E-T or log p-1/T diagrams showing the influence of temperature and pressure in a gaseous phase were presented in par tⅠof the overview.I n partⅡ,the relationship between E-T and Kellogg diagrams or between E-T and E...E-T or log p-1/T diagrams showing the influence of temperature and pressure in a gaseous phase were presented in par tⅠof the overview.I n partⅡ,the relationship between E-T and Kellogg diagrams or between E-T and E-pH diagrams is discussed.E-T diagrams cover larger field of application than the other two.The practical use of E-T or log p-1/T diagrams is also investigated,which includes:the calculation of polycomponent equilibria in a gaseous phase,the prediction of cor rosion products,the interpretation of catalytic mechanism,the exploration for the possibility of producing aluminum with carbothermic method,etc.The limitation of this kind of diagrams is also discussed.展开更多
By use of micro-DTA technique as well as ambient and high temperature X-ray analysis the phase diagram of NaCl-CaCl_2 has been checked.It is.a simple eutectic system with a solid solubility in the sodium chloride side...By use of micro-DTA technique as well as ambient and high temperature X-ray analysis the phase diagram of NaCl-CaCl_2 has been checked.It is.a simple eutectic system with a solid solubility in the sodium chloride side.The eutectic point is at 773K,49 mol% NaCl.The experimental results,especially those of the X-ray diffraction studies have showed that the incongruent compound 4NaCl-CaCl_2 does not exist in the NaCl-CaCl_2 system.展开更多
基金Natural Science Foundation of Shandong province.
文摘E-T or log p-1/T diagrams showing the influence of temperature and pressure in a gaseous phase were presented in par tⅠof the overview.I n partⅡ,the relationship between E-T and Kellogg diagrams or between E-T and E-pH diagrams is discussed.E-T diagrams cover larger field of application than the other two.The practical use of E-T or log p-1/T diagrams is also investigated,which includes:the calculation of polycomponent equilibria in a gaseous phase,the prediction of cor rosion products,the interpretation of catalytic mechanism,the exploration for the possibility of producing aluminum with carbothermic method,etc.The limitation of this kind of diagrams is also discussed.
基金Projects Supported by the National Natural Science Fundation of China.
文摘By use of micro-DTA technique as well as ambient and high temperature X-ray analysis the phase diagram of NaCl-CaCl_2 has been checked.It is.a simple eutectic system with a solid solubility in the sodium chloride side.The eutectic point is at 773K,49 mol% NaCl.The experimental results,especially those of the X-ray diffraction studies have showed that the incongruent compound 4NaCl-CaCl_2 does not exist in the NaCl-CaCl_2 system.
