本文利用同步辐射真空紫外和超声分子束反射式飞行时间质谱系统研究间二甲苯的光电离和离解光电离.通过测定母体离子C_(8)H_(10)^(+)和主要碎片离子(C_(8)H_(9)^(+)和C_(7)H_(7)^(+))的光电离效率谱,确定了母体分子的电离能和主要碎片离...本文利用同步辐射真空紫外和超声分子束反射式飞行时间质谱系统研究间二甲苯的光电离和离解光电离.通过测定母体离子C_(8)H_(10)^(+)和主要碎片离子(C_(8)H_(9)^(+)和C_(7)H_(7)^(+))的光电离效率谱,确定了母体分子的电离能和主要碎片离子(C_(8)H_(8)^(+)和C_(7)H_(7)^(+))的出现势分别为8.60±0.03 eV,11.76±0.04 eV和11.85±0.05 eV eV.在B3LYP/6-311++G(d,p)水平上优化了两个主要解离通道的反应物、过渡态、中间体和产物的结构,并在G3水平上计算了它们的能量,以及两个主要的离解光电离通道产物C_(7)H_(7)^(+)+CH_(3)和C_(8)H_(9)^(+)+H的能量.结合理论和实验结果,间二甲苯的离解光电离机理主要过程是C-H键或C-C键的离解和氢迁移.展开更多
Enhancements of edge zonal flows,radial electric fields,and turbulence are observed in electron cyclotron resonance heating-heated plasmas(Zhao et al 2013 Nucl.Fusion 53083011).In this paper,the effects of sawtooth he...Enhancements of edge zonal flows,radial electric fields,and turbulence are observed in electron cyclotron resonance heating-heated plasmas(Zhao et al 2013 Nucl.Fusion 53083011).In this paper,the effects of sawtooth heat pulses on flows and turbulence are presented.These experiments are performed using multiple Langmuir probe arrays in the edge plasmas of the HL-2A tokamak.The edge zonal flows,radial electric fields,and turbulence are all enhanced by sawteeth.Propagation of the zonal flow and turbulence intensities is also observed.The delay time of the maximal intensity of the electric fields,zonal flows,and turbulence with respect to the sawtooth crashes is estimated as~1 ms and comparable to that of the sawtooth-triggered intermediate phases.Not only the zonal flows but also the radial electric fields lag behind the turbulence.Furthermore,the intensities of both the zonal flows and electric fields nearly linearly increase/decrease with the increase/decrease of the turbulence intensity.A double-source predator-prey model analysis suggests that a relatively strong turbulence source may contribute to the dominant zonal flow formation during sawtooth cycles.展开更多
A hot cathode bucket ion source is used for the EAST（experimental advanced superconducting tokamak）neutral beam injector.The thermal electrons emitted from the surface of the cathode are extracted and accelerated by...A hot cathode bucket ion source is used for the EAST（experimental advanced superconducting tokamak）neutral beam injector.The thermal electrons emitted from the surface of the cathode are extracted and accelerated by the electric field formed by the arc voltage,which is applied between the arc chamber of the ion source and the cathode.This paper analyzes the effects of arc voltage on the arc discharge in a hot cathode high current ion source.展开更多
基金This work was supported by the National Natural Science Foundation of China(No.11275006,No.12105042,No.11805032,No.11505027,No.11575178,No.U1532137)Nuclear Technology Application Engineering Research Center Open Foundation of Ministry of Education(No.HJSJYB2015-6,No.HJSJYB2017-1,HJSJYB2018-6)+4 种基金the Chinese Scholarship Council(No.201608360053)the Graduate Students High-Quality Course Construction Program of Jiangxi Province(No.JXYYK2016-12)the China Postdoctoral Science Foundation(No.2013M531530)the Doctoral Foundation of East China University of Technology(No.DHBK201401,No.DHBK2018059)the Provincial Natural Science Research Program of Higher Education Institutions of Anhui Province(No.KJ2012B086).
文摘本文利用同步辐射真空紫外和超声分子束反射式飞行时间质谱系统研究间二甲苯的光电离和离解光电离.通过测定母体离子C_(8)H_(10)^(+)和主要碎片离子(C_(8)H_(9)^(+)和C_(7)H_(7)^(+))的光电离效率谱,确定了母体分子的电离能和主要碎片离子(C_(8)H_(8)^(+)和C_(7)H_(7)^(+))的出现势分别为8.60±0.03 eV,11.76±0.04 eV和11.85±0.05 eV eV.在B3LYP/6-311++G(d,p)水平上优化了两个主要解离通道的反应物、过渡态、中间体和产物的结构,并在G3水平上计算了它们的能量,以及两个主要的离解光电离通道产物C_(7)H_(7)^(+)+CH_(3)和C_(8)H_(9)^(+)+H的能量.结合理论和实验结果,间二甲苯的离解光电离机理主要过程是C-H键或C-C键的离解和氢迁移.
基金National Natural Science Foundation of China(Nos.12075057,11775069,11320101005,and 11875020)National Magnetic Confinement Fusion Science Program of China(No.2017YFE0301201)+3 种基金East China University of Technology,Doctoral Foundation(Nos.DHBK 2017134 and DHBK 2018059)Grant-in-Aid for Scientific Research of the Japan Society for the Promotion of Science(Nos.15H02155,15H02335,21K03513)Landmark Achievements in Nuclear Science and Technology(No.xxkjs2018011)Natural Science Foundation of Jiangxi Province(Nos.20202ACBL201002 and 0192ACB80006)。
文摘Enhancements of edge zonal flows,radial electric fields,and turbulence are observed in electron cyclotron resonance heating-heated plasmas(Zhao et al 2013 Nucl.Fusion 53083011).In this paper,the effects of sawtooth heat pulses on flows and turbulence are presented.These experiments are performed using multiple Langmuir probe arrays in the edge plasmas of the HL-2A tokamak.The edge zonal flows,radial electric fields,and turbulence are all enhanced by sawteeth.Propagation of the zonal flow and turbulence intensities is also observed.The delay time of the maximal intensity of the electric fields,zonal flows,and turbulence with respect to the sawtooth crashes is estimated as~1 ms and comparable to that of the sawtooth-triggered intermediate phases.Not only the zonal flows but also the radial electric fields lag behind the turbulence.Furthermore,the intensities of both the zonal flows and electric fields nearly linearly increase/decrease with the increase/decrease of the turbulence intensity.A double-source predator-prey model analysis suggests that a relatively strong turbulence source may contribute to the dominant zonal flow formation during sawtooth cycles.
基金supported by the National Magnetic Confinement Fusion Science Program of China(No.2013GB101000)National Natural Science Foundation of China(No.11405207)
文摘A hot cathode bucket ion source is used for the EAST（experimental advanced superconducting tokamak）neutral beam injector.The thermal electrons emitted from the surface of the cathode are extracted and accelerated by the electric field formed by the arc voltage,which is applied between the arc chamber of the ion source and the cathode.This paper analyzes the effects of arc voltage on the arc discharge in a hot cathode high current ion source.
