Molecular structure characterization of middle-high rank coal via^(13)C NMR,XPS,and FTIR spectroscopy

Elemental analysis,nuclear magnetic resonance carbon spectroscopy(^(13)C-NMR),X-ray photoelectron spectroscopy(XPS)and Fourier transform infrared spectroscopy(FTIR)experiments were carried out to determine the existence of aromatic structure,heteroatom structure and fat structure in coal.MS(materials studio)software was used to optimize and construct a 3D molecular structure model of coal.A method for establishing a coal molecular structure model was formed,which was“determination of key structures in coal,construction of planar molecular structure model,and optimization of three-dimensional molecular structure model”.The structural differences were compared and analyzed.The results show that with the increase of coal rank,the dehydrogenation of cycloalkanes in coal is continuously enhanced,and the content of heteroatoms in the aromatic ring decreases.The heteroatoms and branch chains in the coal are reduced,and the structure is more orderly and tight.The stability of the structure is determined by theπ-πinteraction between the aromatic rings in the nonbonding energy EN.Key Stretching Energy The size of EB determines how tight the structure is.The research results provide a method and reference for the study of the molecular structure of medium and high coal ranks.

Hot tensile deformation behavior and globularization mechanism of bimodal microstructured Ti-6Al-2Zr-1Mo-1V alloy

The hot deformation behavior,microstructure evolution and fracture characteristics of bimodal microstructured Ti-6Al-2Zr-1Mo-1V alloy were investigated by isothermal tensile tests.Results reveal that flow softening is caused by dynamic globularization of the bimodal microstructure,which also results in a relatively high stress exponent and thermal activation energy.The corresponding SEM,EBSD and TEM observations indicate that the dynamic globularization at750and800℃is accomplished by the formation ofα/αsub-grain boundary and penetration of theβphase.However,dynamic recrystallization(DRX)is the main globularization mechanism at850℃,which was proved by the generation of fine grains with a necklace-like character due to the transformation of low-angle boundaries(LABs)into high-angle boundaries(HABs).With an increase in the deformation temperature or a decrease in the strain rate,the fracture mechanism changes from microvoid coalescence to intergranular fracture.

Influence of process parameters on properties of AA6082 in hot forming process

The influences of process parameters on mechanical properties of AA6082in the hot forming and cold-die quenching(HFQ)process were analysed experimentally.Transmission electron microscopy was used to observe the precipitate distribution and to thus clarify strengthening mechanism.A new model was established to describe the strengthening of AA6082by HFQ process in this novel forming technique.The material constants in the model were determined using a genetic algorithm tool.This strengthening model for AA6082can precisely describe the relationship between the strengths of formed workpieces and process parameters.The predicted results agree well with the experimental ones.The Pearson correlation coefficient,average absolute relative error,and root-mean-square error between the calculated and experimental hardness values are0.99402,2.0054%,and2.045,respectively.The model is further developed into an FE code ABAQUS via VUMAT to predict the mechanical property variation of a hot-stamped cup in various ageing conditions.

Effect of hot stamping parameters on the mechanical properties and microstructure of cold-rolled 22MnB5 steel strips

Thermomechanical experiments were carried out to reproduce the hot stamping process and to investigate the effects of process parameters on the microstructure and mechanical properties of stamped parts. The process parameters, such as austenitizing temperature, soaking time, initial deformation temperature and cooling rate, are studied. The resulting microstructures of specimens were observed and analyzed. To evaluate the mechanical properties of specimens, tensile and hardness tests were also performed at room temperature. The op-timum parameters to achieve the highest tensile strength and the desired microstructure were acquired by comparing and analyzing the results. It is indicated that hot deformation changes the transformation characteristics of 22MnB5 steel. Austenite deformation promotes the austen-ite-to-ferrite transformation and elevates the critical cooling rate to induce a fully martensitic transformation.

Effect of cross wedge rolling on the microstructure of GH4169 alloy

The metal microstructure during the hot forming process has a significant effect on the mechanical properties of final products. To study the microstructural evolution of the cross wedge rolling （CWR） process, the microstructural model of GH4169 alloy was programmed into the user subroutine of DEFORM-3D by FORTRAN. Then, a coupled thermo-mechanical and microstructural simulation was performed under different conditions of CWR, such as area reduction, rolling temperature, and roll speed. Comparing experimental data with simulation results, the difference in average grain size is from 11.2% to 33.4% so it is verified that the mierostructural model of GH4169 alloy is reliable and accurate. The fine grain of about 12-15 p.m could be obtained by the CWR process, and the grain distribution is very homogeneous. For the symmetry plane, increasing the area reduction is helpful to refine the grain and the value should be around 61%. Moreover, when the roiling temperature changes from 1000 to 1100℃ and the roll speed from 6 to 10 r.min-1, the grain size of the rolled piece decreases first and then increases. The temperature may be better to choose the value around 1050℃ and the speed less than 10 r-min-1.

Ductile fracture behavior of TA15 titanium alloy at elevated temperatures

To better understand the fracture behavior of TA15 titanium alloy during hot forming, three groups of experiments were conducted to investigate the influence of deformation temperature, strain rate, initial microstructure, and stress triaxiality on the fracture behavior of TA15 titanium alloy. The microstructure and fracture surface of the alloy were observed by scanning electronic microscopy to analyze the potential fracture mechanisms under the experimental deformation conditions. The experimental results indicate that the fracture strain increases with increasing deformation temperature, decreasing strain rate, and decreasing stress triaxiality. Fracture is mainly caused by the nucleation, growth, and coalescence of microvoids because of the breakdown of compatibility requirements at the α/β interface. In the equiaxed microstructure, the fracture strain decreases with decreasing volume fraction of the primary α-phase(αp) and increasing α/β-interface length. In the bimodal microstructure, the fracture strain is mainly affected by α-lamella width.

Deep drawing of aluminum alloy 7075 using hot stamping

In this paper, simulations of deep drawing tests at elevated temperatures were carried out with experimental validation. The aim of this work was to study the effect of process parameters on formability and mechanical properties of aluminum alloy 7075 in hot stamping process.Process parameters, including blank temperature, stamping speed, blank holder force and friction coefficient, were studied. Stamping tests were conducted at temperatures between 350 and 500 ℃, blank holder force between 0 and 10 kN, stamping speed between 50 and 150 mm·s^-1, and friction coefficient between 0.1 and 0.3. Based on the analysis, it is shown that thickness homogeneity could be improved when the blank is formed at lower temperature,lower blank holder force and lower friction coefficient.Formability could be improved when the blank was well lubricated at about 400 ℃. Formability at stamping speed 50 mm·s^-1 is far better than those at other speeds. The mechanical property analysis shows that the hot stamping process could make the formed part to obtain high quality.

Hot Stamping Parameters Optimization of Boron Steel Using a Response Surface Methodology Based on Central Composite Design

The effect of hot stamping parameters on the mechanical properties of 22MnB5 steel sheet with thickness of 1.1 mm is studied. The considered parameters are austenization temperature （800- 1 000 ℃ ）, austenitizing soa king time （60-540 s）, initial deformation temperature （560-800 C） and tool temperature （20-220 ℃）. In order to obtain hot stamped parts with optimal mechanical properties, response surface methodology based on the central composite design has been employed to design the experiment matrix. Tensile strength of hot stamped parts is deter- mined as the relation in the mathematical model. The optimal condition and objective effects of parameters are deter mined via this relation. The statistical analysis showed that all four factors significantly affect the tensile strength of the hot stamped parts. The optimum austenization temperature is found to be 918.89 ℃ with the austenitizing soa- king time, initial deformation temperature and tool temperature of 279.45 s, 684.69 C and 21.85 ℃, respectively. These optimal hot stamping parameters prove to have high tensile strength （1 631.84 MPa） where deviation between predicted and actual response falls within 2 %.

Modeling of microstructural evolution and flow behavior of superalloy IN718 using physically based internal state variables

Microstructural evolution and flow behavior greatly affect the hot forming process of IN718.In this research,hot deformation behaviors of IN718 were investigated by performing hot compression tests at temperature range of 1000-1100℃with strain rates of 0.1-20.0 s^(-1).By incorporating physically based internal state variables such as dislocation density,volume fraction of dynamic recrystallization,and grain size,a set of unified viscoplastic constitutive equations were developed to predict the microstructural evolution and flow behavior of IN718.The material constants were determined using a genetic algorithm(G A)-based optimization method.Comparisons of the computed and experimental results indicate that the constitutive equations established in this study can accurately describe the hot deformation behavior and microstructural evolution of IN718.