Bis{2-[(2,4-dichloro-phenytimino)-methyl]-4,6-diiodo-phenol}-copper(II) (1) has been synthesized and its structure determined by X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n wit...Bis{2-[(2,4-dichloro-phenytimino)-methyl]-4,6-diiodo-phenol}-copper(II) (1) has been synthesized and its structure determined by X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n with a = 14.7558(17), b = 20.770(2), c = 20.3260(19) A, β = 90.6110(10)°, V= 6229.2(11) A3 and Z = 8. The Cu atom is surrounded by two O atoms and two N atoms from two 2-[(2,4-diehloro-phenylimino)-methyl]-4,6-diiodo-phenol molecules to form a tetrahedral coordination environment. The complex is linked into a column by weak intermolecular interactions.展开更多
基金National Natural Science Foundation of China (Projects 30772627)a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions, China
文摘Bis{2-[(2,4-dichloro-phenytimino)-methyl]-4,6-diiodo-phenol}-copper(II) (1) has been synthesized and its structure determined by X-ray diffraction. It crystallizes in the monoclinic system, space group P21/n with a = 14.7558(17), b = 20.770(2), c = 20.3260(19) A, β = 90.6110(10)°, V= 6229.2(11) A3 and Z = 8. The Cu atom is surrounded by two O atoms and two N atoms from two 2-[(2,4-diehloro-phenylimino)-methyl]-4,6-diiodo-phenol molecules to form a tetrahedral coordination environment. The complex is linked into a column by weak intermolecular interactions.