Bivariate Analysis of Pollutants Monthly Maxima in Mexico City Using Extreme Value Distributions and Copula

In the present work, we are interested in studying the joint distributions of pairs of the monthly maxima of the pollutants used by the environmental authorities in Mexico City to classify the air quality in the metropolitan area. In order to obtain the joint distributions a copula will be considered. Since we are analyzing the monthly maxima, the extreme value distributions of Weibull and Fréchet are taken into account. Using these two distributions as marginal distributions in the copula a Bayesian inference was made in order to estimate the parameters of both distributions and also the association parameters appearing in the copula model. The pollutants taken into account are ozone, nitrogen dioxide, sulphur dioxide, carbon monoxide, and particulate matter with diameters smaller than 10 and 2.5 microns obtained from the Mexico City monitoring network. The estimation was performed by taking samples of the parameters generated through a Markov chain Monte Carlo algorithm implemented using the software OpenBugs. Once the algorithm is implemented it is applied to the pairs of pollutants where one of the coordinates of the pair is ozone and the other varies on the set of the remaining pollutants. Depending on the pollutant and the region where they were collected, different results were obtained. Hence, in some cases we have that the best model is that where we have a Fréchet distribution as the marginal distribution for the measurements of both pollutants and in others the most suitable model is the one assuming a Fréchet for ozone and a Weibull for the other pollutant. Results show that, in the present case, the estimated association parameter is a good representation to the correlation parameters between the pair of pollutants analyzed. Additionally, it is a straightforward task to obtain these correlation parameters from the corresponding association parameters.

Air Quality Estimation Using Nonhomogeneous Markov Chains: A Case Study Comparing Two Rules Applied to Mexico City Data

A nonhomogeneous Markov chain is applied to the study of the air quality classification in Mexico City when the so-called criterion pollutants are used. We consider the indices associated with air quality using two regulations where different ways of classification are taken into account. Parameters of the model are the initial and transition probabilities of the chain. They are estimated under the Bayesian point of view through samples generated directly from the corresponding posterior distributions. Using the estimated parameters, the probability of having an air quality index in a given hour of the day is obtained.

A Gibbs Sampling Algorithm to Estimate the Parameters of a Volatility Model: An Application to Ozone Data

In this work we consider a stochastic volatility model, commonly used in financial time series studies, to analyse ozone data. The model considered depends on some parameters and in order to estimate them a Markov chain Monte Carlo algorithm is proposed. The algorithm considered here is the so-called Gibbs sampling algorithm which is programmed using the language R. Its code is also given. The model and the algorithm are applied to the weekly ozone averaged measurements obtained from the monitoring network of Mexico City.

Analysis of Ozone Behaviour in the City of Puebla-Mexico Using Non-Homogeneous Poisson Models with Multiple Change-Points

In this work, some non-homogeneous Poisson models are considered to study the behaviour of ozone in the city of Puebla, Mexico. Several functions are used as the rate function for the non-homogeneous Poisson process. In addition to their dependence on time, these rate functions also depend on some parameters that need to be estimated. In order to estimate them, a Bayesian approach will be taken. The expressions for the distributions of the parameters involved in the models are very complex. Therefore, Markov chain Monte Carlo algorithms are used to estimate them. The methodology is applied to the ozone data from the city of Puebla, Mexico.