Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated d...Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated during the discharge process leads to energy waste and low energy utilization efficiency.In this work,an innovative DBD thermally-conducted catalysis(DBD-TCC)system,integrating high-frequency AC-DBD plasma and its generated thermal effects to activate the Co/SBA-15 catalyst,was employed for toluene removal.Specifically,Co/SBA-15 catalysts are closely positioned to the ground electrode of the plasma zone and can be heated and activated by the thermal effect when the voltage exceeds 10 k V.At12.4 k V,the temperature in the catalyst zone reached 261℃ in the DBD-TCC system,resulting in an increase in toluene degradation efficiency of 17%,CO_(2)selectivity of 21.2%,and energy efficiency of 27%,respectively,compared to the DBD system alone.In contrast,the DBD thermally-unconducted catalysis(DBD-TUC)system fails to enhance toluene degradation due to insufficient heat absorption and catalytic activation,highlighting the crucial role of AC-DBD generated heat in the activation of the catalyst.Furthermore,the degradation pathway and mechanism of toluene in the DBD-TCC system were hypothesized.This work is expected to provide an energy-efficient approach for high-frequency AC-DBD plasma removal of VOCs.展开更多
现代视频编码标准普遍采用变换与运动补偿预测混合型编码架构,该架构对运动补偿预测后的残差图像和运动矢量等信息进行变换编码,运动补偿预测的准确度对编码性能有显著影响.由于实际对象的运动精度是任意小的,允许运动矢量具有“分像素...现代视频编码标准普遍采用变换与运动补偿预测混合型编码架构,该架构对运动补偿预测后的残差图像和运动矢量等信息进行变换编码,运动补偿预测的准确度对编码性能有显著影响.由于实际对象的运动精度是任意小的,允许运动矢量具有“分像素”精度,可以有效地提高运动补偿预测准确度,为了得到“分像素”位置的像素值,需要参考其周围相邻的像素值进行插值滤波.文中提出了一种低空间复杂度1/4像素插值方法两步四抽头插值法(Two Steps Four Taps Interpolation,TSFT),该方法与目前国际上最先进的视频编码标准H.264/AVC相比,可以降低11%的空间复杂度,计算复杂度和编码效率相当,已经被国内制定的编码标准AVS1.0采纳.另外,分像素插值是解码端主要的访存和计算瓶颈,文中给出了一个基于多级流水线结构的VLSI实现结构,可以降低访存带宽,同时提高插值器的运算速度,满足高清视频实时解码的需要.展开更多
A new hydroxyl-functionalized ionic liquid(HIILsBr) supported on MCM-41 was prepared by grafting HIILsBr onto porous MCM-41 with 3-chloropyltriethoxysilane.It was found that the immobilization condition had an obvious...A new hydroxyl-functionalized ionic liquid(HIILsBr) supported on MCM-41 was prepared by grafting HIILsBr onto porous MCM-41 with 3-chloropyltriethoxysilane.It was found that the immobilization condition had an obvious effect on the activity of catalyst.The immobilization time,immobilization temperature,ratio of ILs to carrier and solvent had an important effect on the performance of HIILs/MCM-41.In order to obtain optimum immobilization stability,the immobilization condition must be kept at a proper temperature,time,ratio of ILs to carrier range and with a proper solvent.Its performance for the synthesis of propylene carbonate(PC)from CO2 and propylene oxide was also investigated.Under the reaction condition(115℃,2.0 MPa,4 h),the yield of PC was 89.9% and the selectivity of PC was 99.5%.展开更多
基金supported by National Natural Science Foundation of China(No.52177130)the Key Projects for Industrial Prospects and Core Technology Research in Suzhou City(No.SYC2022029)。
文摘Dielectric barrier discharge(DBD)plasma excited by a high-frequency alternating-current(AC)power supply is widely employed for the degradation of volatile organic compounds(VOCs).However,the thermal effect generated during the discharge process leads to energy waste and low energy utilization efficiency.In this work,an innovative DBD thermally-conducted catalysis(DBD-TCC)system,integrating high-frequency AC-DBD plasma and its generated thermal effects to activate the Co/SBA-15 catalyst,was employed for toluene removal.Specifically,Co/SBA-15 catalysts are closely positioned to the ground electrode of the plasma zone and can be heated and activated by the thermal effect when the voltage exceeds 10 k V.At12.4 k V,the temperature in the catalyst zone reached 261℃ in the DBD-TCC system,resulting in an increase in toluene degradation efficiency of 17%,CO_(2)selectivity of 21.2%,and energy efficiency of 27%,respectively,compared to the DBD system alone.In contrast,the DBD thermally-unconducted catalysis(DBD-TUC)system fails to enhance toluene degradation due to insufficient heat absorption and catalytic activation,highlighting the crucial role of AC-DBD generated heat in the activation of the catalyst.Furthermore,the degradation pathway and mechanism of toluene in the DBD-TCC system were hypothesized.This work is expected to provide an energy-efficient approach for high-frequency AC-DBD plasma removal of VOCs.
文摘现代视频编码标准普遍采用变换与运动补偿预测混合型编码架构,该架构对运动补偿预测后的残差图像和运动矢量等信息进行变换编码,运动补偿预测的准确度对编码性能有显著影响.由于实际对象的运动精度是任意小的,允许运动矢量具有“分像素”精度,可以有效地提高运动补偿预测准确度,为了得到“分像素”位置的像素值,需要参考其周围相邻的像素值进行插值滤波.文中提出了一种低空间复杂度1/4像素插值方法两步四抽头插值法(Two Steps Four Taps Interpolation,TSFT),该方法与目前国际上最先进的视频编码标准H.264/AVC相比,可以降低11%的空间复杂度,计算复杂度和编码效率相当,已经被国内制定的编码标准AVS1.0采纳.另外,分像素插值是解码端主要的访存和计算瓶颈,文中给出了一个基于多级流水线结构的VLSI实现结构,可以降低访存带宽,同时提高插值器的运算速度,满足高清视频实时解码的需要.
文摘A new hydroxyl-functionalized ionic liquid(HIILsBr) supported on MCM-41 was prepared by grafting HIILsBr onto porous MCM-41 with 3-chloropyltriethoxysilane.It was found that the immobilization condition had an obvious effect on the activity of catalyst.The immobilization time,immobilization temperature,ratio of ILs to carrier and solvent had an important effect on the performance of HIILs/MCM-41.In order to obtain optimum immobilization stability,the immobilization condition must be kept at a proper temperature,time,ratio of ILs to carrier range and with a proper solvent.Its performance for the synthesis of propylene carbonate(PC)from CO2 and propylene oxide was also investigated.Under the reaction condition(115℃,2.0 MPa,4 h),the yield of PC was 89.9% and the selectivity of PC was 99.5%.
