Various trace elements, especially potential toxic trace elements such as As, Cd, Cr, Cu, Hg, Pb, Ni, Se, Tl, Zn, would be concentrated in processing of coal. Determination of these elements in coal is very important ...Various trace elements, especially potential toxic trace elements such as As, Cd, Cr, Cu, Hg, Pb, Ni, Se, Tl, Zn, would be concentrated in processing of coal. Determination of these elements in coal is very important for identification of coal quality. A method is developed for determination of 49 trace elements in coal by high resolution inductively coupled plasma mass spectrometry (HR-ICPMS). Microwave acid digestion and low-temperature airproof acid digestion for sample preparation were investigated. It is shown that the low-temperature airproof acid digestion method is of lower blank, and more suitalbe for the coal sample preparation. The on-line internal standard (Rh) sample introduction is applied to compensate matrix effects in measurement by ICPMS. The method gives low detection limits (0.002-1.60 μg/g) and better relative standard deviations (0.60%-4.78%) for the determined 49 elements in coal.展开更多
According to current situation of the severe water pollution and bad water environment of Nanfeihe River catchment, the major environment problems were id- entified based on the investigation and analysis of the gener...According to current situation of the severe water pollution and bad water environment of Nanfeihe River catchment, the major environment problems were id- entified based on the investigation and analysis of the general situation of the catch- ment, the present situation of water quality and water volume composition, corre- sponding countermeasures were put forward to provide a reliable theoretical support for controlling pollution in water environment of Nanfeihe River.展开更多
文摘Various trace elements, especially potential toxic trace elements such as As, Cd, Cr, Cu, Hg, Pb, Ni, Se, Tl, Zn, would be concentrated in processing of coal. Determination of these elements in coal is very important for identification of coal quality. A method is developed for determination of 49 trace elements in coal by high resolution inductively coupled plasma mass spectrometry (HR-ICPMS). Microwave acid digestion and low-temperature airproof acid digestion for sample preparation were investigated. It is shown that the low-temperature airproof acid digestion method is of lower blank, and more suitalbe for the coal sample preparation. The on-line internal standard (Rh) sample introduction is applied to compensate matrix effects in measurement by ICPMS. The method gives low detection limits (0.002-1.60 μg/g) and better relative standard deviations (0.60%-4.78%) for the determined 49 elements in coal.
基金Supported by National Science and Technology Major Project for Water Pollution Control and Treatment(2012ZX07103-003,2012ZX07103-004)~~
文摘According to current situation of the severe water pollution and bad water environment of Nanfeihe River catchment, the major environment problems were id- entified based on the investigation and analysis of the general situation of the catch- ment, the present situation of water quality and water volume composition, corre- sponding countermeasures were put forward to provide a reliable theoretical support for controlling pollution in water environment of Nanfeihe River.
