Sediment cores were collected at an upstream site(Jintang) and a downstream site(Neijiang) in summer and winter in the Tuohe River, which is one of the five largest tributaries of the Changjiang(Yangtze) River in Chin...Sediment cores were collected at an upstream site(Jintang) and a downstream site(Neijiang) in summer and winter in the Tuohe River, which is one of the five largest tributaries of the Changjiang(Yangtze) River in China. A sequential leaching procedure was applied to determine the concentrations of the different forms of solid phosphorus, including exchangeable phosphorus(Exc-P) as well as phosphorus associated with iron oxides(Fe-P), with aluminum oxides(Al-P), with apatite(Ca-P) and with the residual fraction(Res-P), as correlated with water content and total organic carbon. The seasonal variations and the vertical distributions of phosphorus species in sediments at both sampling sites demonstrated that: 1) total phosphorus(TP) in summer and winter were ranged between 1 313–2 330, 1 491–2 228 mg/kg in Jintang and 543–2 128, 603–1 175 mg/kg in Neijiang, respectively. It can predicated the pollution of TP in Jintang is serious than that in Neijiang both in summer and winter; 2) total inorganic phosphorus(TIP) was the dominant form of TP; 3) Ca-P was the main chemical forms of TIP in the sediments. Based on the profiles in sediments and bio-available phosphorus data, it revealed that bio-available phosphorus(BAP) represented only a minor portion(0.61%–3.59%) of TP, and the vertical distribution of soluble reactive phosphorus(SRP) in corresponding porewaters was more abundant in the upper layer of the sediment, which suggests that BAP may be converted to non-bioavailable phosphorus in deeper layer of the sediment of this dynamic system.展开更多
In order to identify the effects of seasonal variation on the migration and transformation of antimony species at the sediment-water interface of the Poyang Lake, the largest fresh lake in China, a simulation study wa...In order to identify the effects of seasonal variation on the migration and transformation of antimony species at the sediment-water interface of the Poyang Lake, the largest fresh lake in China, a simulation study was carried out in the laboratory. Antimony species including antimonite Sb(III), antimonate Sb(V) and the fraction of organic forms(Sb-org) in overlying water at different temperatures were regularly measured during the simulation period. Different bound antimony forms in sediments were also determined along with the different antimony species in porewaters after the simulation terminated. The results indicated that temperature change during seasonal alternation plays an important role in the migration and transformation behavior of antimony at the sediment-water interface of the Poyang Lake. Antimony species both in porewaters and overlying water were sensitive to the variation of temperature, especially the Sb-org species. Antimony migrates from porewaters to the overlying water when the temperature decreases, and meanwhile the equilibrium between Sb(III) and Sb(V) in porewaters shifts toward Sb(V) when the temperature increases during seasonal alternation. Although temperature had less influence on the antimony species in sediments than in porewaters or in the overlying water, the average content of each antimony species in sediments increased with the decrease of temperature, suggesting that the decrease of temperature causes enrichment of antimony in the sediment.展开更多
1 Introduction The brines with high concentrations of magnesium and boron resources are widely distributed in the Qaidam Basin of the Qinghai-Tibet plateau,China(Zheng&Tang,1988).Although some works on the ternary...1 Introduction The brines with high concentrations of magnesium and boron resources are widely distributed in the Qaidam Basin of the Qinghai-Tibet plateau,China(Zheng&Tang,1988).Although some works on the ternary system展开更多
1 Introduction Sodium borates as important raw materials are widely used in the field of glass industry,ceramic industry,medical industry,paper industry,agriculture and so on for
1 Introduction Alkaline lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their high concentration of lithium,potassium,magnesium,boron(Ma,2000).In recent year...1 Introduction Alkaline lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their high concentration of lithium,potassium,magnesium,boron(Ma,2000).In recent years,as a new energy material,lithium and its compounds are widely used in the new area,such as aerospace industry,nuclear展开更多
1 Introduction As the lightest metal with the unique properties of energy production and storage,lithium is regarded as the new century energy metal.Lithium and its compounds were widely used in various industrial fie...1 Introduction As the lightest metal with the unique properties of energy production and storage,lithium is regarded as the new century energy metal.Lithium and its compounds were widely used in various industrial fields,especially in展开更多
1 Introduction Lithium and its compounds as national strategic resources are extensively used in national defense,industrial and agricultural production.As we know,the salt lakes in the western of China are famous for...1 Introduction Lithium and its compounds as national strategic resources are extensively used in national defense,industrial and agricultural production.As we know,the salt lakes in the western of China are famous for its high展开更多
1 Introduction With the industrial development of lithium battery,nuclear and aerospace industry,the demands of metal lithium and its compounds are increasing significantly.Lithium is called as the energy of the metal...1 Introduction With the industrial development of lithium battery,nuclear and aerospace industry,the demands of metal lithium and its compounds are increasing significantly.Lithium is called as the energy of the metal in the new century(Zhang et al.2001).The total reserve of lithium resources around the world7展开更多
1 Introduction Salt lakes are widely distributed in the world,and salt lakes in China are mainly located in the area of the Qinghai-Xizang(Tibet),and the Autonomous Regions of Xinjiang and Inner Mongolia.There are mor...1 Introduction Salt lakes are widely distributed in the world,and salt lakes in China are mainly located in the area of the Qinghai-Xizang(Tibet),and the Autonomous Regions of Xinjiang and Inner Mongolia.There are more than 700salt lakes,each with an area larger than 1 km2,in the展开更多
1 Introduction Although a mumerous of papers were reported for the chemcial or instrumental analysis of inorganic elements for the geocheical samples(Sun and Xie,2014;Sun et al.,2014;Rao et al.,2004).However,the analy...1 Introduction Although a mumerous of papers were reported for the chemcial or instrumental analysis of inorganic elements for the geocheical samples(Sun and Xie,2014;Sun et al.,2014;Rao et al.,2004).However,the analytical methods展开更多
With the rapid increasing demand of metal lithium and its compounds in science and technology,studies on lithium recovery though lithium ion extraction from salt lake brines are blooming bacause more than 60 percent of
1 Introduction Many variable temperature chemical models were developed to predict mineral solubility in the natural waters(Na+,K+,Ca2+,Mg2+//Cl-,SO42-–H2O)in the temperature range below 298.15 K(to near 213.15 K)and...1 Introduction Many variable temperature chemical models were developed to predict mineral solubility in the natural waters(Na+,K+,Ca2+,Mg2+//Cl-,SO42-–H2O)in the temperature range below 298.15 K(to near 213.15 K)and(Na+,K+,展开更多
Cesium as a kind of alkali metals has widely been used in catalysis,medicine,biology,magnetic fluid power and other high-tech fields(Liao and Yang,2012;Cao et al.,2011;Wang et al.,2011).Although there was abundant of
1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous...1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their abundance of lithium,potassium,magnesium,and boron resources.It is展开更多
1 Introduction There are many different magnesium borates synthesized from various conditions or acquired naturally with different compositions,which can be used in a wide range of fields.Their applications involve ce...1 Introduction There are many different magnesium borates synthesized from various conditions or acquired naturally with different compositions,which can be used in a wide range of fields.Their applications involve ceramic展开更多
1 Introduction Salt lakes are widely distributed in the western of China,especially in the area of Qinghai-Xizang(Tibet)Plateau.A series of salt lakes in the Qaidam Basin,located in Qinghai Province,China,is famous fo...1 Introduction Salt lakes are widely distributed in the western of China,especially in the area of Qinghai-Xizang(Tibet)Plateau.A series of salt lakes in the Qaidam Basin,located in Qinghai Province,China,is famous for their abundance of lithium,potassium and boron resources(Zheng et al,1988;Deng et al,2012).It is well known that the展开更多
1 Introduction Lithium resources are widely distributed in the oilfield brine from the Nanyishan district in the Qaidam Basin(Fan et al.,2007).The investigation of the thermodynamics and phase diagram of the brine sys...1 Introduction Lithium resources are widely distributed in the oilfield brine from the Nanyishan district in the Qaidam Basin(Fan et al.,2007).The investigation of the thermodynamics and phase diagram of the brine system is valuable in providing the theoretic foundation and scientific guidance in the comprehensive exploitation of the mixture salts effectively.Comprehensive展开更多
基金Supported by the National Natural Science Foundation of China(Nos.21773170,U1407113,U1607123)the Yangtze Scholars and Innovative Research Team in University of Ministry of Education of China(No.IRT_17R81)the Sichuan Province Outstanding Youth Leader Fund(No.05ZQ26-4)
文摘Sediment cores were collected at an upstream site(Jintang) and a downstream site(Neijiang) in summer and winter in the Tuohe River, which is one of the five largest tributaries of the Changjiang(Yangtze) River in China. A sequential leaching procedure was applied to determine the concentrations of the different forms of solid phosphorus, including exchangeable phosphorus(Exc-P) as well as phosphorus associated with iron oxides(Fe-P), with aluminum oxides(Al-P), with apatite(Ca-P) and with the residual fraction(Res-P), as correlated with water content and total organic carbon. The seasonal variations and the vertical distributions of phosphorus species in sediments at both sampling sites demonstrated that: 1) total phosphorus(TP) in summer and winter were ranged between 1 313–2 330, 1 491–2 228 mg/kg in Jintang and 543–2 128, 603–1 175 mg/kg in Neijiang, respectively. It can predicated the pollution of TP in Jintang is serious than that in Neijiang both in summer and winter; 2) total inorganic phosphorus(TIP) was the dominant form of TP; 3) Ca-P was the main chemical forms of TIP in the sediments. Based on the profiles in sediments and bio-available phosphorus data, it revealed that bio-available phosphorus(BAP) represented only a minor portion(0.61%–3.59%) of TP, and the vertical distribution of soluble reactive phosphorus(SRP) in corresponding porewaters was more abundant in the upper layer of the sediment, which suggests that BAP may be converted to non-bioavailable phosphorus in deeper layer of the sediment of this dynamic system.
基金Supported by the National Natural Science Foundation of China(Nos.U1607129,U1607123,21773170)the Application Foundation and Advanced Technology Program of Tianjin(No.15JCQNJC08300)+1 种基金the Yangtze Scholars and Innovative Research Team in Chinese University(No.IRT_17R81)the Chinese Postdoctoral Science Foundation(Nos.2016M592827,2016M592828)
文摘In order to identify the effects of seasonal variation on the migration and transformation of antimony species at the sediment-water interface of the Poyang Lake, the largest fresh lake in China, a simulation study was carried out in the laboratory. Antimony species including antimonite Sb(III), antimonate Sb(V) and the fraction of organic forms(Sb-org) in overlying water at different temperatures were regularly measured during the simulation period. Different bound antimony forms in sediments were also determined along with the different antimony species in porewaters after the simulation terminated. The results indicated that temperature change during seasonal alternation plays an important role in the migration and transformation behavior of antimony at the sediment-water interface of the Poyang Lake. Antimony species both in porewaters and overlying water were sensitive to the variation of temperature, especially the Sb-org species. Antimony migrates from porewaters to the overlying water when the temperature decreases, and meanwhile the equilibrium between Sb(III) and Sb(V) in porewaters shifts toward Sb(V) when the temperature increases during seasonal alternation. Although temperature had less influence on the antimony species in sediments than in porewaters or in the overlying water, the average content of each antimony species in sediments increased with the decrease of temperature, suggesting that the decrease of temperature causes enrichment of antimony in the sediment.
基金Financial supports from the National Natural Science Foundation of China (21276194 and 21306136)Key Laboratory of Salt Lake Resources and Chemistry at Chinese Academy Sciences (KLSLRC-KF-13-HX-2)Tianjin Key Laboratory of Marine Resources and Chemistry (201206)
文摘1 Introduction The brines with high concentrations of magnesium and boron resources are widely distributed in the Qaidam Basin of the Qinghai-Tibet plateau,China(Zheng&Tang,1988).Although some works on the ternary system
基金Financial supports from the NNSFCs (Grants 21276194 and 21306136)the Specialized Research Fund for the Doctoral Program of Chinese Higher Education (Grant 20101208110003)the Opening Funds of Tianjin Key Laboratory of Marine Resources and Chemistry for Tianjin University of Science and Technology (Grant 201206)
文摘1 Introduction Sodium borates as important raw materials are widely used in the field of glass industry,ceramic industry,medical industry,paper industry,agriculture and so on for
基金Financial support from the NSFCs (21106103, 21276194 and 21306136)the Specialized Research Funds for the Doctoral Program of Chinese Higher Education (20101208110003 and 20111208120003)+1 种基金the Natural Science Foundation of Tianjin (12JCQNJC03400)the Senior Professor Program for TUST (20100405)
文摘1 Introduction Alkaline lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their high concentration of lithium,potassium,magnesium,boron(Ma,2000).In recent years,as a new energy material,lithium and its compounds are widely used in the new area,such as aerospace industry,nuclear
基金Financial support from the National Natural Science Foundation of China (21276194)the Specialized Research Fund for the Doctoral Program of Chinese Higher Education (20101208110003)the Key Pillar Program of Tianjin Municipal Science and Technology (11ZCKGX02800)
文摘1 Introduction As the lightest metal with the unique properties of energy production and storage,lithium is regarded as the new century energy metal.Lithium and its compounds were widely used in various industrial fields,especially in
基金Financial supports from the NNSFCs (Grants 21276194 and 21306136)the Specialized Research Fund for the Doctoral Program of Chinese Higher Education (Grant 20101208110003)the Opening Funds of Tianjin Key Laboratory of Marine Resources and Chemistry for Tianjin University of Science and Technology (Grant 201206)
文摘1 Introduction Lithium and its compounds as national strategic resources are extensively used in national defense,industrial and agricultural production.As we know,the salt lakes in the western of China are famous for its high
基金Financial supports from National Natural Science of China (21276194)the Key Pillar Program of Tianjin Municipal Science and Technology (11ZCKGX02800)+1 种基金the Specialized Research Fund for the Doctoral Program of Chinese Higher Education (20101208110003)The Research Fund of Tianjin Key Laboratory of Marine Resources and Chemistry (201206)
文摘1 Introduction With the industrial development of lithium battery,nuclear and aerospace industry,the demands of metal lithium and its compounds are increasing significantly.Lithium is called as the energy of the metal in the new century(Zhang et al.2001).The total reserve of lithium resources around the world7
基金Financial support from the State Key Program of NNSFC (20836009)the NNSFCs (Grants 21106136, 21276194 and 21306136)
文摘1 Introduction Salt lakes are widely distributed in the world,and salt lakes in China are mainly located in the area of the Qinghai-Xizang(Tibet),and the Autonomous Regions of Xinjiang and Inner Mongolia.There are more than 700salt lakes,each with an area larger than 1 km2,in the
基金Financial support from the Special Fundamental Scientific Research Fund for the National Public Welfare Institutes (AS2010J03)
文摘1 Introduction Although a mumerous of papers were reported for the chemcial or instrumental analysis of inorganic elements for the geocheical samples(Sun and Xie,2014;Sun et al.,2014;Rao et al.,2004).However,the analytical methods
基金Financial support from the State Surface Project of National Natural Science of China (21276194)the Key Pillar Program of Tianjin Municipal Science and Technology (11ZCKGX02800)the Specialized Research Fund for the Doctoral Program of Chinese Higher Education (20101208110003)
文摘With the rapid increasing demand of metal lithium and its compounds in science and technology,studies on lithium recovery though lithium ion extraction from salt lake brines are blooming bacause more than 60 percent of
基金Financial support from the National Natural Science Foundation of China (21276194 and 21306136)the Training Program for Changjiang Scholars and Innovative Research Teamin University ([2013]373)+1 种基金the Innovative Research Team of Tianjin Municipral Education Commission (TD12- 5004)Tianj in Key Laboratory of Marine Resources and Chemistry (201201)
文摘1 Introduction Many variable temperature chemical models were developed to predict mineral solubility in the natural waters(Na+,K+,Ca2+,Mg2+//Cl-,SO42-–H2O)in the temperature range below 298.15 K(to near 213.15 K)and(Na+,K+,
基金Financial support from the State Surface Project of National Natural Science of China (21276194)the Key Pillar Program of Tianjin Municipal Science and Technology (11ZCKGX02800)the Specialized Research Fund for the Doctoral Program of Chinese Higher Education (20101208110003)
文摘Cesium as a kind of alkali metals has widely been used in catalysis,medicine,biology,magnetic fluid power and other high-tech fields(Liao and Yang,2012;Cao et al.,2011;Wang et al.,2011).Although there was abundant of
基金Financial supports from the NSFCs (21106103, 21276194 and 21306136)the Specialized Research Funds for the Doctoral Program of Chinese Higher Education (20101208110003 and 20111208120003)+1 种基金the Natural Science Foundation of Tianjin (12JCQNJC03400)the Senior Professor Program for TUST (20100405)
文摘1 Introduction A salt lake is a naturally occurring complex body of water and salt interaction.More than 700 salt lakes are widely distributed in the area of the Qinghai-Tibet Plateau.Most of the salt lakes are famous for their abundance of lithium,potassium,magnesium,and boron resources.It is
基金Financial supports from the National Natural Science of China (Grants 21276194 and 21306136)the Specialized Research Fund for the Doctoral Program of Chinese Higher Education (Grant 20101208110003)the Opening Funds of Tianjin Key Laboratory of Marine Resources and Chemistry for Tianjin University of Science and Technology (Grants 201201 and 201206)
文摘1 Introduction There are many different magnesium borates synthesized from various conditions or acquired naturally with different compositions,which can be used in a wide range of fields.Their applications involve ceramic
基金Financial support from the NSFCs (21106103, 21276194 and 21306136)the Specialized Research Funds for the Doctoral Program of Chinese Higher Education (20101208110003, 20111208120003)+1 种基金the Natural Science Foundation of Tianjin (12JCQNJC03400)Senior Professor Program for TUST (20100405)
文摘1 Introduction Salt lakes are widely distributed in the western of China,especially in the area of Qinghai-Xizang(Tibet)Plateau.A series of salt lakes in the Qaidam Basin,located in Qinghai Province,China,is famous for their abundance of lithium,potassium and boron resources(Zheng et al,1988;Deng et al,2012).It is well known that the
基金Supported by the NNSFCs (21276194 and 21306136)the Key Pillar Program of Tianjin Municipal S&T (11ZCKGX02800)the Specialised Research Fund for the Doctoral Program of Chinese Higher Education (20101208110003)
文摘1 Introduction Lithium resources are widely distributed in the oilfield brine from the Nanyishan district in the Qaidam Basin(Fan et al.,2007).The investigation of the thermodynamics and phase diagram of the brine system is valuable in providing the theoretic foundation and scientific guidance in the comprehensive exploitation of the mixture salts effectively.Comprehensive