We present a precise measurement of171Yb magnetic constants for 1S_(0)-3P_(0) clock transition. The background magnetic field is firstly compensated to < 1 m Gs(1 Gs = 10^(-4)T) through measuring the splitting of t...We present a precise measurement of171Yb magnetic constants for 1S_(0)-3P_(0) clock transition. The background magnetic field is firstly compensated to < 1 m Gs(1 Gs = 10^(-4)T) through measuring the splitting of two π transitins of171Yb clock transition at different compensation coils currents. Then, the splitting ratios of the π and σ components of171Yb clock transition at different bias magnetic fields are measured, and the first-order Zeeman coefficient is determined to beα = 199.49(5) Hz/Gs. The second-order Zeeman shifts at various bias magnetic fields are also measured through interleaved self-comparison in which the bias magnetic fields are modulated between high and low values. The second-order Zeeman coefficient is fitted to be β =-6.09(3) Hz/m T^(2), which is consistent with the result of NIST group.展开更多
The complete elimination of methylammonium(MA)cations in Sn-Pb composites can extend their light and thermal stabilities.Unfortunately,MA-free Sn-Pb alloyed perovskite thin films suffer from wrinkled surfaces and poor...The complete elimination of methylammonium(MA)cations in Sn-Pb composites can extend their light and thermal stabilities.Unfortunately,MA-free Sn-Pb alloyed perovskite thin films suffer from wrinkled surfaces and poor crystallization,due to the coexistence of mixed intermediate phases.Here,we report an additive strategy for finely regulating the impurities in the intermediate phase of Cs_(0.25)FA_(0.75)Pb_(0.6)Sn_(0.4)I_(3)and,thereby,obtaining high-performance solar cells.We introduced d-homoserine lactone hydrochloride(D-HLH)to form hydrogen bonds and strong Pb-O/Sn-O bonds with perovskite precursors,thereby weakening the incomplete complexation effect between polar aprotic solvents(e.g.,DMSO)and organic(FAI)or inorganic(CsI,PbI_(2),and SnI_(2))components,and balancing their nucleation processes.This treatment completely transformed mixed intermediate phases into pure preformed perovskite nuclei prior to thermal anneal-ing.Besides,this D-HLH substantially inhibited the oxidation of Sn^(2+) species.This strategy generated a record efficiency of 21.61%,with a Voc of 0.88 V for an MA-free Sn-Pb device,and an efficiency of 23.82%for its tandem device.The unencapsulated devices displayed impressive thermal stability at 85℃ for 300 h and much improved continuous operation stability at MPP for 120 h.展开更多
基金supported by the National Key Research and Development Program of China (Grant No. 2017YFA0304402)the National Natural Science Foundation of China (Grant Nos. U20A2075 and 11803072)the Strategic Priority Research Program of the Chinese Academy of Sciences (Grant No. XDB21030100)。
文摘We present a precise measurement of171Yb magnetic constants for 1S_(0)-3P_(0) clock transition. The background magnetic field is firstly compensated to < 1 m Gs(1 Gs = 10^(-4)T) through measuring the splitting of two π transitins of171Yb clock transition at different compensation coils currents. Then, the splitting ratios of the π and σ components of171Yb clock transition at different bias magnetic fields are measured, and the first-order Zeeman coefficient is determined to beα = 199.49(5) Hz/Gs. The second-order Zeeman shifts at various bias magnetic fields are also measured through interleaved self-comparison in which the bias magnetic fields are modulated between high and low values. The second-order Zeeman coefficient is fitted to be β =-6.09(3) Hz/m T^(2), which is consistent with the result of NIST group.
基金funded by the Natural Science Foundation of Shanghai(22ZR1428200)the National Natural Science Foundation of China(51950410581)+1 种基金the Shanghai Government(20JC141500)and CATL-SJTU joint funding.
文摘The complete elimination of methylammonium(MA)cations in Sn-Pb composites can extend their light and thermal stabilities.Unfortunately,MA-free Sn-Pb alloyed perovskite thin films suffer from wrinkled surfaces and poor crystallization,due to the coexistence of mixed intermediate phases.Here,we report an additive strategy for finely regulating the impurities in the intermediate phase of Cs_(0.25)FA_(0.75)Pb_(0.6)Sn_(0.4)I_(3)and,thereby,obtaining high-performance solar cells.We introduced d-homoserine lactone hydrochloride(D-HLH)to form hydrogen bonds and strong Pb-O/Sn-O bonds with perovskite precursors,thereby weakening the incomplete complexation effect between polar aprotic solvents(e.g.,DMSO)and organic(FAI)or inorganic(CsI,PbI_(2),and SnI_(2))components,and balancing their nucleation processes.This treatment completely transformed mixed intermediate phases into pure preformed perovskite nuclei prior to thermal anneal-ing.Besides,this D-HLH substantially inhibited the oxidation of Sn^(2+) species.This strategy generated a record efficiency of 21.61%,with a Voc of 0.88 V for an MA-free Sn-Pb device,and an efficiency of 23.82%for its tandem device.The unencapsulated devices displayed impressive thermal stability at 85℃ for 300 h and much improved continuous operation stability at MPP for 120 h.
