The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most ...The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most probable thermal decomposition mechanism is the three-dimensional diffusion model of Jander equation,and the mechanism code is D3.The activation energy and pre-exponential factor for thermal decomposition of high iron gibbsite ore calculated by the Popescu method are 75.36 kJ/mol and 1.51×10-5 s-(-1),respectively.The correctness of the obtained mechanism function is validated by the activation energy acquired by the iso-conversional method.Popescu method is a rational and reliable method for the analysis of the thermal decomposition mechanism of high iron gibbsite ore.展开更多
文摘使用田口法探索了影响钒钛磁铁矿热压块抗压强度的重要因子,并通过信噪比分析计算各因子对抗压强度的贡献率,最终给出钒钛磁铁矿热压块的最佳制备条件.实验结果表明,在热压温度、配碳比、煤粉粒度三个影响因素中,煤粉粒度对抗压强度的影响程度最大,其贡献率达到了79.99%,温度和配碳比二者的贡献率分别为15%和3.63%.优化后钒钛磁铁矿热压块的制备参数为热压温度300℃、煤粉粒度<75μm、配碳比1.8.在优化后的参数下进行验证实验,得到的钒钛矿热压块的平均抗压强度达到1 152.1 N.
基金Project(51374058)supported by the National Natural Science Foundation of China
文摘The thermal decomposition kinetics of high iron gibbsite ore was investigated under non-isothermal conditions.Popescu method was applied to analyzing the thermal decomposition mechanism.The results show that the most probable thermal decomposition mechanism is the three-dimensional diffusion model of Jander equation,and the mechanism code is D3.The activation energy and pre-exponential factor for thermal decomposition of high iron gibbsite ore calculated by the Popescu method are 75.36 kJ/mol and 1.51×10-5 s-(-1),respectively.The correctness of the obtained mechanism function is validated by the activation energy acquired by the iso-conversional method.Popescu method is a rational and reliable method for the analysis of the thermal decomposition mechanism of high iron gibbsite ore.