The synthesis, composition optimization, VUV Photoluminescence (PL) spectra, and optical properties, of (Y,Gd)(V,P)O4∶Eu3+ phosphors were investigated by synchrotron radiation. The VUV PLE spectra and the correlation...The synthesis, composition optimization, VUV Photoluminescence (PL) spectra, and optical properties, of (Y,Gd)(V,P)O4∶Eu3+ phosphors were investigated by synchrotron radiation. The VUV PLE spectra and the correlation among VUV PL intensity, λem, and Eu3+, Gd3+, and P-content were established. The PLE spectral studies showed that (Y,Gd)(V,P)O4∶Eu3+ exhibited significant absorption in the VUV range. The VUV PL intensity was found to enhance with PO43- and Gd3+-doping. Furthermore, the chromaticity characteristics of (Y,Gd)(V,P)O4∶Eu3+ were also found to be (0.6614, 0.3286) and compared against (Y, Gd)BO3∶Eu3+ as a reference. Based on the characterization results, we are currently improving and evaluating the potential application of (Y,Gd)(V,P)O4∶Eu3+ as a new red-emitting PDP phosphor.展开更多
In an effort to develop new green-emitting PDP phosphors with high efficiency, investigated were the synthesis, VUV photoluminescence (PL) spectra, optical properties, and chromaticity of Ca(La1-x-yTbxGdy. )4Si3O13 ph...In an effort to develop new green-emitting PDP phosphors with high efficiency, investigated were the synthesis, VUV photoluminescence (PL) spectra, optical properties, and chromaticity of Ca(La1-x-yTbxGdy. )4Si3O13 phosphors by using synchrotron radiation. Upon analysis of the VUV spectroscopic and chromaticity investigations on the new greenemitting VUV phosphors, were an optimized composition achieved. The PLE spectral studies show that Ca ( La1-x-y TbxGdy)4Si3O13 exhibit significant absorption in the VUV range. The VUV PL intensity was found to enhance with Gd3+-doping. Furthermore, the 1931 CIE chromaticity coordinates of Ca(La,Gd)4Si3O13:Tb were found to be (0.286, 0.548), as compared to (0.230, 0.712) for Zn2SiP4:Mn2+ as a reference. The potential application of Ca(La,Gd)4Si3O13:Tb as a new green-emitting PDP phosphor are being currently improving and evaluating.展开更多
The goal of this work was aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic cells by using the solar spectral conversion principle, which employs an up-conversion phosph...The goal of this work was aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic cells by using the solar spectral conversion principle, which employs an up-conversion phosphor to convert a low energy infrared photon to the more energetic visible photons to improve the spectral response. In this study, the surface of multicrystalline silicon solar cells was coated with an up-conversion molybdate phosphor to improve the spectral response of the solar cell in the near-infrared spectral range. The short circuit current （Isc）, open circuit voltage （Voc）, and conversion efficiency （η） of spectral conversion cells were measured. Preliminary experimental results revealed that the light conversion efficiency of a 1.5%–2.7% increase in Si-based cell was achieved.展开更多
The goal of this work is aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic （PV） cells by using the solar spectral conversion principle, which employed a down-convertin...The goal of this work is aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic （PV） cells by using the solar spectral conversion principle, which employed a down-converting phosphor to convert a high-energy ultraviolet photon to the less energetic red-emitting photons to improve the spectral response of Si solar cells. In this study, the surface of silicon solar cells was coated with a red-emitting KCaGd（PO4）2：Eu3＋ phosphor by using the screen-printing technique. In addition to the investigation on the microstructure using scanning electron microscopy （SEM）, we measured the short circuit current （Isc）, open circuit voltage （Voc）, and power conversion efficiency （η） of spectral-conversion cells and compared with those of bare solar cells as a reference. Preliminary experimental results revealed that in an optimized PV cell, an enhancement of （0.64＋0.01）% （from 16.03% to 16.67%） in Δη of a Si-based PV cell was achieved.展开更多
The effects of strontium aluminates of SrAl2O4：Eu2＋,Dy3＋（SAED） and boron-modified SAED （BSAED） phases synthesized from a sol-gel process on thermoluminescence （TL） along with their afterglow properties were s...The effects of strontium aluminates of SrAl2O4：Eu2＋,Dy3＋（SAED） and boron-modified SAED （BSAED） phases synthesized from a sol-gel process on thermoluminescence （TL） along with their afterglow properties were systematically investigated with thermal activation in the different atmospheres. The result showed that the addition of boron and the reduction routes of Eu3＋to Eu2＋ in SrAl2O4：Dy3＋were related to phosphorescent decay properties. The aid of Dy3＋to induce the hole-trapping effect required both SAED and BSAED to be heated at 1300°C under the H2/N2（5%：95%） atmosphere. However, the trapping behavior of the reductions of SAED in nitrogen was similar to the compound without Dy3＋co-doping SrAl2O4：Eu2＋ （SAE） in H2/N2（5%：95%）. BSAED showed deeper traps in situ compared to SAED which contained no boron, and this led to the better afterglow properties of BSAED than those of SAED. The afterglow spectrum of BSAED showed two peaks at 400±1 nm and 485±1 nm, which were two individuals composed and contributed from different depths of traps at 0.57 and 0.76eV, accordingly. The depth of the traps was calculated from the Hoogenstraaten’s plot of glow curves. The calculations for SAED and SAE were at around 0.43 and 0.18eV, respectively.展开更多
基金the National Science Council of Taiwan (NSC95 -2113-M-009-024-MY3)
文摘The synthesis, composition optimization, VUV Photoluminescence (PL) spectra, and optical properties, of (Y,Gd)(V,P)O4∶Eu3+ phosphors were investigated by synchrotron radiation. The VUV PLE spectra and the correlation among VUV PL intensity, λem, and Eu3+, Gd3+, and P-content were established. The PLE spectral studies showed that (Y,Gd)(V,P)O4∶Eu3+ exhibited significant absorption in the VUV range. The VUV PL intensity was found to enhance with PO43- and Gd3+-doping. Furthermore, the chromaticity characteristics of (Y,Gd)(V,P)O4∶Eu3+ were also found to be (0.6614, 0.3286) and compared against (Y, Gd)BO3∶Eu3+ as a reference. Based on the characterization results, we are currently improving and evaluating the potential application of (Y,Gd)(V,P)O4∶Eu3+ as a new red-emitting PDP phosphor.
基金Project supported by National Science Council of Taiwan, R.O.C. (NSC94-2113-M-009-001)
文摘In an effort to develop new green-emitting PDP phosphors with high efficiency, investigated were the synthesis, VUV photoluminescence (PL) spectra, optical properties, and chromaticity of Ca(La1-x-yTbxGdy. )4Si3O13 phosphors by using synchrotron radiation. Upon analysis of the VUV spectroscopic and chromaticity investigations on the new greenemitting VUV phosphors, were an optimized composition achieved. The PLE spectral studies show that Ca ( La1-x-y TbxGdy)4Si3O13 exhibit significant absorption in the VUV range. The VUV PL intensity was found to enhance with Gd3+-doping. Furthermore, the 1931 CIE chromaticity coordinates of Ca(La,Gd)4Si3O13:Tb were found to be (0.286, 0.548), as compared to (0.230, 0.712) for Zn2SiP4:Mn2+ as a reference. The potential application of Ca(La,Gd)4Si3O13:Tb as a new green-emitting PDP phosphor are being currently improving and evaluating.
基金Project supported by National Science Council of Taiwan (NSC98-2113-M-009-005-MY3)
文摘The goal of this work was aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic cells by using the solar spectral conversion principle, which employs an up-conversion phosphor to convert a low energy infrared photon to the more energetic visible photons to improve the spectral response. In this study, the surface of multicrystalline silicon solar cells was coated with an up-conversion molybdate phosphor to improve the spectral response of the solar cell in the near-infrared spectral range. The short circuit current （Isc）, open circuit voltage （Voc）, and conversion efficiency （η） of spectral conversion cells were measured. Preliminary experimental results revealed that the light conversion efficiency of a 1.5%–2.7% increase in Si-based cell was achieved.
基金Project supported by National Science Council of Taiwan (NSC98-2113-M-009-005-MY3)
文摘The goal of this work is aimed to improve the power conversion efficiency of single crystalline silicon-based photovoltaic （PV） cells by using the solar spectral conversion principle, which employed a down-converting phosphor to convert a high-energy ultraviolet photon to the less energetic red-emitting photons to improve the spectral response of Si solar cells. In this study, the surface of silicon solar cells was coated with a red-emitting KCaGd（PO4）2：Eu3＋ phosphor by using the screen-printing technique. In addition to the investigation on the microstructure using scanning electron microscopy （SEM）, we measured the short circuit current （Isc）, open circuit voltage （Voc）, and power conversion efficiency （η） of spectral-conversion cells and compared with those of bare solar cells as a reference. Preliminary experimental results revealed that in an optimized PV cell, an enhancement of （0.64＋0.01）% （from 16.03% to 16.67%） in Δη of a Si-based PV cell was achieved.
基金Project supported by Industrial Technology Research Institute
文摘The effects of strontium aluminates of SrAl2O4：Eu2＋,Dy3＋（SAED） and boron-modified SAED （BSAED） phases synthesized from a sol-gel process on thermoluminescence （TL） along with their afterglow properties were systematically investigated with thermal activation in the different atmospheres. The result showed that the addition of boron and the reduction routes of Eu3＋to Eu2＋ in SrAl2O4：Dy3＋were related to phosphorescent decay properties. The aid of Dy3＋to induce the hole-trapping effect required both SAED and BSAED to be heated at 1300°C under the H2/N2（5%：95%） atmosphere. However, the trapping behavior of the reductions of SAED in nitrogen was similar to the compound without Dy3＋co-doping SrAl2O4：Eu2＋ （SAE） in H2/N2（5%：95%）. BSAED showed deeper traps in situ compared to SAED which contained no boron, and this led to the better afterglow properties of BSAED than those of SAED. The afterglow spectrum of BSAED showed two peaks at 400±1 nm and 485±1 nm, which were two individuals composed and contributed from different depths of traps at 0.57 and 0.76eV, accordingly. The depth of the traps was calculated from the Hoogenstraaten’s plot of glow curves. The calculations for SAED and SAE were at around 0.43 and 0.18eV, respectively.
