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中国钴—镍成矿规律与高效勘查技术 被引量:18
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作者 张照伟 李文渊 +8 位作者 丰成友 王辉 王亚磊 武军杰 李德贤 吕新彪 朱伯鹏 惠博 刘会文 《西北地质》 CAS CSCD 北大核心 2022年第2期14-34,共21页
钴、镍是全球战略性关键矿产,对国民经济、国家安全和科技发展具有重要战略意义。中国现有钴、镍资源储量均较低,超过90%的钴、镍原材料依赖进口,给国家战略性关键矿产资源供应带来重大安全隐患。因此,立足国内,加强钴—镍成矿规律研究... 钴、镍是全球战略性关键矿产,对国民经济、国家安全和科技发展具有重要战略意义。中国现有钴、镍资源储量均较低,超过90%的钴、镍原材料依赖进口,给国家战略性关键矿产资源供应带来重大安全隐患。因此,立足国内,加强钴—镍成矿规律研究,创新高效勘查技术,寻找新的接续资源已迫在眉睫。中国含钴矿床类型多样,特别是随着钴成矿新类型(辽吉带变沉积岩容矿钴—铜矿及三江带伴生钴矿)的发现,展示了巨大的找矿前景。但目前不同类型矿床中钴—镍发育特征、赋存状态、富集机制与成矿潜力尚不明确,缺少针对性的找矿模型与高效的勘查技术方法,极大地制约了钴—镍资源的找矿突破。笔者拟通过对钴—镍元素超常富集机理与成矿规律及勘查技术的研究,解决大陆聚—散过程中多圈层相互作用与钴—镍超常富集机理的重大科学问题和空—地—井高精度重磁电震物探数据采集、处理与多参数联合正反演解译的关键技术难题,旨在揭示钴—镍矿产资源成矿潜力和找矿新靶区,支撑服务战略性矿产找矿行动,极大增强中国钴—镍矿产资源安全供应保障能力。 展开更多
关键词 钴—镍 富集机理 成矿规律 勘查技术 找矿潜力
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青海野马泉铁锌矿床二长花岗岩锆石U-Pb和金云母Ar-Ar测年及地质意义 被引量:12
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作者 刘建楠 丰成友 +4 位作者 何书跃 裴荣富 李大新 瞿泓滢 白生龙 《大地构造与成矿学》 EI CAS CSCD 北大核心 2017年第6期1158-1170,共13页
青海野马泉铁锌矿床地处祁漫塔格山与柴达木盆地之间的盆山结合部位,是矽卡岩型铁锌多金属矿床。矿体均呈隐伏?半隐伏状产出、具多期次强烈岩浆活动叠加等特征。长期以来,有关野马泉铁锌多金属矿床的成矿岩体和成矿时代众说纷纭,制约了... 青海野马泉铁锌矿床地处祁漫塔格山与柴达木盆地之间的盆山结合部位,是矽卡岩型铁锌多金属矿床。矿体均呈隐伏?半隐伏状产出、具多期次强烈岩浆活动叠加等特征。长期以来,有关野马泉铁锌多金属矿床的成矿岩体和成矿时代众说纷纭,制约了对该矿床成因机制的认识及进一步的矿产勘查工作。本文基于详细的野外实地调查和矿床地质特征解剖,开展了成岩成矿年龄精测,探讨了成矿构造环境。铁锌矿体产于二长花岗岩与围岩地层的外接触带,发育石榴子石、透辉石、金云母、绿帘石等矽卡岩化作用。利用LA-ICP-MS锆石U-Pb法,获得成矿二长花岗岩的年龄为229.5±2.2 Ma(n=22,MSWD=1.3);采用Ar-Ar分步升温法获得与磁铁矿共生的金云母坪年龄为222.0±1.3 Ma(MSWD=0.41)、等时线年龄为222.4±2.5 Ma(MSWD=1.4),证实野马泉铁锌多金属矿床形成于晚三叠世,成矿岩体属过铝质、高钾钙碱性系列,为I-A过渡型花岗岩,具有高SiO_2,高K_2O/Na_2O,低P_2O_5,低Sr高Yb的特点。结合区域其他多金属矿床最新成岩成矿年代学数据,认为野马泉矿床形成于东昆仑地区海西?印支造山旋回晚期、由碰撞向后碰撞转换的地质构造环境。 展开更多
关键词 锆石U-PB年龄 金云母Ar-Ar年龄 野马泉铁锌矿床 祁漫塔格 东昆仑
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赣北大湖塘地区昆山钨-钼-铜矿床流体包裹体研究和稳定同位素特征 被引量:6
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作者 张明玉 丰成友 +4 位作者 武广 王辉 吴玉 韩梅梅 武文恒 《岩石学报》 SCIE EI CAS CSCD 北大核心 2018年第9期2615-2631,共17页
昆山矿床位于大湖塘钨多金属矿田的南部,产出石英细脉带型W-Mo-Cu矿体。该矿床的成矿过程可以划分为黑钨矿-石英阶段(Ⅰ)、辉钼矿-石英阶段(Ⅱ)、黄铜矿-石英阶段(Ⅲ)及石英-方解石阶段(Ⅳ)。本文通过流体包裹体岩相学、显微测温、激光... 昆山矿床位于大湖塘钨多金属矿田的南部,产出石英细脉带型W-Mo-Cu矿体。该矿床的成矿过程可以划分为黑钨矿-石英阶段(Ⅰ)、辉钼矿-石英阶段(Ⅱ)、黄铜矿-石英阶段(Ⅲ)及石英-方解石阶段(Ⅳ)。本文通过流体包裹体岩相学、显微测温、激光拉曼光谱和稳定同位素研究,探讨了昆山矿床的成因机制。研究结果表明,昆山矿床发育纯气相型(PG)、纯液相型(PL)、富液两相水溶液型(WL)三类包裹体。Ⅰ阶段主要发育WL型流体包裹体,并有少量PG型包裹体,均一温度为236~388℃,盐度为0. 5%~13. 8%NaCleqv,密度为0. 54~0. 90g/cm^3;Ⅱ阶段亦主要发育WL型和少量PG型包裹体,其均一温度为221~390℃,盐度为0. 5%~12. 7%Na Cleqv,密度为0. 51~0. 93g/cm^3;Ⅲ阶段主要发育WL型包裹体,均一温度为228~376℃,盐度为0. 7%~11. 2%NaCleqv,密度为0. 57~0. 91g/cm^3;Ⅳ阶段主要发育WL型包裹体,并有少量的PL型包裹体,其均一温度为173~288℃,盐度为0. 4%~11. 8%NaCleqv,密度为0. 76~0. 97g/cm^3。主成矿阶段流体属于中高温、中低盐度、中等密度流体,成矿晚阶段流体属于中低温、中低盐度、中高密度流体。包裹体气相成分主要是H_2O,亦有少量CH_4和CO_2,成矿流体总体上属于H_2O-NaCl-(CH_4-CO_2)体系。Ⅰ、Ⅱ和Ⅲ阶段成矿流体的δD值为-92‰~-56‰,计算获得的δ^(18)O水值为3. 8‰~6. 4‰;石英-方解石阶段的δD值为-68‰~-58‰,δ^(18)O水值为0. 5‰~0. 7‰。H-O同位素结果表明,昆山矿床主成矿阶段的流体以岩浆水为主,成矿晚阶段有少量的大气降水加入。金属硫化物的δ^(34)S值分布集中,其值为-1. 5‰~3. 0‰,表明成矿流体中的硫主要来自深源岩浆。辉钼矿-石英阶段的石英包裹体中CO_2的δ^(13)CV-PDB值为-6. 6‰和-5. 9‰,平均-6. 3‰;晚阶段石英-方解石脉中方解石的δ^(13)CV-PDB值为-12. 3‰~-10. 2‰,平均-11. 0‰,表明昆山矿床主成矿阶段流体中的碳主要由花岗岩浆提供,且受低温蚀变作用的影响,而晚阶段方解石脉中的碳还受到了双桥山群沉积有机物质的影响。成矿流体的冷却作用是导致昆山矿床钨、钼和铜沉淀的主要机制。 展开更多
关键词 流体包裹体 H-O-C-S同位素 昆山W-Mo-Cu矿床 大湖塘矿田 赣北
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赣南隆坪萤石矿床成矿时代及成因初探:来自萤石Sm-Nd测年及黑云母电子探针的证据 被引量:14
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作者 杨世文 丰成友 +3 位作者 楼法生 张芳荣 贺斌 曹员兵 《高校地质学报》 CAS CSCD 北大核心 2019年第3期341-351,共11页
隆坪萤石矿床是赣南已探明的大型单一萤石矿床,矿体产于永丰复式岩体外接触带北东向硅化破碎带中。文章首次采用Sm-Nd等时线法对隆坪萤石矿进行测年和稀土元素分析,并对永丰复式岩体中黑云母矿物成分进行了系统的测试;获得了隆坪萤石矿... 隆坪萤石矿床是赣南已探明的大型单一萤石矿床,矿体产于永丰复式岩体外接触带北东向硅化破碎带中。文章首次采用Sm-Nd等时线法对隆坪萤石矿进行测年和稀土元素分析,并对永丰复式岩体中黑云母矿物成分进行了系统的测试;获得了隆坪萤石矿的成矿年龄为158±3 Ma,与永丰复式岩体的成岩时代基本一致,表明该矿床萤石成矿作用与晚侏罗世岩浆活动关系密切。隆坪萤石矿中萤石轻稀土元素略富集,重稀土相对平坦,具微弱Ce正异常(δCe=1.08~1.11,平均1.09)和微弱Eu负异常(δEu=0.91~0.98,平均0.95),指示了萤石矿床的成矿流体经历了相对较高的温度。黑云母电子探针分析结果证实永丰复式岩体形成于相对高温、低压和高氧逸度的环境,岩浆起源于古老地壳物质的部分熔融,岩浆结晶分异晚阶段岩浆期后热液富含F等挥发分。隆坪萤石矿床形成于晚侏罗世,成因类型为岩浆期后热液充填型。 展开更多
关键词 隆坪萤石矿床 SM-ND定年 黑云母电子探针 矿床成因
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全球钴矿资源特征及勘查研究进展 被引量:39
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作者 王辉 丰成友 张明玉 《矿床地质》 CAS CSCD 北大核心 2019年第4期739-750,共12页
近年来,钴矿相关新兴产业方兴未艾,从新能源汽车的充电电池到喷气涡轮机中的超级合金,钴均是不可或缺的关键金属材料之一。文章介绍了全球钴矿类型及分布特征,着重对近年来全球钴矿的勘查、研究取得的进展进行了梳理和总结。迄今为止,... 近年来,钴矿相关新兴产业方兴未艾,从新能源汽车的充电电池到喷气涡轮机中的超级合金,钴均是不可或缺的关键金属材料之一。文章介绍了全球钴矿类型及分布特征,着重对近年来全球钴矿的勘查、研究取得的进展进行了梳理和总结。迄今为止,全球钴资源主要来源于沉积岩容矿型层控Cu-Co矿床、红土型Ni-Co矿床和岩浆型Ni-Cu-Co矿床及热液、火山成因钴多金属矿床,但总体分布极不均衡。热液及火山成因Co多金属矿床多数以Co为主要金属,表现出较大的找矿的潜力。上述几种钴矿床大多与基性-超基性岩有着直接的或间接的成因联系。此外,还有大量的钴资源赋存在洋底Fe-Mn结核与结壳内。关于钴矿的成矿条件、构造背景与成矿机理等关键问题仍亟需开展进一步的研究工作,深入理解钴矿的成矿规律并建立行之有效的找矿模型,将为“新能源时代”钴矿的勘查和开发提供有效的支撑和指导。 展开更多
关键词 地质学 钴矿床 成因类型 资源特征 勘查进展 研究现状
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闽西行洛坑钨矿流体演化过程与成矿机制:白钨矿原位微量元素、Sr同位素的制约 被引量:8
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作者 王辉 丰成友 +4 位作者 李荣西 李超 赵超 陈欣 王光华 《岩石学报》 SCIE EI CAS CSCD 北大核心 2021年第3期698-716,共19页
行洛坑钨矿位于武夷山成矿带中部,是该带目前规模最大的钨矿床。钨矿体主要产于强烈蚀变的似斑状黑云母花岗岩岩株顶部,发育细脉浸染状、网脉状及大脉状多种矿化类型,黑钨矿与白钨矿含量近1∶1。关于矿床的流体演化过程与成矿机制目前... 行洛坑钨矿位于武夷山成矿带中部,是该带目前规模最大的钨矿床。钨矿体主要产于强烈蚀变的似斑状黑云母花岗岩岩株顶部,发育细脉浸染状、网脉状及大脉状多种矿化类型,黑钨矿与白钨矿含量近1∶1。关于矿床的流体演化过程与成矿机制目前仍不清楚,成因存在较大争议。本文在详细成矿阶段划分的基础上,对不同阶段产出的不同世代白钨矿开展了系统的原位LA-ICP-MS微量元素和Sr同位素、以及流体包裹体和H-O同位素的研究工作。行洛坑钨矿由早至晚可以划分为3个成矿阶段:细脉浸染状白钨矿-辉钼矿阶段(阶段Ⅰ)、钾长石-白钨矿-黑钨矿-绿柱石阶段(阶段Ⅱ)及硫化物-黑钨矿-白钨矿-碳酸盐阶段(阶段Ⅲ)。流体包裹体研究显示成矿流体为中高温、低盐度的Na Cl-H_2O-CO_2体系。H-O与Sr同位素表明成矿流体主要为岩浆流体,仅成矿晚期阶段有少量的大气降水加入。阶段I白钨矿相对富REE、Mo、Na和Nb,贫Sr;而随着流体演化,白钨矿REE、Mo、Na、Nb含量逐渐降低,Sr含量显著升高。阶段I白钨矿呈自形-半自形粒状,CL图像显示细密的、均匀的震荡环带,稀土元素主要与Na和Nb结合进入白钨矿晶格;阶段Ⅱ、阶段Ⅲ白钨矿呈半自形-他形,不发育或仅发育宽缓的、不规则震荡环带,稀土元素与Ca(Ca的离子空位)结合置换白钨矿中的Ca。结合蚀变与矿化特征,认为阶段I白钨矿形成于低水岩比环境,由初始岩浆流体沿微小裂隙渗透交代而形成;而阶段Ⅱ、Ⅲ白钨矿形成于高水岩比环境,CO_2的不混溶作用伴随强烈的水岩反应导致了钨的富集沉淀。结合矿床地质特征,认为行洛坑钨矿属于广义的斑岩型钨矿,细脉浸染状矿化构成了钨成矿的基础,而网脉状、大脉状矿化的叠加是钨进一步富集的关键。 展开更多
关键词 白钨矿 流体演化 斑岩型钨矿 行洛坑 武夷山成矿带
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大兴安岭北部漠河地区早奥陶世A型花岗岩锆石U-Pb年代学、地球化学及Hf同位素研究 被引量:13
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作者 吴琼 丰成友 +3 位作者 瞿泓滢 钟世华 刘建楠 张明玉 《地质学报》 EI CAS CSCD 北大核心 2019年第2期368-380,共13页
大兴安岭北部漠河地区黑云母二长花岗岩中锆石自形程度较好,主要为长柱状,具有较为清晰的韵律环带结构,表明锆石岩浆成因。锆石LA-ICP-MS U-Pb年代学研究显示岩石形成时代为早奥陶世(481±5Ma)。岩石地球化学研究显示,岩石属于钙碱... 大兴安岭北部漠河地区黑云母二长花岗岩中锆石自形程度较好,主要为长柱状,具有较为清晰的韵律环带结构,表明锆石岩浆成因。锆石LA-ICP-MS U-Pb年代学研究显示岩石形成时代为早奥陶世(481±5Ma)。岩石地球化学研究显示,岩石属于钙碱性、弱过铝质系列花岗岩,高硅(SiO_2=71.42%~72.57%)、富碱(ALK=8.11%~8.76%)、贫镁(MgO=0.52%~0.54%)。10000Ga/Al值为2.73~2.85,Zr+Nb+Ce+Y含量374×10^(-6)~495×10^(-6),岩浆形成温度801~897℃,判断岩石为A型花岗岩。岩石有中等的负Eu异常(δEu=0.24~0.35),Rb/Sr值为1.18~1.38、Ba/La值为8.7~12.4、Mg~#值为23.3~30.3,及低Ni(1.51×10^(-6)~5.59×10^(-6))、Cr(6.60×10^(-6)~13.4×10^(-6))、V(20.0×10^(-6)~21.6×10^(-6))含量。岩石的ε_(Hf)(t)值为-2.22~5.57,二阶段模式年龄(t_(DM2))变化于1021~1453Ma之间,主要源于中新元古代增生地壳。结合区域构造演化及构造判别,认为岩石形成于额尔古纳地块与西伯利亚板块拼合造山后的伸展背景。 展开更多
关键词 锆石U-Pb年龄 岩石地球化学 兴华渡口群 A型花岗岩 大兴安岭 漠河地区
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运用机器学习和锆石微量元素构建花岗岩成矿潜力判别图解:以东昆仑祁漫塔格为例 被引量:4
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作者 郭广慧 钟世华 +7 位作者 李三忠 丰成友 戴黎明 索艳慧 刘嘉情 牛警徽 黄宇 薛梓萌 《西北地质》 CAS CSCD 北大核心 2023年第6期57-70,共14页
由于锆石在中酸性岩中广泛存在且成分稳定、不易受到后期热液活动的扰动,因此锆石成分可以有效记录成矿岩浆信息。其中,锆石的Ce^(4+)/Ce^(3+)、Ce/Ce*、Eu/Eu*和Ce/Nd值可以反映岩浆氧逸度和含水量等成矿信息,已被广泛用于花岗岩类成... 由于锆石在中酸性岩中广泛存在且成分稳定、不易受到后期热液活动的扰动,因此锆石成分可以有效记录成矿岩浆信息。其中,锆石的Ce^(4+)/Ce^(3+)、Ce/Ce*、Eu/Eu*和Ce/Nd值可以反映岩浆氧逸度和含水量等成矿信息,已被广泛用于花岗岩类成矿潜力评价。然而,随着研究的深入发现,这些地球化学指标并不完全具有普适性。此外,以往研究均是根据对成矿岩体的“已知认识”提出成矿潜力判别方法,但考虑到成矿过程的复杂性,许多反映岩浆成矿能力的地球化学信息可能均尚未被揭露。为此,笔者以东昆仑祁漫塔格成矿带为例,借助当前广泛应用的机器学习算法之一—支持向量机,对来自该成矿带斑岩-矽卡岩Cu-Fe-Pb-Zn多金属矿床成矿岩体和全球非成矿岩体的锆石数据开展机器学习训练,目的在于挖掘能够反映岩浆成矿能力的锆石微量元素特征,从而构建花岗岩成矿潜力判别图解。模型训练结果显示,在21个常见的锆石微量元素特征中,Gd、Dy、Yb、Y、Tm等5种元素特征对识别岩浆成矿能力最为重要。在此基础上,笔者新建立了10个二元判别图解,它们在识别成矿岩体和非成矿岩体时的准确率均接近1。研究表明,利用机器学习方法和地质大数据,可以挖掘传统研究方法难以发现的新的地球化学指标和图解,这对深入认识矿床成因、指导找矿勘查具有重要意义。 展开更多
关键词 锆石微量元素 花岗岩 二元判别图解 机器学习 东昆仑
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基于机器学习和全岩成分识别东昆仑祁漫塔格斑岩-矽卡岩矿床成矿岩体和贫矿岩体 被引量:2
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作者 刘嘉情 钟世华 +7 位作者 李三忠 丰成友 戴黎明 索艳慧 郭广慧 牛警徽 薛梓萌 黄宇 《西北地质》 CAS CSCD 北大核心 2023年第6期41-56,共16页
东昆仑祁漫塔格成矿带是中国西北地区重要的铜钼铁铅锌多金属成矿带,发育卡尔却卡、野马泉、维宝、乌兰乌珠儿等许多与花岗岩类有关的斑岩-矽卡岩矿床。随着新一轮找矿突破战略行动的开展,进一步加强对祁漫塔格成矿带花岗岩成矿潜力的研... 东昆仑祁漫塔格成矿带是中国西北地区重要的铜钼铁铅锌多金属成矿带,发育卡尔却卡、野马泉、维宝、乌兰乌珠儿等许多与花岗岩类有关的斑岩-矽卡岩矿床。随着新一轮找矿突破战略行动的开展,进一步加强对祁漫塔格成矿带花岗岩成矿潜力的研究,已成为推动该地区金属矿产储量增长的重要突破口。为此,笔者在系统收集祁漫塔格成矿带典型斑岩-矽卡岩多金属矿床成矿岩体和贫矿岩体(即非成矿岩体)的全岩主量和微量元素数据基础上,选取28种常见的全岩地球化学特征,借助机器学习算法——随机森林,开展机器学习模型训练,建立能够识别该地区斑岩-矽卡岩多金属矿床成矿岩体和非成矿岩体的新方法。根据模型评价指标,笔者训练得到的随机森林分类模型准确率为0.90,证明该方法能够有效识别成矿岩体和非成矿岩体。该研究为祁漫塔格成矿带斑岩-矽卡岩多金属矿床的找矿勘查提供了新思路,将极大地提高找矿效率、降低找矿经济和人力成本,从而更好的服务新一轮找矿突破战略行动。相关机器学习代码已上传至GitHub,地址为https://github.com/ShihuaZhong/2023-Qimantagh-RF-whole-rock-classifier。 展开更多
关键词 成矿潜力 全岩主微量元素 随机森林 机器学习 祁漫塔格 东昆仑
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Isotopic Chronological Study of the Huangsha-Tieshanlong Quartz Vein-Type Tungsten Deposit and Timescale of Molybdenum Mineralization in Southern Jiangxi Province,China 被引量:19
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作者 HUANG Fan feng chengyou +4 位作者 CHEN Yuchuan YING Lijuan CHEN Zhenghui1 ZENG Zailin QU Wenjun 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2011年第6期1434-1447,共14页
The Huangsha-Tieshanlong quartz-vein tungsten polymetallic ore deposit, located in the northern Pangushan-Tieshanlong tungsten ore field in eastern Ganxian-Yudu prospecting areas of the Yushan metallogenic belt, is a ... The Huangsha-Tieshanlong quartz-vein tungsten polymetallic ore deposit, located in the northern Pangushan-Tieshanlong tungsten ore field in eastern Ganxian-Yudu prospecting areas of the Yushan metallogenic belt, is a well-known tungsten deposit in southern Jiangxi province, China. SHRIMP-determined dating of zircons from the Tieshanlong granite yields ages of 168.1±2.1 Ma (n=11, MSWD-1.3). Rhenium and osmium isotopic dating of molybdenite from the Huangsha quartz-vein tungsten deposit determined by ICP-MS yields a weighted average ages of 153-3 Ma and model ages of 150.22.1 Ma - 155.4-2.3 Ma. The age of the Huangsha tungsten deposit is 10 to 15 Ma later than the Tieshanlong granite, which shows that there might have been another early Late Jurassic magmatic activity between 150 and 160 Ma, a process which is closely related with tungsten mineralization in this area. The Tieshanlong granite, the Hnangsha tungsten deposit and the Pangushan-Tieshanlong ore field were all formed around 150-170 Ma, belonging to products of a Mesozoic second large-scale mineralization. According to the collected molybdenite Re-Os dating results in southern Jiangxi province, the timescale of the associated molybdenum mineralization is 2-6 Ma in the tungsten deposit and the timescale of independent molybdenum mineralization is 1-4 Ma, implying the complexity of tungsten mineralization. Times of molybdenum mineralization are mainly concentrated in the Yanshanian, which includes three stages of 133-135 Ma, 150-162 Ma, and 166-170 Ma, respectively. The 150-162 Ma-stage is in accordance with ages of large-scale WoSn mineralization, which is mainly molybdenum mineralization characterized by associated molybdenum mineralization with development of an even greater-intensity independent molybdenum mineralization. Independent molybdenum mineralization occurred before and after large-scale W-Sn mineralization, which indicates that favorable prospecting period for molybdenum may be in Cretaceous and early late Jurassic. 展开更多
关键词 SHRIMP zircon U-Pb molybdenite Re-Os ages TIMESCALE granite quartz vein-type tungsten deposit Huangsha Tieshanlong Jiangxi
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Mineralization Styles and Genesis of the Yinkeng Au-Ag-Pb-Zn-Cu-Mn Polymetallic Orefield, Southern Jiangxi Province, SE China: Evidence from Geology, Fluid Inclusions, Isotopes and Chronology 被引量:14
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作者 feng chengyou LI Daxin +2 位作者 ZENG Zailin ZHANG Dequan SHE Hongquan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第3期825-844,共20页
The Yinkeng orefield in Yudu County,Jiangxi Province,SE China,is a zone of concentrated Au-Ag-Pb-Zn-Cu-Mn polymetallic ores.Based on summing up basic geology and ore geology of the orefieid,the polymetallic deposits i... The Yinkeng orefield in Yudu County,Jiangxi Province,SE China,is a zone of concentrated Au-Ag-Pb-Zn-Cu-Mn polymetallic ores.Based on summing up basic geology and ore geology of the orefieid,the polymetallic deposits in the orefield have been divided into seven major substyles according to their occurring positions and control factors.The ore-forming fluid inclusion styles in the orefield include those of two-phase fluid,liquid CO2-bearing three-phase and daughter mineral-bearing multi-phase.The homogenization temperatures range from 382° to 122℃,falling into five clusters of 370° to 390°,300° to 360°,230° to 300°,210° to 290° and 120° to 200°,and the clusters of 300° to 360°,230° to 300° and 120° to 200° are three major mineralization stages,with fluid salinity peaks from 4.14% to 7.31%,2.07% to 7.31% and 0.53% to 3.90%,respectively.The ore-forming fluids are mainly type of NaCl-H2O with medium to high density (0.74-1.02 g/cm3),or CO2-bearing NaCl-H2O with medium to low density (0.18-0.79 g/cm3).The fluid salinity and density both show a decline tendency with decreasing temperature.According to the measurement and calculation of Hand O-isotopic compositions in the quartz of the quartz-sulfide veins,δDV-SMOW of the ore-forming fluid is from-84‰ to-54‰,and δ18OV-SMOW of that is from 6.75‰ to 9.21‰,indicating a magmatic fluid.The δ34SV-CDT of sulfides in the ores fall into two groups,one is from-4.4‰ to 2.2‰ with average of-1.42‰,and the other from 18.8‰ to 21.6‰ with average of 19.8‰.The S-isotopic data shows one peak at-4.4‰ to 2.2‰ (meaning-1.42‰) suggesting a simple magmatic sulfur source.The ore Pbisotopic ratios are 206pb/204pb from 17.817 to 17.983,207pb/204pb from 15.470 to 15.620 and 208pb/204pb from 38.072 to 38.481,indicating characteristics of mantle-derived lead.The data show that the major ore deposits in the orefield have a magmatic-hydrothermal genesis and that the SHRIMP zircon age of the granodiorite porphyry,closely related to the mineralization,is 151.2±4.2 Ma (MSWD =1.3),which can represent the formation ages of the ores and intrusion rocks.The study aids understanding of the ore-forming processes of the major metallic ore deposits in the orefield. 展开更多
关键词 Ore geology geochemistry fluid inclusion SHRIMP zircon U-Pb dating ore genesis Carboniferous Jiangxi Province
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Ages, Sources and Tectonic Settings of the Triassic Igneous Rocks in the Easternmost Segment of the East Kunlun Orogen, Central China 被引量:13
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作者 REN Haidong WANG Tao +5 位作者 ZHANG Lei WANG Xiaoxia HUANG He feng chengyou TESCHNER Claudia SONG Peng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第2期641-668,共28页
U–Pb analysis of zircons from igneous rocks in the Elashan Mountain, easternmost segment of the East Kunlun Orogen yielded 252–232 Ma. Geochemically, these rocks are mainly high in SiO_2, K_2O and K_2O+Na_2O conten... U–Pb analysis of zircons from igneous rocks in the Elashan Mountain, easternmost segment of the East Kunlun Orogen yielded 252–232 Ma. Geochemically, these rocks are mainly high in SiO_2, K_2O and K_2O+Na_2O contents, low in P_2O_5 and TiO_2 contents, depleted in Ba, Sr, P, Ti and enriched in U, Hf, Zr, showing features of I–type granite. The zircon εHf(t) values of the Early Triassic Jiamuge'er rhyolite porphyry(252±3 Ma) are positive(+1.6 to +12.1), suggesting a juvenile crustal source mixing with little old crustal component, and the zircon εHf(t) values of the Middle Triassic Manzhang'gang granodiorite(244±3 Ma) and Dehailong diorite(237±3 Ma) are predominately negative(-8.4 to +1.0), indicating an older crustal source. In comparison, the zircon εHf(t) values of the Late Triassic syenogranites from Suigen'ergang(234±2Ma), Ge'ermugang(233±2 Ma) and Yue'ergen(232±3 Ma) plutons vary from-3.8 to +5.0, suggesting a crust-mantle mixing source. From Early–Middle Triassic(252–237 Ma) to Late Triassic(234–232 Ma), the geochemical characteristics of these rocks show the change from a subduction–collision setting to a post-collision or within-plate setting. By comparing of these new age data with 77 zircon U–Pb ages of igneous rocks of the eastern part of East Kunlun orogen from published literatures, we conclude that the igneous rocks of Elashan Mountain and these of the eastern part of East Kunlun Orogen belong to one magmatic belt. All these data indicate that the Triassic magmatic events of the eastern part of East Kunlun Orogen can be divided into three stages: 252–238 Ma, 238–226 Ma and 226–212 Ma. Statistically, the average εHf(t) values of the threestage igneous rocks show a tendency, from the old to young, from-0.75±0.25 to lower-2.65±0.52 and then to-1.22±0.25, respectively, which reveal the change of their sources. These characteristics can be explained as a crust-mantle mixing source generated in a subductional stage, mainly crust source in a syn–collisional stage and a crust-mantle mixing source(lower crust with mantle-derived underplating magma) in a post-collisional stage. The identification of these three magmatic events in the Elashan Mountain, including all the eastern part of East Kunlun Orogen, provides new evidence for better understanding of the tectonic evolution of the northward subduction and closure of the Paleo-Tethyan(252–238 Ma), the collision of the Songpan–Ganzi block with the southern margin of Qaidam block(238–226 Ma), and the post–collisional setting(226–212 Ma) during the Early Mesozoic period. 展开更多
关键词 GRANITOIDS zircon U–Pb dating magmatic evolution isotopes TRIASSIC the East Kunlun orogen
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China's First Independent Cobalt Deposit and its Metallogenic Mechanism:Evidence from Fluid Inclusions and Isotopic Geochemistry 被引量:9
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作者 feng chengyou QI feng +2 位作者 ZHANG Dequan LI Daxin SHE Hongquan 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2011年第6期1403-1418,共16页
The Tuolugou cobalt deposit is the first independent large-scale Co- and Au-bearing deposit discovered in northwestern China. It is located in the eastern Kunlun orogenic belt in Qinghai Province, and occurs conformab... The Tuolugou cobalt deposit is the first independent large-scale Co- and Au-bearing deposit discovered in northwestern China. It is located in the eastern Kunlun orogenic belt in Qinghai Province, and occurs conformably in low-grade metamorphic volcano-sedimentary rock series with well-developed Na-rich hydrothermal sedimentary rocks and typical hydrothermal sedimentary ore fabrics. Fluid inclusions and isotopic geochemistry studies suggest that cobalt mineralizing fluid is dominated by NaCI-H20 system, accompanied by NaCI-CO2-H20-N2 system responsible for gold mineralization. Massive, banded and disseminated pyrite ores have similar compositions of He and Ar isotopes from the mineralizing fluid, with 3He/4He range between 0.10 to 0.31Ra (averaging 0.21Ra), and 4~Ar/36Ar between 302 and 569 (averaging 373), which reflects that Co mineralizing fluids derived dominantly from meteoric water deeply circulating. ~34S values of pyrite approaches to zero (~34S ranging from -4.5%o to +1.5%o, centering around -1.8%o to -0.2%o), reflecting its deep source. Ore lead is characterized by distinctly high radiogenesis, with 2~6pb/2~4pb〉19.279, 2~7pb/2~4pb〉15.691 and 2~spb/2~4pb〉39.627, and its values show an increase trend from country rocks, regional Paleozoic volcanic rocks to ores. This may have suggested that high radiogentic ore Pb derived mainly from country rocks by leaching meteoric water-dominated hydrothermal fluid during its circulation at depth. Cobalt occurs mainly in sulfide phase (such as pyrite), but cobalt enrichment, and presence and increasing contents of Co-bearing minerals have a positive correlation with metamorphic degree. The Tuolugou deposit and other typical strata-bound Co-Cu-Au deposits have striking similarities in the geological features and metallogenic pattern of primary cobalt. All of them are syngenetic hydrothermal exhalative sedimentation in origin. 展开更多
关键词 cobalt deposit fluid inclusion isotopic geochemistry SEDEX metallogenic mechanism Tuolugou in Qinghai Province eastern Knnlun orogenic belt
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Chronology of the Tungsten Deposits in Southern Jiangxi Province, and Episodes and Zonation of the Regional W-Sn Mineralization-Evidence from High-precision Zircon U-Pb, Molybdenite Re-Os and Muscovite Ar-Ar Ages 被引量:9
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作者 feng chengyou ZHANG Dequan +1 位作者 ZENG Zailind WANG Song 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2012年第3期555-567,共13页
Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP (sensitive high-resolution ion microprobe) zircon U-Pb, zircon LA-ICPMS (laser-ablation-inductively coupled plasma ma... Previous studies have obtained some petrogenetic and metallogenic chronological data with SHRIMP (sensitive high-resolution ion microprobe) zircon U-Pb, zircon LA-ICPMS (laser-ablation-inductively coupled plasma mass spectroscopy) U-Pb, molybdenite Re-Os isochron and muscovite Ar-Ar methods in southern Jiangxi Province and its adjacent areas. Based on these, the purpose of this paper is to study the petrogenetic and metallogenic ages and their time gap for different genetic types of W-Sn deposits, and thus to research their numerous episodes, zonal arrangement and their geodynamic background. The result shows that the large-scale W-Sn mineralization in southern Jiangxi Province occurred in the middle to late Jurassic (170-150 Ma), the skarn W-Sn-polymetallic deposits formed much earlier (170-161 Ma), and all of the wolframite-quartz vein type, greisen type, altered granite type and fractured zone type tungsten deposits formed in the late Jurassic (160-150 Ma). In one ore field or ore district, greisen type tungsten deposits formed earlier than quartz vein type ones hosted in the endoor exo-contact zone; and quartz vein type hosted in the endocontact zone formed earlier than that of exocontact zone. There is no significant time difference between tungstentin mineralization and its intimately associated parent granite emplacement (1-6 Ma). They all formed in the same rock-forming and ore-forming system and under the same geodynamic setting. Regionally, rock-forming and ore-forming processes of the W-Sn deposits in the Nanling region (include southern Jiangxi Province, southern Hunan Province, northern Guangdong Province and eastern Guangxi Zhuang Autonomous Region) exhibit numerous episodes. The mineralization in the Nanling region mainly occurred at (240-210) Ma, (170-150) Ma and (130-90) Ma. The tungsten-tin deposits in this region are centered by the largest scale in southern Jiangxi Province and southern Hunan Province, and become small in the east, west, south and north directions. This displays a zonal arrangement and temporal and spatial distribution regularity. Integrated with the latest research results, it is concluded that the W-Sn mineralization in southern Jiangxi Province and its adjacent areas corresponds to the second large-scale mineralization in South China. The Indosinian W-Sn mineralization formed under the extensional tectonic regime between collisional compressional stages, while the Yanshanian large-scale petrogenetic and metallogenic processes occurred in the Jurassic intraplate extensional geodynamic setting of lithosphere extension. 展开更多
关键词 isotopic chronology mutiple episodes of mineralization geodynamics W-Sn deposit Southern Jiangxi NANLING
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赣南隆坪萤石矿床成矿流体特征及成矿模式 被引量:4
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作者 杨世文 丰成友 +1 位作者 楼法生 许德如 《地质学报》 EI CAS CSCD 北大核心 2022年第11期3886-3900,共15页
赣南兴国县隆坪大型萤石矿床位于大余-南城深大断裂西侧兴国-宁都萤石成矿带内,呈板状、似层状、脉状产于永丰复式岩体外接触带北东向硅化破碎带中。本文划分了兴国县隆坪萤石矿床的成矿阶段,通过流体包裹体岩相学、显微测温、激光拉曼... 赣南兴国县隆坪大型萤石矿床位于大余-南城深大断裂西侧兴国-宁都萤石成矿带内,呈板状、似层状、脉状产于永丰复式岩体外接触带北东向硅化破碎带中。本文划分了兴国县隆坪萤石矿床的成矿阶段,通过流体包裹体岩相学、显微测温、激光拉曼成分分析和H-O同位素研究,讨论了该矿床成矿流体性质、来源、演化与成矿模式。根据矿物穿插关系和矿相学特征,将隆坪萤石矿床划分为3个成矿阶段,即成矿早阶段(萤石-石英阶段)、成矿主阶段(石英-萤石阶段)和成矿晚阶段(萤石-方解石阶段)。流体包裹体类型主要为富液相两相包裹体,均一温度变化范围在111~374℃之间,盐度变化于0.53%~3.55%NaCleq之间,密度变化于0.58~1.02 g/cm^(3)之间。包裹体成分以H_(2)O为主。总体而言,成矿流体属于中低温、中低盐度、中低密度的NaCl-H_(2)O体系,但成矿早阶段存在高温、相对高盐度的流体端元(温度大于300℃,盐度为2.0%~2.7%NaCleq),推断永丰复式岩体晚阶段岩浆热液参与早阶段萤石成矿作用,提供F的来源和热源。隆坪萤石矿床流体包裹体中的δD_(V-SMOW)和δ^(18)O_(V-SMOW)值均较低,分别为-66.8‰~-53.1‰(平均值为-59.5‰)和-5.9‰~-3.3‰(平均值为-4.6‰),成矿流体主要来源于大气降水和地热水。成矿早阶段萤石沉淀机制主要为岩浆热液和大气降水混合与水-岩反应,而流体冷却作用是成矿主阶段和晚阶段萤石沉淀的主要机制。隆坪萤石矿床属断裂控矿、中低温热液裂隙充填型萤石矿床。 展开更多
关键词 赣南 隆坪萤石矿床 流体包裹体 H-O同位素 成矿模型
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The Major Ore Clusters of Super-Large Iron Deposits in the World, Present Situation of Iron Resources in China, and Prospect 被引量:2
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作者 ZHAO Yiming feng chengyou LI Daxin 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2014年第6期1895-1915,共21页
The metamorphosed sedimentary type of iron deposits(BIF) is the most important type of iron deposits in the world, and super-large iron ore clusters of this type include the Quadrilatero Ferrifero district and Caraj... The metamorphosed sedimentary type of iron deposits(BIF) is the most important type of iron deposits in the world, and super-large iron ore clusters of this type include the Quadrilatero Ferrifero district and Carajas in Brazil, Hamersley in Australia, Kursk in Russia, Central Province of India and Anshan-Benxi in China. Subordinated types of iron deposits are magmatic, volcanic-hosted and sedimentary ones. This paper briefly introduces the geological characteristics of major super-large iron ore clusters in the world. The proven reserves of iron ores in China are relatively abundant, but they are mainly low-grade ores. Moreover, a considerate part of iron ores are difficult to utilize for their difficult ore dressing, deep burial or other reasons. Iron ore deposits are relatively concentrated in 11 metallogenic provinces(belts), such as the Anshan-Benxi, eastern Hebei, Xichang-Central Yunnan Province and middle-lower reaches of Yangtze River. The main minerogenetic epoches vary widely from the Archean to Quaternary, and are mainly the Late Archean to Middle Proterozoic, Variscan, and Yanshanian periods. The main 7 genetic types of iron deposits in China are metamorphosed sedimentary type(BIF), magmatic type, volcanic-hosted type, skarn type, hydrothermal type, sedimentary type and weathered leaching type. The iron-rich ores occur predominantly in the skarn and marine volcanic-hosted iron deposits, locally in the metamorphosed sedimentary type(BIF) as hydrothermal reformation products. The theory of minerogenetic series of mineral deposits and minerogenic models has applied in investigation and prospecting of iron ore deposits. A combination of deep analyses of aeromagnetic anomalies and geomagnetic anomalies, with gravity anomalies are an effective method to seeking large and deep-buried iron deposits. China has a relatively great oresearching potential of iron ores, especially for metamorphosed sedimentary, skarn, and marine volcanic-hosted iron deposits. For the lower guarantee degree of iron and steel industry, China should give a trading and open the foreign mining markets. 展开更多
关键词 major ore clusters of super-large iron deposits present situation of iron ore resources in China genetic type temporal-spatial distribution ore-searching potential
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