The effect of Nb addition on the microstructure and magnetic properties of nanocrystaUine Sm(CobaiNbxZr0.02)7 permanent magnet were investigated, The magnetization reversal behavior for ball milled Sm(CobaiNbxZr0.0...The effect of Nb addition on the microstructure and magnetic properties of nanocrystaUine Sm(CobaiNbxZr0.02)7 permanent magnet were investigated, The magnetization reversal behavior for ball milled Sm(CobaiNbxZr0.02)7 samples with high coercivity was investigated by analyzing hysteresis curves and recoil loops of demagnetization curves. Nb addition proved to result in relevant improvement in the magnetic properties, especially in the coercivity He. It was shown that the magnetic properties of Sm(CobalNbx- Zr0.02)7 nanocrystalline magnets were improved by an additional 0.06 at.% Nb. In particular, Hc was improved from 602 to 786 kA/m at room temperature. The maximum value of the integrated recoil loops area for 0.06 at.% Nb-doped samples of 1.81 kJ/m3 was much lower than that of the Nb-free sample, which could be explained by a smaller recoverable portion of the magnetization remaining in the Nb-doped sample when the applied field was below the coercivity Hc. The nucleation field Hn for irreversible magnetization reversal of the magnetically hard phase were calculated by analyzed in terms of the△Mirrev-H curve and the Kondorsky model.展开更多
基金supported by the Natural Science Foundation of Zhejiang Province(LQ15E010005LR15E010001)+3 种基金National Natural Science Foundation of China(510010926137902751371163 and 51301158)the National Public Interest Research Special Fund(201210107)
文摘The effect of Nb addition on the microstructure and magnetic properties of nanocrystaUine Sm(CobaiNbxZr0.02)7 permanent magnet were investigated, The magnetization reversal behavior for ball milled Sm(CobaiNbxZr0.02)7 samples with high coercivity was investigated by analyzing hysteresis curves and recoil loops of demagnetization curves. Nb addition proved to result in relevant improvement in the magnetic properties, especially in the coercivity He. It was shown that the magnetic properties of Sm(CobalNbx- Zr0.02)7 nanocrystalline magnets were improved by an additional 0.06 at.% Nb. In particular, Hc was improved from 602 to 786 kA/m at room temperature. The maximum value of the integrated recoil loops area for 0.06 at.% Nb-doped samples of 1.81 kJ/m3 was much lower than that of the Nb-free sample, which could be explained by a smaller recoverable portion of the magnetization remaining in the Nb-doped sample when the applied field was below the coercivity Hc. The nucleation field Hn for irreversible magnetization reversal of the magnetically hard phase were calculated by analyzed in terms of the△Mirrev-H curve and the Kondorsky model.