A series of nominal compositions MgAl_(2-x)(Li_(1/3)Ti_(2/3))_(x)O_(4)(x=0,0.04,0.08,0.12,0.16,and 0.20)ceramics were successfully prepared via the conventional solid-state reaction route.The phase compositions,micros...A series of nominal compositions MgAl_(2-x)(Li_(1/3)Ti_(2/3))_(x)O_(4)(x=0,0.04,0.08,0.12,0.16,and 0.20)ceramics were successfully prepared via the conventional solid-state reaction route.The phase compositions,microstructures,and microwave dielectric properties were investigated.The results of x-ray diffraction(XRD)and scanning electron microscopy(SEM)showed that a single phase of MgAl_(2-x)(Li_(1/3)Ti_(2/3))_(x)O_(4)ceramics with a spinel structure was obtained at x≤0.12,whereas the second phase of MgTi_(2)O_(5)appeared when x>0.12.The cell parameters were obtained by XRD refinement.As the x values increased,the unit cell volume kept expanding.This phenomenon could be attributed to the partial substitution of(Li_(1/3)Ti_(2/3))^(3+)for Al^(3+).Results showed that(Li_(1/3)Ti_(2/3))^(3+)doping into MgAl_(2)O_(4)spinel ceramics effectively reduced the sintering temperature and improved the quality factor(Q_f)values.Good microwave dielectric properties were achieved for a sample at x=0.20 sintering at 1500℃in air for 4 h:dielectric constantε_(r)=8.78,temperature coefficient of resonant frequencyτ_(f)=-85 ppm/℃,and Q_(f)=62300 GHz.The Q_(f)value of the x=0.20 sample was about 2 times higher than that of pure MgAl_(2)O_(4)ceramics(31600 GHz).Thus,MgAl_(2-x)(Li_(1/3)Ti_(2/3))_(x)O_(4)ceramics with excellent microwave dielectric properties can be applied to 5G communications.展开更多
通常利用单一铁氧体材料制成的微带环行器难以有超倍频程的带宽。根据一般微带环行器的设计理论,利用两种不同的铁氧体材料构成的复合基片设计并制作了一种工作在三倍频程带宽的超宽带微带环行器。仿真结果表明,该环行器在6~18 GHz的工...通常利用单一铁氧体材料制成的微带环行器难以有超倍频程的带宽。根据一般微带环行器的设计理论,利用两种不同的铁氧体材料构成的复合基片设计并制作了一种工作在三倍频程带宽的超宽带微带环行器。仿真结果表明,该环行器在6~18 GHz的工作频带内,插入损耗(|S12|)小于1 d B,回波损耗(|S11|)大于20 d B,隔离度(|S21|)约19 d B,满足超宽带微带环行器的设计指标。除在整个工作频带内插入损耗有所增加且在低频段的6~6.5 GHz内出现了低场损耗外,实测结果与仿真结果基本吻合。文末讨论了实测结果和仿真结果之间出现低场损耗等差异的原因。展开更多
基金the Chengdu University of Technology(Grant No.KYQD201907728)。
文摘A series of nominal compositions MgAl_(2-x)(Li_(1/3)Ti_(2/3))_(x)O_(4)(x=0,0.04,0.08,0.12,0.16,and 0.20)ceramics were successfully prepared via the conventional solid-state reaction route.The phase compositions,microstructures,and microwave dielectric properties were investigated.The results of x-ray diffraction(XRD)and scanning electron microscopy(SEM)showed that a single phase of MgAl_(2-x)(Li_(1/3)Ti_(2/3))_(x)O_(4)ceramics with a spinel structure was obtained at x≤0.12,whereas the second phase of MgTi_(2)O_(5)appeared when x>0.12.The cell parameters were obtained by XRD refinement.As the x values increased,the unit cell volume kept expanding.This phenomenon could be attributed to the partial substitution of(Li_(1/3)Ti_(2/3))^(3+)for Al^(3+).Results showed that(Li_(1/3)Ti_(2/3))^(3+)doping into MgAl_(2)O_(4)spinel ceramics effectively reduced the sintering temperature and improved the quality factor(Q_f)values.Good microwave dielectric properties were achieved for a sample at x=0.20 sintering at 1500℃in air for 4 h:dielectric constantε_(r)=8.78,temperature coefficient of resonant frequencyτ_(f)=-85 ppm/℃,and Q_(f)=62300 GHz.The Q_(f)value of the x=0.20 sample was about 2 times higher than that of pure MgAl_(2)O_(4)ceramics(31600 GHz).Thus,MgAl_(2-x)(Li_(1/3)Ti_(2/3))_(x)O_(4)ceramics with excellent microwave dielectric properties can be applied to 5G communications.
基金Project(SKL-SPM-202021) supported by the State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,ChinaProject(2023YFQ0082) supported by Sichuan Science and Technology Program,ChinaProject(EFMD2022005Z) supported by Guangdong Provincial Key Laboratory of Electronic Functional Materials and Devices,China。
文摘通常利用单一铁氧体材料制成的微带环行器难以有超倍频程的带宽。根据一般微带环行器的设计理论,利用两种不同的铁氧体材料构成的复合基片设计并制作了一种工作在三倍频程带宽的超宽带微带环行器。仿真结果表明,该环行器在6~18 GHz的工作频带内,插入损耗(|S12|)小于1 d B,回波损耗(|S11|)大于20 d B,隔离度(|S21|)约19 d B,满足超宽带微带环行器的设计指标。除在整个工作频带内插入损耗有所增加且在低频段的6~6.5 GHz内出现了低场损耗外,实测结果与仿真结果基本吻合。文末讨论了实测结果和仿真结果之间出现低场损耗等差异的原因。