探讨建立分光光度法测定毛酸浆中的总黄酮含量的方法,通过考察显色剂用量以及加入显色剂后放置时间对毛酸浆总黄酮测定的影响,采用单因素和正交试验优化硝酸铝-亚硝酸钠比色法测定毛酸浆果中总黄酮的含量。结果表明,毛酸浆中总黄酮含量...探讨建立分光光度法测定毛酸浆中的总黄酮含量的方法,通过考察显色剂用量以及加入显色剂后放置时间对毛酸浆总黄酮测定的影响,采用单因素和正交试验优化硝酸铝-亚硝酸钠比色法测定毛酸浆果中总黄酮的含量。结果表明,毛酸浆中总黄酮含量测定的最佳的条件为：5%Na NO2溶液0.8 m L,混匀放置2 min后,加10%Al（NO3）3溶液0.8 m L,混匀,继续加4%Na OH溶液6 m L,定容混匀后立即在335 nm下测其吸光度。在此条件下,芦丁标准溶液在0~0.002 4 mg/m L范围内与吸光度值间的回归方程y=289.02x＋0.008,R2=0.999 5。该测定方法的平均加标回收率为100.83%,稳定性、精密度以及回收率的相对标准偏差（RSD）分别为0.34%,0.29%和2.91%。该方法简便、快速、准确,可以用于毛酸浆果汁中总黄酮含量的测定。展开更多
安德森局域化是物理学中的一个基本现象,最初是安德森提出在晶体中电子受到杂质散射由于散射路径的相干导致电导完全消失,这完全来源于电子的波动特性,后来在其他各种波,如,光、微波、超声波,甚至是冷原子体系中都观察到安德森局域化现...安德森局域化是物理学中的一个基本现象,最初是安德森提出在晶体中电子受到杂质散射由于散射路径的相干导致电导完全消失,这完全来源于电子的波动特性,后来在其他各种波,如,光、微波、超声波,甚至是冷原子体系中都观察到安德森局域化现象。在晶体中,除电子外,还可能存在各种各样的磁激发准粒子,但是对于这些磁性准粒子的安德森局域化研究几乎没有。我们测量了苯甲酸铜Cu(C6H5COO)2·3H2O这个一维反铁磁海森堡链单晶的极低温比热和热导率,发现一直到50 m K的极低温,spinon磁性准粒子对比热都有一个恒定的线性贡献项Cs/T,但是其热导率的线性贡献项ks/T只保持不变到300 m K。在300m K以下,ks/T迅速减小,到100 m K以下就基本消失了。实验结果是spinon安德森局域化的一个较强的证据,为在凝聚态物理中研究安德森局域化现象开辟了一个新的窗口。展开更多
Exploration of exotic phenomena in magnetic topological systems is at the frontier of condensed matter physics,holding a significant promise for applications in topological spintronics.However,complex magnetic structu...Exploration of exotic phenomena in magnetic topological systems is at the frontier of condensed matter physics,holding a significant promise for applications in topological spintronics.However,complex magnetic structures carrying nontrivial topological properties hinder its progresses.Here,we investigate the pressure effect on the novel topological kagome magnets GdV_(6)Sn_(6) and TbV_(6)Sn_(6) to dig out the interplay between magnetic Gd/Tb layers and nonmagnetic V-based kagome sublattice.The pressure-tuned magnetic transition temperature Tm in both the compounds exhibit a turning point at the critical pressure P_(c),accompanied with a sign reversal in anomalous Hall effect(AHE).The separation of intrinsic and extrinsic contributions using the Tian-Ye-Jin scaling model suggests that the intrinsic mechanism originating from the electronic Berry curvature holds the priority in the competition with extrinsic mechanism in AHE.The above-mentioned findings can be attributed to the combined effect of pressure-tuned band topology and magnetic interaction in segregated layers.Our results provide a practical route to design and manipulate the intrinsic AHE in magnetic topological materials.展开更多
文摘探讨建立分光光度法测定毛酸浆中的总黄酮含量的方法,通过考察显色剂用量以及加入显色剂后放置时间对毛酸浆总黄酮测定的影响,采用单因素和正交试验优化硝酸铝-亚硝酸钠比色法测定毛酸浆果中总黄酮的含量。结果表明,毛酸浆中总黄酮含量测定的最佳的条件为：5%Na NO2溶液0.8 m L,混匀放置2 min后,加10%Al（NO3）3溶液0.8 m L,混匀,继续加4%Na OH溶液6 m L,定容混匀后立即在335 nm下测其吸光度。在此条件下,芦丁标准溶液在0~0.002 4 mg/m L范围内与吸光度值间的回归方程y=289.02x＋0.008,R2=0.999 5。该测定方法的平均加标回收率为100.83%,稳定性、精密度以及回收率的相对标准偏差（RSD）分别为0.34%,0.29%和2.91%。该方法简便、快速、准确,可以用于毛酸浆果汁中总黄酮含量的测定。
文摘安德森局域化是物理学中的一个基本现象,最初是安德森提出在晶体中电子受到杂质散射由于散射路径的相干导致电导完全消失,这完全来源于电子的波动特性,后来在其他各种波,如,光、微波、超声波,甚至是冷原子体系中都观察到安德森局域化现象。在晶体中,除电子外,还可能存在各种各样的磁激发准粒子,但是对于这些磁性准粒子的安德森局域化研究几乎没有。我们测量了苯甲酸铜Cu(C6H5COO)2·3H2O这个一维反铁磁海森堡链单晶的极低温比热和热导率,发现一直到50 m K的极低温,spinon磁性准粒子对比热都有一个恒定的线性贡献项Cs/T,但是其热导率的线性贡献项ks/T只保持不变到300 m K。在300m K以下,ks/T迅速减小,到100 m K以下就基本消失了。实验结果是spinon安德森局域化的一个较强的证据,为在凝聚态物理中研究安德森局域化现象开辟了一个新的窗口。
基金supported by the National Key Research and Development Program of China(Grant No.2022YFA1402203)the Shanghai Municipal Science and Technology Major Project(Grant No.2019SHZDZX01)+5 种基金supported by the National Key R&D Program of China(Grants No.2023YFA1406100)the Double First-Class Initiative Fund of ShanghaiTech Universitysupported by the National Natural Science Foundation of China(Grant No.52272265)supported by the National Science Basic Research Plan in the Shaanxi Province of China(Grant No.2024JC-YBQN-0390)supported by the open project from State Key Laboratory of Surface Physics and Department of Physics,Fudan University(Grant No.KF2022-13)supported by the National Natural Science Foundation of China(Grant No.52302010)。
文摘Exploration of exotic phenomena in magnetic topological systems is at the frontier of condensed matter physics,holding a significant promise for applications in topological spintronics.However,complex magnetic structures carrying nontrivial topological properties hinder its progresses.Here,we investigate the pressure effect on the novel topological kagome magnets GdV_(6)Sn_(6) and TbV_(6)Sn_(6) to dig out the interplay between magnetic Gd/Tb layers and nonmagnetic V-based kagome sublattice.The pressure-tuned magnetic transition temperature Tm in both the compounds exhibit a turning point at the critical pressure P_(c),accompanied with a sign reversal in anomalous Hall effect(AHE).The separation of intrinsic and extrinsic contributions using the Tian-Ye-Jin scaling model suggests that the intrinsic mechanism originating from the electronic Berry curvature holds the priority in the competition with extrinsic mechanism in AHE.The above-mentioned findings can be attributed to the combined effect of pressure-tuned band topology and magnetic interaction in segregated layers.Our results provide a practical route to design and manipulate the intrinsic AHE in magnetic topological materials.
