济阳坳陷桩海地区馆陶组上段三角洲沉积特征

为了加深对桩海地区馆陶组上段沉积相的认识,根据测井资料、地震剖面资料、等时地层切片资料等,通过古地貌及砂岩百分含量等值线图,分析馆陶组上段物源供应特征和沉积特征,对沉积相平面展布特征进行刻画,并对储层有利区进行预测。结果表明,研究区存在来自西南和东南两个方向的物源;馆陶组上段早期发育了三角洲相,三角洲平原不发育,三角洲前缘较发育,以水下分流河道、河口砂坝和支流间湾等微相为主;有利区位于发育河口砂坝和水下分流河道的中部和南部区域。

Depositional Environment and Lithofacies Analyses of Eocene Lacustrine Shale in the Bohai Bay Basin:Insights from Mineralogy and Elemental Geochemistry

The effect of various depositional parameters including paleoclimate,paleosalinity and provenance,on the depositional mechanism of lacustrine shale is very important in reconstructing the depositional environment.The classification of shale lithofacies and the interpretation of shale depositional environment are key features used in shale oil and gas exploration and development activity.The lower 3rd member of the Eocene Shahejie Formation(Es_(3)^(x)shale)was selected for this study,as one of the main prospective intervals for shale oil exploration and development in the intracratonic Bohai Bay Basin.Mineralogically,it is composed of quartz(avg.9.6%),calcite(avg.58.5%),dolomite(avg.7%),pyrite(avg.3.3%)and clay minerals(avg.20%).An advanced methodology(thin-section petrography,total organic carbon and total organic sulfur contents analysis,X-ray diffraction(XRD),X-ray fluorescence(XRF),field-emission scanning electron microscopy(FE-SEM))was adopted to establish shale lithofacies and to interpret the depositional environment in the lacustrine basin.Six different types of lithofacies were recognized,based on mineral composition,total organic carbon(TOC)content and sedimentary structures.Various inorganic geochemical proxies(Rb/Sr,Ca/(Ca+Fe),Ti/Al,Al/Ca,Al/Ti,Zr/Rb)have been used to interpret and screen variations in depositional environmental parameters during the deposition of the Es_(3)^(x)shale.The experimental results indicate that the environment during the deposition of the Es_(3)^(x)shale was warm and humid with heightened salinities,moderate to limited detrital input,higher paleohydrodynamic settings and strong oxygen deficient(reducing)conditions.A comprehensive depositional model of the lacustrine shale was developed.The interpretations deduced from this research work are expected to not only expand the knowledge of shale lithofacies classification for lacustrine fine-grained rocks,but can also offer a theoretical foundation for lacustrine shale oil exploration and development.

Sedimentary Processes and Depositional Characteristics of Coarse-grained Subaqueous Fans along Steep Slopes in a Lacustrine Rift Basin:A Case Study from the Dongying Depression,Bohai Bay Basin,China

Coarse-grained subaqueous fans are vital oil and gas exploration targets in the Bohai Bay basin,China.The insufficient understanding of their sedimentary processes,depositional patterns,and controlling factors restricts efficient exploration and development.Coarse-grained subaqueous fans in the Yong′an area,Dongying Depression,are investigated in this study.These fans include nearshore subaqueous fans,and sublacustrine fans,and their sedimentary processes,depositional patterns and distribution characteristics are mainly controlled by tectonic activity and paleogeomorphology.Nearshore subaqueous fans developed near the boundary fault during the early–middle deposition stage due to strong tectonic activity and large topographic subsidence.Early sublacustrine fans developed at the front of the nearshore subaqueous fans in the area where the topography changed from gentle to steep along the source direction.While the topography was gentle,sublacustrine fans did not develop.During the late weak tectonic activity stage,late sublacustrine fans developed with multiple stages superimposed.Frequent fault activity and related earthquakes steepened the basin margin,and the boundary fault slopes were 25.9°–34°.During the early–middle deposition stage,hyperpycnal flows triggered by outburst floods developed.During the late deposition stage,with weak tectonic activity,seasonal floods triggered hyperpycnal flows,and hybrid event beds developed distally.

Spontaneous decoration of ionic compounds at perovskite interfaces to achieve 23.38% efficiency with 85% fill factor in NiO_X-based perovskite solar cells

Inorganic hole transport materials, particularly NiO_X, have shown considerable promise in boosting the efficiency and stability of perovskite solar cells. However, a major barrier to commercialization of NiO_X-based perovskite solar cells with positive-intrinsic-negative architectures is their direct contact with the absorbing layer, which can lead to losses of photovoltage and fill factor. Furthermore, highly positive under-coordinated Ni cations degrade the perovskite at the interface. Here, we address these issues with the use of an ionic compound(QAPyBF_(4)) as an additive to passivate defects throughout the perovskite layer and improve carrier conduction and interactions with under-coordinated Ni cations. Specifically,the highly electronegative inorganic anion [BF_(4)]~- interacts with the NiO_x/perovskite interface to passivate under-coordinated cations(Ni^(≥3+)). Accordingly, the decorated cells achieved a power conversion efficiency of 23.38% and a fill factor of 85.5% without a complex surface treatment or NiO_X doping.

湖泊碎屑岩沙坝成因机制及构型表征研究进展

湖泊碎屑岩沙坝因波浪和沿岸流的反复冲刷,成熟度较高,显示出巨大的油气勘探潜力,已成为隐蔽油气藏勘探的重点。作者在大量文献调研的基础上,总结了近年来前人在滩坝定义、沉积特征、主控因素、成因机制及内部构型研究中的重要进展,在此基础上提出了沙坝演化阶段及沉积构型的新认识。结果表明,沙坝完整的演化历程主要包括4个阶段,分别是弱波浪作用阶段、动荡水流—冲洗回流阶段、风成阶段及沼泽化阶段。影响沙坝发育的控制因素多样,其中物源和风场是沙坝发育的根本因素,两者分别影响了沙坝发育的物质来源和能量供给;而风场所决定的水动力是影响沙坝储集体发育的最直接因素;构造运动和层序演化则控制沙坝的分布位置及保存程度;各因素综合作用决定了坝的形态、发育规模及保存状况。依据前人构型理论,将沙坝构型按照正序方案依次划分为6级,对构型表征方法和沙坝3~5级构型定量表征进行了初步探索,以期为滩坝砂体勘探开发提供理论和实践支持。

Heat Dissipation Modeling of <i>In-Situ</i>Conversion Process of Oil Shale

In-situ conversion of process of oil shale has been technically proven as a pilot field project. Gradually heating the reservoir by using subsurface electric heaters converts the oil shale reservoir kerogen into oil, gas and other producible components. This process also enhances the internal energy of the porous media as well as the subsurface fluid. Heat is transmitted in the reservoir within each fluid by different processes i.e. , due to the flow of fluid called advective process, and due to molecular diffusion where dispersive and diffusive processes take place. Heat transfer through conduction and convection mechanisms in the porous media are modeled mathematically and numerically incorporating the advective, dispersive and diffusive processes in the reservoir. The results show the production of oil and gas as a result of conversion of kerogen due to modeled heat dissipation.

Pore size distribution,their geometry and connectivity in deeply buried Paleogene Es1 sandstone reservoir,Nanpu Sag,East China

The study or pore characteristics is or great importance in reservoir evaluation,especially in deeply buried s andstone.It controls the storage mechanism and reservoir fluid properties of the permeable horizons.The first member of Eocene Shahejie Formation(Esl)sandstone is classified as feldspathic litharenite and lithic arkose.The present research investigates the pore characteristics and reservoir features of the deeply buried sandstone reservoir of Esl member of Shahejie Formation.The techniques including thin-section petrography,mercury injection capillary pressure(MICP),scanning electron microscopy and laser scanning confocal microscope images were used to demarcate the pores including primary intergranular pores and secondary intergranular,intragranular,dissolution and fracture pores.Mercury injection test and routine core analysis were led to demarcate the pore network characteristics of the studied reservoir.Pore size and pore throat size distribution are acquired from mercury injection test.Porosity values range from 0.5%to 30%,and permeability ranges 0.006-7000 mD.Pore radii of coarse-grained sandstone and fine-grained sandstone range from 0.2 to>4μm and 1 nm to 1.60μm,respectively,by MICP analysis.The mineral composition also plays an important role in protecting the pores with pressure from failure.Fractured sandstone and coarse-grained sandstone consist of large and interconnected pores that enhance the reservoir porosity and permeability,whereas fine-grained sandstone and siltstone consist of numerous pores but not well interconnected,and so they consist of high porosity with low permeability.

Reformation of thiophene-functionalized phthalocyanine isomers for defect passivation to achieve stable and efficient perovskite solar cells

Lewis acid–base passivation is a significant technique to achieve structural stability of perovskite solar cells(PSCs) by overcoming the issues of wide grain boundaries, crystal defects, and the instability of PSCs. In this work, the combined effects of thiophene with phthalocyanine(Pc) as isomers(S2 and S3)on the photovoltaic performance of PSCs were studied for the first time. Through density functional theory calculations, we confirmed that the position of the S atom in the structure affects Lewis acid–base interactions with under-coordinated Pb^(2+) sites. The morphology of methylammonium lead iodide(MAPbI_(3)) for passivated devices was improved and thin dense layers with compact surface and large grain size were observed, leading to improvement of the charge extraction ability and reduction of non-radiative recombination and the trap density. A highest power conversion efficiency of 18% was achieved for the Pc S3 passivated device, which was 6.69% more than that of the controlled device.Furthermore, the Pcs passivated devices demonstrated remarkable stability under high-moisture and high-temperature conditions.