1-Butylbenzimidazole L reacted with Cd（NO3）2·4H2O to afford complex [CdL（NO3）3H2O]·[HL] 1. The heptacoordinated Cd（Ⅱ） center adopts a distorted pentagongal bipyramidal geometry, and complex [CdL（NO3...1-Butylbenzimidazole L reacted with Cd（NO3）2·4H2O to afford complex [CdL（NO3）3H2O]·[HL] 1. The heptacoordinated Cd（Ⅱ） center adopts a distorted pentagongal bipyramidal geometry, and complex [CdL（NO3）3H2O]-entity and the protonated benzimidazium salt [HL]＋ are connected via N–H···O hydrogen bond to form a dimeric unit [CdL（NO3）3H2O]·[HL]. A 3-D supramolecular network of 1 is formed through N–H···O and O–H···O hydrogen bonds together with π-π stacking interactions. Reaction of L with CuCl2 afforded a mononuclear complex, [CuL2Cl2] 2, in which the tetracoordinated Cu（II） center adopts a distorted tetrahedral geometry. In contrast, 2-D supramolecular layers of 2 are formed by C–H···Cl hydrogen bonds. The fluorescent emission spectra of L, 1 and 2 are described.展开更多
基金Supported by the National Natural Science Foundation of China (No. 20872111)Natural Science Foundation of Tianjin (07JCYBJC00300)
文摘1-Butylbenzimidazole L reacted with Cd（NO3）2·4H2O to afford complex [CdL（NO3）3H2O]·[HL] 1. The heptacoordinated Cd（Ⅱ） center adopts a distorted pentagongal bipyramidal geometry, and complex [CdL（NO3）3H2O]-entity and the protonated benzimidazium salt [HL]＋ are connected via N–H···O hydrogen bond to form a dimeric unit [CdL（NO3）3H2O]·[HL]. A 3-D supramolecular network of 1 is formed through N–H···O and O–H···O hydrogen bonds together with π-π stacking interactions. Reaction of L with CuCl2 afforded a mononuclear complex, [CuL2Cl2] 2, in which the tetracoordinated Cu（II） center adopts a distorted tetrahedral geometry. In contrast, 2-D supramolecular layers of 2 are formed by C–H···Cl hydrogen bonds. The fluorescent emission spectra of L, 1 and 2 are described.
