A mathematical model to describe the enzyme reaction, mass transfer and heat effects in the calorimetric system is discussed. The model is based on non-stationary diffusion Equation containing a nonlinear term related...A mathematical model to describe the enzyme reaction, mass transfer and heat effects in the calorimetric system is discussed. The model is based on non-stationary diffusion Equation containing a nonlinear term related to immobilize liver esterase by flow calorimetry. This paper presents the complex numerical methods (Adomian decomposition method, Homotopy analysis and perturbation method) to solve the non-linear differential Equations that depict the diffusion coupled with a non-linear reaction terms. Approximate analytical expressions for substrate concentration have been derived for all values of parameters α, β and γE. These analytical results are compared with the available numerical results and are found to be in good agreement.展开更多
The nonlinear coupled system of diffusion equations are solved analytically for the transport and kinetics of electrons and reactant in the layer of a modified electrode. Analytical expressions of concentrations of su...The nonlinear coupled system of diffusion equations are solved analytically for the transport and kinetics of electrons and reactant in the layer of a modified electrode. Analytical expressions of concentrations of substrate and mediator are presented using He’s variational iteration method. The approximate expression of current for microheterogeneous catalysis at isonomer or redox polymer modified electrodes is also obtained. The results of the available limiting cases are compared with our results and are found to be in good agreement.展开更多
A mathematical modelling by a biofilm under steady state conditions is discussed. The nonlinear differential Equations in biofilm reaction is solved using the Adomian decomposition method. Approximate analytical expre...A mathematical modelling by a biofilm under steady state conditions is discussed. The nonlinear differential Equations in biofilm reaction is solved using the Adomian decomposition method. Approximate analytical expressions for substrate concentration have been derived for all values of parameters δ and SL. These analytical results are compared with the available numerical results and are found to be in good agreement.展开更多
文摘A mathematical model to describe the enzyme reaction, mass transfer and heat effects in the calorimetric system is discussed. The model is based on non-stationary diffusion Equation containing a nonlinear term related to immobilize liver esterase by flow calorimetry. This paper presents the complex numerical methods (Adomian decomposition method, Homotopy analysis and perturbation method) to solve the non-linear differential Equations that depict the diffusion coupled with a non-linear reaction terms. Approximate analytical expressions for substrate concentration have been derived for all values of parameters α, β and γE. These analytical results are compared with the available numerical results and are found to be in good agreement.
文摘The nonlinear coupled system of diffusion equations are solved analytically for the transport and kinetics of electrons and reactant in the layer of a modified electrode. Analytical expressions of concentrations of substrate and mediator are presented using He’s variational iteration method. The approximate expression of current for microheterogeneous catalysis at isonomer or redox polymer modified electrodes is also obtained. The results of the available limiting cases are compared with our results and are found to be in good agreement.
文摘A mathematical modelling by a biofilm under steady state conditions is discussed. The nonlinear differential Equations in biofilm reaction is solved using the Adomian decomposition method. Approximate analytical expressions for substrate concentration have been derived for all values of parameters δ and SL. These analytical results are compared with the available numerical results and are found to be in good agreement.
