Hydrothermal reaction of MgCl2 and ethyl tetrazolate-5-carboxylate at 160 ℃unexpectedly yielded compound {（H3O）[Mg（H2O）6]Cl3} （1）. The result of X-ray diffraction analysis indicates that 1 crystallizes in the m...Hydrothermal reaction of MgCl2 and ethyl tetrazolate-5-carboxylate at 160 ℃unexpectedly yielded compound {（H3O）[Mg（H2O）6]Cl3} （1）. The result of X-ray diffraction analysis indicates that 1 crystallizes in the monoclinic system, space group C2/c with a = 9.2896（3）, b = 9.5570（4）, c = 13.3169（5） A, β = 90.1221（12）°, V= 1182.28（8） A3, Z = 4, Mr = 257.78, Dc = 1.448 g/cm3, μ = 0.824 mm^-1, F（000） = 536, R = 0.0265 and wR - 0.0706. 1 is composed of one hexa-aqua-magnesium（Ⅱ） ion, one hydroxonium ion, and three chlorine anions. These three components weave a perfect three-dimensional （3D） （4,4,6,12）-connected hydrogen bonding network within 1.展开更多
基金Supported by the Youth Foundation of Jiangxi Provincial Office of Education (GJJ09605)the Science Foundation of Jiangxi Provincial Office of Education (GJJ09637)
文摘Hydrothermal reaction of MgCl2 and ethyl tetrazolate-5-carboxylate at 160 ℃unexpectedly yielded compound {（H3O）[Mg（H2O）6]Cl3} （1）. The result of X-ray diffraction analysis indicates that 1 crystallizes in the monoclinic system, space group C2/c with a = 9.2896（3）, b = 9.5570（4）, c = 13.3169（5） A, β = 90.1221（12）°, V= 1182.28（8） A3, Z = 4, Mr = 257.78, Dc = 1.448 g/cm3, μ = 0.824 mm^-1, F（000） = 536, R = 0.0265 and wR - 0.0706. 1 is composed of one hexa-aqua-magnesium（Ⅱ） ion, one hydroxonium ion, and three chlorine anions. These three components weave a perfect three-dimensional （3D） （4,4,6,12）-connected hydrogen bonding network within 1.
