Tri-n-butyl phosphate（TBP）dissolved in kerosene was chosen as extractant for lithium from a modelbrine having high magnesium-to-lithium ratio and ferric chloride was added to the system.The influences of con-tact ti...Tri-n-butyl phosphate（TBP）dissolved in kerosene was chosen as extractant for lithium from a modelbrine having high magnesium-to-lithium ratio and ferric chloride was added to the system.The influences of con-tact time,concentration of the extractant,concentrations of some salts(Mg<sup>2+</sup>, Na<sup>+</sup>,K<sup>+</sup>)in the solution,acid-ity of hydrochloric acid and extraction temperature on the exttaction of lithium with TBP-kerosene system werestudied.The suitable extraction conditions were found to be:contact time not any less than 20min;at 20-25C;[Fe<sup>+3</sup>]/[Li<sup>+</sup>]about 1.5-2.0;TBP concentration 50%-70%;[MgCl<sub>2</sub>]exceeding 3 mol·L<sup>-1</sup>;pH about 2;while most sodium and potassium salts in the aqueous phase should be removed before the extraction.展开更多
The binary solubilities of tetraethylene glycol (TTEG) with benzene, toluene or p xylene, were measured by the turbidity point method. In TTEG the content of water ranged from 0 to 5% and the test temperature ran...The binary solubilities of tetraethylene glycol (TTEG) with benzene, toluene or p xylene, were measured by the turbidity point method. In TTEG the content of water ranged from 0 to 5% and the test temperature ranged from 20℃ to 120℃. Increasing the temperature resulted in greater solubility of the aromatics in TTEG, while increasing the content of water caused the aromatic solubility to decrease. The benzene solubillity in TTEG was the greatest followed by toluene and xylene at the same water content and temperature. The mutual solubility was predicted by correlating the paramaters of a new group for the UNIFAC model for the aromatics extraction system. The modified UNIFAC group contribution model was used to predict the binary solubility of TTEG and aromatics. The average deviation between the experimental result and prediction is 4.06%. Therefore, the UNIFAC model can be used to describe the solubility phenomena for TTEG aromatics systems.展开更多
文摘Tri-n-butyl phosphate（TBP）dissolved in kerosene was chosen as extractant for lithium from a modelbrine having high magnesium-to-lithium ratio and ferric chloride was added to the system.The influences of con-tact time,concentration of the extractant,concentrations of some salts(Mg<sup>2+</sup>, Na<sup>+</sup>,K<sup>+</sup>)in the solution,acid-ity of hydrochloric acid and extraction temperature on the exttaction of lithium with TBP-kerosene system werestudied.The suitable extraction conditions were found to be:contact time not any less than 20min;at 20-25C;[Fe<sup>+3</sup>]/[Li<sup>+</sup>]about 1.5-2.0;TBP concentration 50%-70%;[MgCl<sub>2</sub>]exceeding 3 mol·L<sup>-1</sup>;pH about 2;while most sodium and potassium salts in the aqueous phase should be removed before the extraction.
文摘The binary solubilities of tetraethylene glycol (TTEG) with benzene, toluene or p xylene, were measured by the turbidity point method. In TTEG the content of water ranged from 0 to 5% and the test temperature ranged from 20℃ to 120℃. Increasing the temperature resulted in greater solubility of the aromatics in TTEG, while increasing the content of water caused the aromatic solubility to decrease. The benzene solubillity in TTEG was the greatest followed by toluene and xylene at the same water content and temperature. The mutual solubility was predicted by correlating the paramaters of a new group for the UNIFAC model for the aromatics extraction system. The modified UNIFAC group contribution model was used to predict the binary solubility of TTEG and aromatics. The average deviation between the experimental result and prediction is 4.06%. Therefore, the UNIFAC model can be used to describe the solubility phenomena for TTEG aromatics systems.
