This work focuses on the organic depressant,disodium bis(carboxymethyl)trithiocarbonate(DBT),as a selectivedepressant in copper?molybdenum sulfide flotation separation.Micro-flotation,Zeta potential,FTIR and XPS measu...This work focuses on the organic depressant,disodium bis(carboxymethyl)trithiocarbonate(DBT),as a selectivedepressant in copper?molybdenum sulfide flotation separation.Micro-flotation,Zeta potential,FTIR and XPS measurements werecarried out to investigate the selective depression mechanism of DBT on chalcopyrite.Zeta potential and FTIR measurementsrevealed that DBT had higher affinity for chalcopyrite than molybdenite and the XPS results of chalcopyrite before and aftertreatment with DBT further proved that DBT adsorbed on chalcopyrite surface.The investigation indicates that the mechanism ofDBT adsorbing on chalcopyrite is mainly physical adsorption.Locked circuit experiments were carried out and the results showedthat DBT could be considered as a cleaner option in commercial Cu?Mo flotation separation circuits.展开更多
In order to produceα-calcium sulfate hemihydrate(α-CaSO4·0.5H2O)whiskers with high aspect ratios,a minor amount of CuCl2·2H2O was used as the modifying agent in the process of hydrothermal treatment of cal...In order to produceα-calcium sulfate hemihydrate(α-CaSO4·0.5H2O)whiskers with high aspect ratios,a minor amount of CuCl2·2H2O was used as the modifying agent in the process of hydrothermal treatment of calcium sulfate dihydrate(CaSO4·2H2O)precursor.The presence of 2.60×10–3 mol/L CuCl2·2H2O resulted in the increase of the aspect ratios ofα-CaSO4·0.5H2O whiskers from 81 to 253.The preferential adsorption of Cu2+on the negative{110}and{100}facets ofα-CaSO4·0.5H2O crystal structures was confirmed by EDS and XPS.And ATR-FTIR demonstrated the ligand adsorption of Cu2+on the surface ofα-CaSO4·0.5H2O whiskers.The experimental results reveal that the whiskers with high aspect ratios are attributed to the adsorption of Cu2+,which promotes the 1-D growth ofα-CaSO4·0.5H2O whiskers along the c axis.展开更多
Flotation tailings were successfully flocculated in the presence of cationic polyacrylamide and silica gel.The effects of various parameters such as polymer weight,charge density,and pH on the rate of flocculation wer...Flotation tailings were successfully flocculated in the presence of cationic polyacrylamide and silica gel.The effects of various parameters such as polymer weight,charge density,and pH on the rate of flocculation were also investigated in the current study.The flocculation mechanism of the flocculant on tailings was investigated using zeta potential and Fourier transform infrared(FTIR)measurements.The results obtained reveal that 1)sodium silicate gel,used as a binder for the consolidation of tailings form primary flocs,acts as an anchor and the adsorption of polymer flocculant on these anchors results in the formation of larger flocs and,consequently,enhanced settling rate;2)flocculation in the presence of silica gel and polymer has a faster settling rate than single-polymer flocculation owing to the mechanisms of charge neutralization and bridging as identified using zeta potential and FTIR measurements.A pilot level study was conducted to investigate the influence of processed water on the flotation of scheelite.The results show that the proposed tailing disposal method could improve scheelite recovery by 2%(approximately)and could reduce the daily operation costs of the plant by approximately 108.57 USD.展开更多
According to the recently developed single-trough floating machine with the world's largest volume(inflatable mechanical agitation flotation machine with volume of 320 m3) in China, the gas-fluid two-phase flow in...According to the recently developed single-trough floating machine with the world's largest volume(inflatable mechanical agitation flotation machine with volume of 320 m3) in China, the gas-fluid two-phase flow in flotation cell was simulated using computational fluid dynamics method. It is shown that hexahedral mesh scheme is more suitable for the complex structure of the flotation cell than tetrahedral mesh scheme, and a mesh quality ranging from 0.7 to 1.0 is obtained. Comparative studies of the standard k-ε, k-ω and realizable k-ε turbulence models were carried out. It is indicated that the standard k-ε turbulence model could give a result relatively close to the practice and the liquid phase flow field is well characterized. In addition, two obvious recirculation zones are formed in the mixing zones, and the pressure on the rotor and stator is well characterized. Furthermore, the simulation results using improved standard k-ε turbulence model show that surface tension coefficient of 0.072, drag model of Grace and coefficient of 4, and lift coefficient of 0.001 can be achieved. The research results suggest that gas-fluid two-phase flow in large flotation cell can be well simulated using computational fluid dynamics method.展开更多
基金Project(2016zzts109)supported by the Innovation Driven Plan of Central South University,ChinaProject(B14034)supported by the National 111 Project,China
文摘This work focuses on the organic depressant,disodium bis(carboxymethyl)trithiocarbonate(DBT),as a selectivedepressant in copper?molybdenum sulfide flotation separation.Micro-flotation,Zeta potential,FTIR and XPS measurements werecarried out to investigate the selective depression mechanism of DBT on chalcopyrite.Zeta potential and FTIR measurementsrevealed that DBT had higher affinity for chalcopyrite than molybdenite and the XPS results of chalcopyrite before and aftertreatment with DBT further proved that DBT adsorbed on chalcopyrite surface.The investigation indicates that the mechanism ofDBT adsorbing on chalcopyrite is mainly physical adsorption.Locked circuit experiments were carried out and the results showedthat DBT could be considered as a cleaner option in commercial Cu?Mo flotation separation circuits.
基金Project(B14034)supported by the National 111 Project,ChinaProject(2015CX005)supported by the Innovation Driven Plan of Central South University,ChinaProject(2016zzts104)supported by the Fundamental Research Funds for the Central Universities,China
文摘In order to produceα-calcium sulfate hemihydrate(α-CaSO4·0.5H2O)whiskers with high aspect ratios,a minor amount of CuCl2·2H2O was used as the modifying agent in the process of hydrothermal treatment of calcium sulfate dihydrate(CaSO4·2H2O)precursor.The presence of 2.60×10–3 mol/L CuCl2·2H2O resulted in the increase of the aspect ratios ofα-CaSO4·0.5H2O whiskers from 81 to 253.The preferential adsorption of Cu2+on the negative{110}and{100}facets ofα-CaSO4·0.5H2O crystal structures was confirmed by EDS and XPS.And ATR-FTIR demonstrated the ligand adsorption of Cu2+on the surface ofα-CaSO4·0.5H2O whiskers.The experimental results reveal that the whiskers with high aspect ratios are attributed to the adsorption of Cu2+,which promotes the 1-D growth ofα-CaSO4·0.5H2O whiskers along the c axis.
基金Project(2016zzts109)supported by the Innovation Driven Plan of Central South University,ChinaProject(2015CX005)supported by the Innovation driven Program of National Basic Research Program of ChinaProject(B14034)supported by the Program of Introdution Talents of Discipline to Universities,China(111 Project)
文摘Flotation tailings were successfully flocculated in the presence of cationic polyacrylamide and silica gel.The effects of various parameters such as polymer weight,charge density,and pH on the rate of flocculation were also investigated in the current study.The flocculation mechanism of the flocculant on tailings was investigated using zeta potential and Fourier transform infrared(FTIR)measurements.The results obtained reveal that 1)sodium silicate gel,used as a binder for the consolidation of tailings form primary flocs,acts as an anchor and the adsorption of polymer flocculant on these anchors results in the formation of larger flocs and,consequently,enhanced settling rate;2)flocculation in the presence of silica gel and polymer has a faster settling rate than single-polymer flocculation owing to the mechanisms of charge neutralization and bridging as identified using zeta potential and FTIR measurements.A pilot level study was conducted to investigate the influence of processed water on the flotation of scheelite.The results show that the proposed tailing disposal method could improve scheelite recovery by 2%(approximately)and could reduce the daily operation costs of the plant by approximately 108.57 USD.
基金Project(51074027)supported by the National Natural Science Foundation of China
文摘According to the recently developed single-trough floating machine with the world's largest volume(inflatable mechanical agitation flotation machine with volume of 320 m3) in China, the gas-fluid two-phase flow in flotation cell was simulated using computational fluid dynamics method. It is shown that hexahedral mesh scheme is more suitable for the complex structure of the flotation cell than tetrahedral mesh scheme, and a mesh quality ranging from 0.7 to 1.0 is obtained. Comparative studies of the standard k-ε, k-ω and realizable k-ε turbulence models were carried out. It is indicated that the standard k-ε turbulence model could give a result relatively close to the practice and the liquid phase flow field is well characterized. In addition, two obvious recirculation zones are formed in the mixing zones, and the pressure on the rotor and stator is well characterized. Furthermore, the simulation results using improved standard k-ε turbulence model show that surface tension coefficient of 0.072, drag model of Grace and coefficient of 4, and lift coefficient of 0.001 can be achieved. The research results suggest that gas-fluid two-phase flow in large flotation cell can be well simulated using computational fluid dynamics method.
