The title complex of nickel (II) with 3,5-dimethylbenzoic acid, m-methylbenzoic acid and 1,10- phenanthroline was synthesized and characterized. Crystal data for this complex: triclinic, space group P1, a=1.198 5(2) n...The title complex of nickel (II) with 3,5-dimethylbenzoic acid, m-methylbenzoic acid and 1,10- phenanthroline was synthesized and characterized. Crystal data for this complex: triclinic, space group P1, a=1.198 5(2) nm, b=1.315 3(2) nm, c=1.531 8(3) nm, α=92.602(3)°, β=103.292(3)°, γ=114.849(3)°, V=2.104 7(6) nm3, Dc=1.361 g·cm-3, Z=2, F(000)=902, final GooF=1.071, R1=0.067 2, wR2=0.155 5. The crystal structure shows that the nickel ion is coordinated with four nitrogen atoms of two 1,10-phenanthroline molecules and two oxygen atoms of one 3,5-dimethyl benzoic acid molecule, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex was also investigated. CCDC: 286966.展开更多
A complex [Mn(2,4-DAA)2(4,4'-bipy)]n with 2,4-dichlorophenoxy acetic acid and 4,4'-bipy has been synthesized and characterized. It crystallizes in the monoclinic space group C2/c with a=2.307 8(6) nm, b=1.164 ...A complex [Mn(2,4-DAA)2(4,4'-bipy)]n with 2,4-dichlorophenoxy acetic acid and 4,4'-bipy has been synthesized and characterized. It crystallizes in the monoclinic space group C2/c with a=2.307 8(6) nm, b=1.164 3(3) nm, c=0.970 9(3) nm, β=96.249(5)°, V=2.593 2(12) nm3, Dc=1.668 g·cm-3, Z=4, F(000)=1 316, Final GooF=1.032, R1=0.046 1, wR2=0.110 2. The crystal structure shows that the complex forms a 2D layer structure by bi-dentate bridging 2,4-dichlorophenoxy acetic acid groups and 4,4'-bipy molecules. The manganese(Ⅱ) ion is coordinated with four oxygen atoms from four 2,4-dichlorophenoxy acetic acid molecules and two nitrogen atoms of two 4,4'-bipy molecules, respectively, giving a distorted octahedral coordination geometry. The luminescence property of the complex was also studied. CCDC: 674225.展开更多
The title complex with benzilic acid and 1,10-phenanthroline monohydrate has been synthesized and characterized in the solvent mixture of water and methyl-alcohol. It falls into the triclinic, characteristic of the sp...The title complex with benzilic acid and 1,10-phenanthroline monohydrate has been synthesized and characterized in the solvent mixture of water and methyl-alcohol. It falls into the triclinic, characteristic of the space group P1 with a=1.142 8(3) nm, b=1.638 8(4) nm, c=1.645 6(4) nm, α=74.428(5)°, β=84.205(5)°, γ=74.917(5)°, V=2.864 9(12) nm3, Dc=1.347 g·cm-3. Z=2, F(000)=1 216, the reliability factor R1=0.068 9, wR2=0.189 9. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from the three phens, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 274184.展开更多
The crystal structure of the title complex with the stoichiometric formula Cu(PTA)(Phen)2 ( p-MBA)(H2O) (Phen=1,10-phenanthroline, PTA=terephthalic acid, p-MBA=p-toluic acid) has been determined by single-crystal X-ra...The crystal structure of the title complex with the stoichiometric formula Cu(PTA)(Phen)2 ( p-MBA)(H2O) (Phen=1,10-phenanthroline, PTA=terephthalic acid, p-MBA=p-toluic acid) has been determined by single-crystal X-ray diffraction. The crystal (C48H40CuN4O10, Mr=896.38) belongs to the monoclinic space group C2/c, with the following crystallographic parameters: a=1.778 6(3) nm, b=1.912 5(3) nm, c=1.389 9(2) nm, β=114.686(2)°, V=4.295 7(12) nm3, Dc=1.386 g·cm-3, Z=4, μ(Mo Kα)=0.574 mm-1, F(000)=1 860, final GooF=1.019, R=0.054 0, wR=0.148 3 for 2 644 observed reflections (I>2σ(I)). The crystal structure shows that the copper?髤 ion is coordinated with two oxygen atoms from one terephthalic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 298809.展开更多
One novel manganese(Ⅱ) complex [Mn2(α-Furacrylic radical)4(phen)2(H2O)]·H2O with α-furacrylic acid radical and 1,10-phenanthroline has been synthesized and characterized. Crystal data for this complex:monoclin...One novel manganese(Ⅱ) complex [Mn2(α-Furacrylic radical)4(phen)2(H2O)]·H2O with α-furacrylic acid radical and 1,10-phenanthroline has been synthesized and characterized. Crystal data for this complex:monoclinic,space group C2/c,a=1.082 34(16)nm,b=2.445 8(4) nm,c=1.857 4(3) nm,β=104.353(2)°,V=4.763 5(12) nm3,Dc=1.471 g·cm-3,Z=4,F(000)=2 168. Final GooF=1.004,R1=0.039 7,wR2=0.108 7. The crystal structure shows that two neighboring manganese(Ⅱ) ions are linked together by two bridging α-furacrylic acid radicals and one bridging water molecule,forming a cage structure. The Mn(1)…Mn(1A) bond distance is 0.357 6 nm. Each manganese(Ⅱ) ion is coordinated with two nitrogen atoms of one 1,10-phenanthroline molecule and four oxygen atoms from three α-furacrylic acid radicals and one water molecule,forming distorted octahedral coordination geometry. Thermal stability of the complex was also discussed.展开更多
The study of carboxyl complexes has drawn great interests,mainly because of their intriguing variety of architectures and topologies as well as potential applications in many fields,such as functional materials,bioche...The study of carboxyl complexes has drawn great interests,mainly because of their intriguing variety of architectures and topologies as well as potential applications in many fields,such as functional materials,biochemistry,medicine,and so展开更多
The complex {[Cd2(C9H8O3N)2(CH3COO)2(4,4'-bipy)2]·(4,4'-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4'-bipyridine has been synthesized with liquid diffusion method and characterized. It cry...The complex {[Cd2(C9H8O3N)2(CH3COO)2(4,4'-bipy)2]·(4,4'-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4'-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals,forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4'-bipy molecules and the complex molecule forms an one-dimensional doublechain structure. The luminescent properties of the complex were studied.展开更多
文摘The title complex of nickel (II) with 3,5-dimethylbenzoic acid, m-methylbenzoic acid and 1,10- phenanthroline was synthesized and characterized. Crystal data for this complex: triclinic, space group P1, a=1.198 5(2) nm, b=1.315 3(2) nm, c=1.531 8(3) nm, α=92.602(3)°, β=103.292(3)°, γ=114.849(3)°, V=2.104 7(6) nm3, Dc=1.361 g·cm-3, Z=2, F(000)=902, final GooF=1.071, R1=0.067 2, wR2=0.155 5. The crystal structure shows that the nickel ion is coordinated with four nitrogen atoms of two 1,10-phenanthroline molecules and two oxygen atoms of one 3,5-dimethyl benzoic acid molecule, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex was also investigated. CCDC: 286966.
文摘A complex [Mn(2,4-DAA)2(4,4'-bipy)]n with 2,4-dichlorophenoxy acetic acid and 4,4'-bipy has been synthesized and characterized. It crystallizes in the monoclinic space group C2/c with a=2.307 8(6) nm, b=1.164 3(3) nm, c=0.970 9(3) nm, β=96.249(5)°, V=2.593 2(12) nm3, Dc=1.668 g·cm-3, Z=4, F(000)=1 316, Final GooF=1.032, R1=0.046 1, wR2=0.110 2. The crystal structure shows that the complex forms a 2D layer structure by bi-dentate bridging 2,4-dichlorophenoxy acetic acid groups and 4,4'-bipy molecules. The manganese(Ⅱ) ion is coordinated with four oxygen atoms from four 2,4-dichlorophenoxy acetic acid molecules and two nitrogen atoms of two 4,4'-bipy molecules, respectively, giving a distorted octahedral coordination geometry. The luminescence property of the complex was also studied. CCDC: 674225.
文摘The title complex with benzilic acid and 1,10-phenanthroline monohydrate has been synthesized and characterized in the solvent mixture of water and methyl-alcohol. It falls into the triclinic, characteristic of the space group P1 with a=1.142 8(3) nm, b=1.638 8(4) nm, c=1.645 6(4) nm, α=74.428(5)°, β=84.205(5)°, γ=74.917(5)°, V=2.864 9(12) nm3, Dc=1.347 g·cm-3. Z=2, F(000)=1 216, the reliability factor R1=0.068 9, wR2=0.189 9. The crystal structure shows that the nickel atom is coordinated with six nitrogen atoms from the three phens, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 274184.
文摘The crystal structure of the title complex with the stoichiometric formula Cu(PTA)(Phen)2 ( p-MBA)(H2O) (Phen=1,10-phenanthroline, PTA=terephthalic acid, p-MBA=p-toluic acid) has been determined by single-crystal X-ray diffraction. The crystal (C48H40CuN4O10, Mr=896.38) belongs to the monoclinic space group C2/c, with the following crystallographic parameters: a=1.778 6(3) nm, b=1.912 5(3) nm, c=1.389 9(2) nm, β=114.686(2)°, V=4.295 7(12) nm3, Dc=1.386 g·cm-3, Z=4, μ(Mo Kα)=0.574 mm-1, F(000)=1 860, final GooF=1.019, R=0.054 0, wR=0.148 3 for 2 644 observed reflections (I>2σ(I)). The crystal structure shows that the copper?髤 ion is coordinated with two oxygen atoms from one terephthalic acid molecule and four nitrogen atoms from two 1,10-phenanthroline molecules, forming a distorted octahedral coordination geometry. The cyclic voltametric behavior of the complex is also reported. CCDC: 298809.
文摘One novel manganese(Ⅱ) complex [Mn2(α-Furacrylic radical)4(phen)2(H2O)]·H2O with α-furacrylic acid radical and 1,10-phenanthroline has been synthesized and characterized. Crystal data for this complex:monoclinic,space group C2/c,a=1.082 34(16)nm,b=2.445 8(4) nm,c=1.857 4(3) nm,β=104.353(2)°,V=4.763 5(12) nm3,Dc=1.471 g·cm-3,Z=4,F(000)=2 168. Final GooF=1.004,R1=0.039 7,wR2=0.108 7. The crystal structure shows that two neighboring manganese(Ⅱ) ions are linked together by two bridging α-furacrylic acid radicals and one bridging water molecule,forming a cage structure. The Mn(1)…Mn(1A) bond distance is 0.357 6 nm. Each manganese(Ⅱ) ion is coordinated with two nitrogen atoms of one 1,10-phenanthroline molecule and four oxygen atoms from three α-furacrylic acid radicals and one water molecule,forming distorted octahedral coordination geometry. Thermal stability of the complex was also discussed.
文摘The study of carboxyl complexes has drawn great interests,mainly because of their intriguing variety of architectures and topologies as well as potential applications in many fields,such as functional materials,biochemistry,medicine,and so
文摘The complex {[Cd2(C9H8O3N)2(CH3COO)2(4,4'-bipy)2]·(4,4'-bipy)·(H2O)4}n with 4-acetamidobenzoic acid and 4,4'-bipyridine has been synthesized with liquid diffusion method and characterized. It crystallizes in the monoclinic space group C2/c. The crystal structure shows that two neighboring cadmium(Ⅱ) ions are linked together by two bridging acetic acid radicals,forming a binuclear structure. Adjacent binnuclear structure is linked together by two bridging 4,4'-bipy molecules and the complex molecule forms an one-dimensional doublechain structure. The luminescent properties of the complex were studied.
