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In-situ coating and surface partial protonation co-promoting performance of single-crystal nickel-rich cathode in all-solid-state batteries 被引量:1
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作者 Maoyi Yi Jie Li +5 位作者 Mengran wang Xinming Fan Bo Hong Zhian Zhang aonan wang Yanqing Lai 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第2期137-143,I0005,共8页
The poor electrochemical performance of all-solid-state batteries(ASSBs),which is assemblied by Ni-rich cathode and poly(ethylene oxide)(PEO)-based electrolytes,can be attributed to unstable cathodic interface and poo... The poor electrochemical performance of all-solid-state batteries(ASSBs),which is assemblied by Ni-rich cathode and poly(ethylene oxide)(PEO)-based electrolytes,can be attributed to unstable cathodic interface and poor crystal structure stability of Ni-rich cathode.Several coating strategies are previously employed to enhance the stability of the cathodic interface and crystal structure for Ni-rich cathode.However,these methods can hardly achieve simplicity and high efficiency simultaneously.In this work,polyacrylic acid(PAA)replaced traditional PVDF as a binder for cathode,which can achieve a uniform PAA-Li(LixPAA(0<x≤1))coating layer on the surface of single-crystal LiNi_(0.83)Co_(0.12)Mn_(0.05)O_(2)(SC-NCM83)due to H^(+)/Li^(+)exchange reaction during the initial charging-discharging process.The formation of PAA-Li coating layer on cathode can promote interfacial Li^(+)transport and enhance the stability of the cathodic interface.Furthermore,the partially-protonated surface of SC-NCM83 casued by H^(+)/Li^(+)exchange reaction can restrict Ni ions transport to enhance the crystal structure stability.The proposed SC-NCM83-PAA exhibits superior cycling performance with a retention of 92%compared with that(57.3%)of SC-NCM83-polyvinylidene difluoride(PVDF)after 200 cycles.This work provides a practical strategy to construct high-performance cathodes for ASSBs. 展开更多
关键词 Single-crystal LiNi_(0.83)Co_(0.12)Mn_(0.05)O_(2) In-situ coating PAA-Li Partial protonation
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Facile construction of a water-defendable Li anode protection enables rechargeable Li-O_(2) battery operating in humid atmosphere
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作者 Shan Min Xiaoyu Liu +6 位作者 aonan wang Fanghua Ning Yuyu Liu Jiaqian Qin Jiujun Zhang Shigang Lu Jin Yi 《Chinese Chemical Letters》 SCIE CAS CSCD 2023年第10期236-241,共6页
The rechargeable Li-O_(2) battery endowed with high theoretical specific energy density has sparked intense research interest as a promising energy storage system. However, the intrinsic high activity of Li anode,espe... The rechargeable Li-O_(2) battery endowed with high theoretical specific energy density has sparked intense research interest as a promising energy storage system. However, the intrinsic high activity of Li anode,especially to moisture, usually leads to inferior electrochemical performance of Li-O_(2) battery in humid environments, hindering its widespread application. To settle the trouble of poor moisture tolerance, fabricating a water-proof layer on the Li-metal anode could be an effective tactic. Herein, a facile strategy for constructing an ibuprofen-based protective layer on the Li anode has been proposed to realize highly rechargeable Li-O_(2) battery in humid atmosphere. Due to the in-situ reaction between ibuprofen reagent and metallic Li, the protective layer with a thickness of ~30 μm has been uniformly deposited on the surface of Li anode. Particularly, the protective layer, consisting of a large amount of hydrophobic alkyl group and benzene ring, can significantly resist water ingress and enhance the electrochemical stability of Li anode. As a result, the Li-O_(2) battery based on the protected Li anode achieves a long cycle life of 210 h(21 cycles at 1000 m Ah/g, 200 m A/g) in highly moist atmosphere with relative humidity(RH) of68%. This convenient and efficient strategy offers novel design concept of water-resistant metal anode,and paves the way to the promising future prospect for the high-energy Li-O_(2) battery implementing in the ambient atmosphere. 展开更多
关键词 Li-O_(2)battery Hydrophobic Li anode protection Humid atmosphere Cycling stability
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