核镍单元又通过体系中存在的大量的氢键相互作用形成了三维超分子骨架。磁性分析显示双核镍单元内镍镍之间存在反铁磁相互作用。 展开更多
关键词 双核镍配合物 1 2 3-三氮唑-4 5-二羧酸 晶体结构 氢键 磁性质
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关于导师制对提高材料化学专业本科毕业论文质量的探讨 被引量:16
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作者 周馨慧 《广东化工》 CAS 2011年第9期204-204,208,共2页
本科毕业论文是高等院校人才培养计划的重要组成部分,是必须的实践教学环节,其质量的高低是一所高校教育教学质量的直接反映。当前高校本科毕业论文现状,反映出本科生的科研意识淡薄、科研能力低下的问题相当突出。本科生科研导师制对... 本科毕业论文是高等院校人才培养计划的重要组成部分,是必须的实践教学环节,其质量的高低是一所高校教育教学质量的直接反映。当前高校本科毕业论文现状,反映出本科生的科研意识淡薄、科研能力低下的问题相当突出。本科生科研导师制对解决时下本科毕业论文存在的问题具有积极意义,值得尝试。 展开更多
关键词 导师制 毕业论文 材料化学 本科
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结合导师制提高材料化学专业本科毕业论文质量运行新模式研究 被引量:1
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作者 周馨慧 杨涛 《科技视界》 2013年第26期22-23,共2页
本科毕业论文是高等院校人才培养计划的重要组成部分,是必须的实践教学环节,其质量的高低是一所高校教育教学质量的直接反映。当前高校本科毕业论文现状,反映出本科生的科研意识淡薄、科研能力低下的问题相当突出;本科生科研导师制对解... 本科毕业论文是高等院校人才培养计划的重要组成部分,是必须的实践教学环节,其质量的高低是一所高校教育教学质量的直接反映。当前高校本科毕业论文现状,反映出本科生的科研意识淡薄、科研能力低下的问题相当突出;本科生科研导师制对解决时下本科毕业论文存在的问题具有积极意义,值得尝试。 展开更多
关键词 导师制 毕业论文 材料化学 本科
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《光电子器件与工艺》课程教学改革初探 被引量:3
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作者 杨涛 周馨慧 +2 位作者 王磊 张新稳 唐超 《科技信息》 2013年第23期46-46,共1页
本文针对材料物理专业本科生专业课《光电子器件与工艺》,提出了一些教学改革的新思路。通过该课程的教学改革,可以扩大材料物理专业学生在光电子学领域的知识面与专业技能,促进学生多元化就业。
关键词 光电子器件 材料物理 教学改革
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基于半刚性四面体四齿配体构筑的Zn(Ⅱ)/Cd(Ⅱ)配位聚合物及其性质(英文)
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作者 唐文渊 任世斌 +2 位作者 朱冬冬 韩得满 周馨慧 《无机化学学报》 SCIE CAS CSCD 北大核心 2015年第10期2073-2078,共6页
在水热的条件下,利用四(4-吡啶氧甲基)甲烷(L1)或四(3-吡啶氧甲基)甲烷(L2)、1,4-萘二甲酸(1,4-NDC)和d10金属离子发生自组装反应合成了2个化合物{[Cd2(L1)(1,4-NDC)2]·2H2O}n(1)和{[Zn2(L2)(1,4-NDC)2]·DMF·3H2O)}n(2)... 在水热的条件下,利用四(4-吡啶氧甲基)甲烷(L1)或四(3-吡啶氧甲基)甲烷(L2)、1,4-萘二甲酸(1,4-NDC)和d10金属离子发生自组装反应合成了2个化合物{[Cd2(L1)(1,4-NDC)2]·2H2O}n(1)和{[Zn2(L2)(1,4-NDC)2]·DMF·3H2O)}n(2)。单晶结构表明化合物1是通过L1配体与一维链[Cd(1,4-NDC)]n相连构建而成的三维骨架化合物,而化合物2是一对螺旋链与另外的一维链相互垂直交联而形成二维网络结构。更为重要的是,通过引入2种不同空间位阻的配体,研究了辅助配体对金属有机配位聚合物结构多样性的影响。另外,它们的荧光性质也做了相应的探讨。 展开更多
关键词 羧酸配体 异构化 空间位阻 荧光
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A Three-dimensional Porous Metal-organic Framework Based on Cyano Unit and 1,4-Bis(1,2,4-triazol-1-yl)butane(btb):{[Cu_8(btb)_2(CN)_8].3H_2O}_n 被引量:3
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作者 周馨慧 李洪辉 黄维 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2012年第1期33-38,共6页
The title coordination polymer 1,{[Cu8(btb)2(CN)8].3H2O}n(btb = 1,4-bis(1,2,4-triazol-1-yl)butane),has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Complex... The title coordination polymer 1,{[Cu8(btb)2(CN)8].3H2O}n(btb = 1,4-bis(1,2,4-triazol-1-yl)butane),has been hydrothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Complex 1 crystallizes in monoclinic,space group C2/c with a = 1.2938(3),b = 1.9422(5),c = 0.9406(2) nm,β = 121.891(4)°,V = 2.0066(9) nm3,C24H30Cu8N20O3,Mr = 1155.00,Dc = 1.912 g/cm3,μ(MoKα) = 4.209 mm?1,F(000) = 1140,GOF = 1.184,Z = 2,the final R = 0.0634 and wR = 0.1503 for I 2σ(I).In complex 1,one-dimensional CuCN zigzag chains are linked by triazolyl groups of btb ligands to form two-dimensional networks,which are further bridged by 1,4-butyl moieties of btb ligands to fabricate a three-dimensional order framework,in which one-dimensional ellipsoid-like channels are observed. 展开更多
关键词 CYANO 1 4-bis(1 2 4-triazol-1-yl)butane metal-organic framework(MOF) complex Cu+
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A Lanthanide-transition Metal Coordination Polymer:{[CuEu(Hbidc)_2(H_2O)_4]·H_2O}_n(H_3bidc=1H-benzimidazole-5,6-dicarboxylic Acid) 被引量:2
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作者 周馨慧 黄维 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第4期496-501,共6页
The title complex 1,{[CuEu(Hbidc)2(H2O)4]·H2O}n(H3bidc = 1H-benzimidazole-5,6-dicarboxylic acid),has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Comple... The title complex 1,{[CuEu(Hbidc)2(H2O)4]·H2O}n(H3bidc = 1H-benzimidazole-5,6-dicarboxylic acid),has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Complex 1 crystallizes in triclinic,space group P1,with a = 7.791(2),b = 12.058(3),c = 12.109(3),α = 82.189(5),β = 72.407(5),γ = 89.184(4)°,V = 1073.7(5)3,C18H18CuEuN4O13,Mr = 713.86,Dc = 2.208 g/cm3,μ(MoKα) = 3.967 mm-1,F(000) = 700,GOOF = 0.950,Z = 2,the final R = 0.0531 and wR = 0.1068 for I 2σ(I).Complex 1 possess a tape-like chain structure consisting of Eu2C8O4 and Cu2Eu2C18N4O4 metallic rings alternatively arranged and is the first 3d-4f heterometallic complex based on the 1H-ben-zimidazole-5,6-dicarboxylato ligand(Hbidc).Plenty of hydrogen-bonding and π...π stacking interactions connect the 1D chains to construct a 3D supramolecular architecture. 展开更多
关键词 1H-benzimidazole-5 6-dicarboxylic acid 3d-4f HETEROMETALLIC complex Cu+ Eu3+
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A Copper(Ⅱ)-cadmium(Ⅱ) Heterometallic Hexanuclear Complex:[Cd_4Cu_2(pdc)_4(H_2O)_(14)](H_3pdc=3,5-Pyrazoledicarboxylic Acid)
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作者 周馨慧 银秀菊 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第2期180-185,共6页
The title complex 1,[Cd 4 Cu 2 (pdc) 4 (H 2 O) 14 ] (H 3 pdc=3,5-pyrazoledicarboxylic acid),has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Complex 1 crysta... The title complex 1,[Cd 4 Cu 2 (pdc) 4 (H 2 O) 14 ] (H 3 pdc=3,5-pyrazoledicarboxylic acid),has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Complex 1 crystallizes in triclinic,space group P1 with a=0.67235(10),b=1.27935(18),c=1.28569(17) nm,α=112.633(2),β=102.971(3),γ=97.089(2)o,V=0.9673(2) nm 3,C 20 H 32 Cd 4 Cu 2 N 8 O 30,M r=1441.22,D c=2.474 g/cm 3,μ(MoKα)=3.356 mm 1,F(000)=698,S=1.003,Z=1,the final R=0.0471 and wR=0.0748 for I 2σ(Ⅰ).In 1,two deprotonated 3,5-pyrazoledicarboxylic acids (pdc 3),one copper(Ⅱ) ion and one cadmium(Ⅱ) ion firstly form a pyrazole-bridged Cu II Cd II dinuclear unit,two of which related by an inversion center are connected by another two cadmium(Ⅱ) ions through chelating carboxylate groups to construct the copper(Ⅱ)-cadmium(Ⅱ) heterometallic hexanuclear complexes.Plenty of hydrogen bond interactions existing in the system further lead to a three-dimensional (3D) supramolecular framework. 展开更多
关键词 3 5-pyrazoledicarboxylic acid HETEROMETALLIC complex hexanuclear copper(Ⅱ)-cadmium(Ⅱ)
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Synthesis,Structure and Physical Properties of Mn and Cd Complexes with 1,1,2,2-Tetracarboxyl-ethylene Acid
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作者 陈昌云 王小锋 +2 位作者 周宏 周馨慧 左景林 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2011年第1期59-66,共8页
Complex [Mn(tce) 0.5(H2O) 4](1) was obtained from Mn(OAc) 2 and tce,where tce is 1,1,2,2-tetracarboxyl-ethane. The structure of 1 is a single molecule,in which Mn(II) is a distorted octahedron coordinated to... Complex [Mn(tce) 0.5(H2O) 4](1) was obtained from Mn(OAc) 2 and tce,where tce is 1,1,2,2-tetracarboxyl-ethane. The structure of 1 is a single molecule,in which Mn(II) is a distorted octahedron coordinated to six oxygen atoms. Complex [Cd(tce) 0.5(H2O) 3](H2O) (2) fea-tures a pillared layer architecture. The Cd(II) atom is in an octahedral environment coordinated by six oxygen donors from water molecules and tce ligands. Cd(II) atoms are interlinked by the tce ligand to generate a 2-D wavelike layer. The layers are strutted by the intermolecular O-H···O hydrogen bonds to form a 3-D open framework. Luminescence property of complex 2 was investigated. Magnetic property of complex 1 was also studied. 1 belongs to triclinic,space group P1 with a = 6.2901(12) ,b = 8.0212(15) ,c = 8.0769(15) A,α = 108.522(3) ,β = 95.068(3) ,γ = 97.086(3) °,V = 379.92(12)A^3,Mr = 456.08,Dc = 1.993 g/cm^3,F(000) = 232,μ = 1.748 mm^-1,Z = 1,the final R = 0.0297 and wR = 0.0731 for 1575 observed reflections with I 〉 2σ(I) . 2 is of monoclinic system,space group P21/c with a = 6.4367(14) ,b = 9.495(2) ,c = 13.907(3)A,β = 117.405(8) °,V = 754.6(3) A^3,Mr = 285.51,Dc = 2.513 g/cm^3,F(000) = 556,μ = 2.905 mm^-1,Z = 4,the final R = 0.0375 and wR = 0.0737 for 1521 observed reflections with I 〉 2σ(I). 展开更多
关键词 Cd(Ⅱ) complex Mn(Ⅱ) complex XRD luminescence property thermal stability magnetic property
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Anisotropic self-diffusion of fluorinated poly(methacrylate) in metal-organic frameworks assessed with molecular dynamics simulation
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作者 鲁桃 徐彪 +3 位作者 叶飞宏 周馨慧 陆云清 王瑾 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第12期221-226,共6页
Utilizing the periodically structured metal-organic framework (MOF) as the reaction vessel is a promising technique to achieve the aligned polymer molecular chains, where the diffusion procedure of the polymer monom... Utilizing the periodically structured metal-organic framework (MOF) as the reaction vessel is a promising technique to achieve the aligned polymer molecular chains, where the diffusion procedure of the polymer monomer inside MOF is one of the key mechanisms. To investigate the diffusion mechanism of fluorinated polymer monomers in MOFs, in this paper the molecular dynamics simulations combined with the density functional theory and the Monte Carlo method are used and the all-atom models of TFMA (trifluoroethyl methacrylate) monomer and two types of MOFs,[Zn2(BDC)2(TED)]n and[Zn2(BPDC)2(TED)]n, are established. The diffusion behaviors of TFMA monomer in these two MOFs are simulated and the main influencing factors are analyzed. The obtained results are as follows. First, the electrostatic interactions between TFMA monomers and MOFs cause the monomers to concentrate in the MOF channel, which slows down the monomer diffusion. Second, the anisotropic shape of the one-dimensional MOF channel leads to different diffusion speeds of monomers in different directions. Third, MOF with a larger pore diameter due to a longer organic ligand,[Zn2(BPDC)2(TED)]n in this paper, facilitates the diffusion of monomers in the MOF channel. Finally, as the number of monomers increases, the self-diffusion coefficient is reduced by the steric effect. 展开更多
关键词 fluorinated polymer metal-organic framework self-diffusion coefficient molecular dynamics
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A Mn(Ⅱ) Coordination Polymer with the Flexible Tripodal Ligand 1,3,5-Tris-(imidazol-1-ylmethyl)benzene
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作者 银秀菊 张淑华 +1 位作者 周馨慧 左景林 《Chinese Journal of Structural Chemistry》 SCIE CAS CSCD 2010年第2期302-306,共5页
A new Mn(Ⅱ) coordination polymer {[Mn(timb)2(H2O)2]·(Cl)2·(H2O)2}n(1,timb = 1,3,5-tris-(imidazol-1-ylmethyl)benzene) has been synthesized and characterized by elemental analysis,IR,TG and sing... A new Mn(Ⅱ) coordination polymer {[Mn(timb)2(H2O)2]·(Cl)2·(H2O)2}n(1,timb = 1,3,5-tris-(imidazol-1-ylmethyl)benzene) has been synthesized and characterized by elemental analysis,IR,TG and single-crystal X-ray diffraction.The title compound crystallizes in the triclinic system,space group P1 with a=9.0774(13),b=9.8720(15),c=11.4898(16)A,α=93.378(3),β= 95.471(3),γ=101.101(3)°,V=1002.6(3)A^3,Mr=834.67,Dc=1.382 g/cm^3,μ(MoKα)=0.517mm^-1,F(000)=435,GOF=0.986,Z=1,the final R=0.0506 and wR=0.1139 for 3517 observed reflections I〉2σ(I).It consists of one-dimensional double stranded chains formed through bridging bidentate timb ligands,and these chains are further connected to yield a 3D supramolecular framework by hydrogen bonding interactions and π…π stacking interactions. 展开更多
关键词 coordination polymers flexible ligands crystal structures tripodal ligands
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A europium(Ⅲ) metal-organic framework as ratiometric turn-on luminescent sensor for Al^(3+) ions 被引量:6
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作者 Xinhui Zhou Jiahui Cheng +4 位作者 Liang Li Qiang Chen Yujian You Hongping Xiao Wei Huang 《Science China Materials》 SCIE EI CSCD 2018年第5期752-757,共6页
In recent years, luminescent metal-organic frameworks (MOFs) as a new type of sensing material are receiving enormous attention for their superior performance in chemical sensors and biosensors [1-2]. Taking account... In recent years, luminescent metal-organic frameworks (MOFs) as a new type of sensing material are receiving enormous attention for their superior performance in chemical sensors and biosensors [1-2]. Taking account of the excellent optical properties such as large Stokes shifts and high color purity of lanthanide MOFs (LnMOFs), a great deal of important investigations on LnMOFs have been carried out. And then, their promising abilities in detecting temperature, metal ions, oxygen, explosives and polychlorizated benzenes with high sensitivity and se- lectivity have also been exploited successfuUy [3-22]. Ratiometric luminescent sensors can provide a self-cali- brated analyte concentration readout, which is unaffected by fluctuations of sensor concentration and/or instru- mental parameters. However, it is noticed that a majority of related reports are limited to the detection of analyte using single emission, although ratiometric sensors based on dual-emission are more reliable and accurate than the sensors based on single emission. For ratiometric sensors, not only are two significantly different emissions neces- sary, but two emissions need distinctive response to the analyte. From this point of view, LnMOFs with ligand and Ln3+ emissions are very attractive, because organic ligands and Ln3+ ions as the luminescent centers possess completely different physical and chemical properties and they would produce different interactions with analytes. Thus, LnMOFs have been extensively applied to construct ratiometric sensors recently [3,22]. 展开更多
关键词 光传感器 框架材料 金属有机 铕离子 比率 铝离子 AL^3+ 荧光发射峰
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