Geminal dinitropropyl ester plasticizers(DNPEPs) possess excellent energetic performances which provide good potentials as insensitive plasticizer. In this study, we design and synthesize DNPEPs with different alkane ...Geminal dinitropropyl ester plasticizers(DNPEPs) possess excellent energetic performances which provide good potentials as insensitive plasticizer. In this study, we design and synthesize DNPEPs with different alkane chain parts, and systematically investigate their structure-property relationships.Results show that DNPEPs have impact sensitivities all higher than 25.2 J, thermal decomposition temperatures all higher than 254 ℃, and glass transition temperatures(T_(g)) lower than-90 ℃.Furthermore, the effects of DNPEPs as plasticizer are studied on hydroxyl terminated polybutadiene(HTPB) in detail, including the viscosity, glass transition temperatures and others. It is noteworthy that 2,2-dinitropropyl nonanoate(DNPNc) among these DNPEPs exhibits the most expected simultaneous tuning effects on both viscosity and T_(g) of HTPB systems, providing favorable potentials to replace the conventional plastizers as dioctyl sebacate(DOS) in the HTPB based propellants and explosives.展开更多
为了研究液压活塞压缩机压缩气体的动态压缩过程,探究压缩机结构参数与压缩机压缩性能的关系,以撬装式井口天然气回收处理系统的液压活塞式压缩机二级缸为研究对象,基于液压活塞式压缩机二级缸工作原理,将仿真过程划分为3个阶段分步模拟...为了研究液压活塞压缩机压缩气体的动态压缩过程,探究压缩机结构参数与压缩机压缩性能的关系,以撬装式井口天然气回收处理系统的液压活塞式压缩机二级缸为研究对象,基于液压活塞式压缩机二级缸工作原理,将仿真过程划分为3个阶段分步模拟,借助Fluent软件,结合动网格和UDF(user defined functions)编译进行仿真分析,明确了二级缸内天然气的动态压缩过程,并将活塞运动作为压缩机压缩性能的评判指标,得到了二级缸结构参数对压缩机压缩性能的影响。研究表明:工作行程和下气缸出口分布与压缩性能关系不大,而下气缸出口大小的增大对压缩性能有较大提升,范围内最大增幅47.6%。相关研究为液压活塞式压缩机的优化与设计提供一定的参考。展开更多
Lowering the synthesis temperature of boron nitride nanotubes(BNNTs)is crucial for their development.The primary reason for adopting a high temperature is to enable the effective activation of highmelting-point solid ...Lowering the synthesis temperature of boron nitride nanotubes(BNNTs)is crucial for their development.The primary reason for adopting a high temperature is to enable the effective activation of highmelting-point solid boron.In this study,we developed a novel approach for efficiently activating boron by introducing alkali metal compounds into the conventional MgO–B system.This approach can be adopted to form various low-melting-point AM–Mg–B–O growth systems.These growth systems have improved catalytic capability and reactivity even under low-temperature conditions,facilitating the synthesis of BNNTs at temperatures as low as 850℃.In addition,molecular dynamics simulations based on density functional theory theoretically demonstrate that the systems maintain a liquid state at low temperatures and interact with N atoms to form BN chains.These findings offer novel insights into the design of boron activation and are expected to facilitate research on the low-temperature synthesis of BNNTs.展开更多
BACKGROUND Due to frequent and high-risk sports activities,the elbow joint is susceptible to injury,especially to cartilage tissue,which can cause pain,limited movement and even loss of joint function.AIM To evaluate ...BACKGROUND Due to frequent and high-risk sports activities,the elbow joint is susceptible to injury,especially to cartilage tissue,which can cause pain,limited movement and even loss of joint function.AIM To evaluate magnetic resonance imaging(MRI)multisequence imaging for improving the diagnostic accuracy of adult elbow cartilage injury.METHODS A total of 60 patients diagnosed with elbow cartilage injury in our hospital from January 2020 to December 2021 were enrolled in this retrospective study.We analyzed the accuracy of conventional MRI sequences(T1-weighted imaging,T2-weighted imaging,proton density weighted imaging,and T2 star weighted image)and Three-Dimensional Coronary Imaging by Spiral Scanning(3D-CISS)in the diagnosis of elbow cartilage injury.Arthroscopy was used as the gold standard to evaluate the diagnostic effect of single and combination sequences in different injury degrees and the consistency with arthroscopy.RESULTS The diagnostic accuracy of 3D-CISS sequence was 89.34%±4.98%,the sensitivity was 90%,and the specificity was 88.33%,which showed the best performance among all sequences(P<0.05).The combined application of the whole sequence had the highest accuracy in all sequence combinations,the accuracy of mild injury was 91.30%,the accuracy of moderate injury was 96.15%,and the accuracy of severe injury was 93.33%(P<0.05).Compared with arthroscopy,the combination of all MRI sequences had the highest consistency of 91.67%,and the kappa value reached 0.890(P<0.001).CONCLUSION Combination of 3D-CISS and each sequence had significant advantages in improving MRI diagnostic accuracy of elbow cartilage injuries in adults.Multisequence MRI is recommended to ensure the best diagnosis and treatment.展开更多
During the oil production, in order to monitor the working conditions of an electrical submersible pump （ESP）,an electrical current recorder is used to monitor the electric motor current of an ESP. The recorder char...During the oil production, in order to monitor the working conditions of an electrical submersible pump （ESP）,an electrical current recorder is used to monitor the electric motor current of an ESP. The recorder charts indicate various working conditions of the ESP. Subtle malfunctions or abnormal problems of the ESP can be detected and further analyzed from various features of these current curves on the recording charts. Presently, these current charts are manually read and analyzed in oil fields. In this paper, a diagnosis expert system is presented for automatically analyzing these current recording charts and identifying the working condition of the ESP. This expert system includes an open knowledge base, which can be updated or enriched according to the identified features of the current curves on the recording charts, and a condition monitoring and failure pattern recognition method, which is called ＂pick-up method of feature of the recording chart＂, and can be correctly applied in most cases. It has been shown that this expert system can effectively improve the accuracy and efficiency of failure diagnosis and working condition monitoring of ESPs.展开更多
基金financial support of the National Natural Science Foundation of China (21875185)。
文摘Geminal dinitropropyl ester plasticizers(DNPEPs) possess excellent energetic performances which provide good potentials as insensitive plasticizer. In this study, we design and synthesize DNPEPs with different alkane chain parts, and systematically investigate their structure-property relationships.Results show that DNPEPs have impact sensitivities all higher than 25.2 J, thermal decomposition temperatures all higher than 254 ℃, and glass transition temperatures(T_(g)) lower than-90 ℃.Furthermore, the effects of DNPEPs as plasticizer are studied on hydroxyl terminated polybutadiene(HTPB) in detail, including the viscosity, glass transition temperatures and others. It is noteworthy that 2,2-dinitropropyl nonanoate(DNPNc) among these DNPEPs exhibits the most expected simultaneous tuning effects on both viscosity and T_(g) of HTPB systems, providing favorable potentials to replace the conventional plastizers as dioctyl sebacate(DOS) in the HTPB based propellants and explosives.
文摘为了研究液压活塞压缩机压缩气体的动态压缩过程,探究压缩机结构参数与压缩机压缩性能的关系,以撬装式井口天然气回收处理系统的液压活塞式压缩机二级缸为研究对象,基于液压活塞式压缩机二级缸工作原理,将仿真过程划分为3个阶段分步模拟,借助Fluent软件,结合动网格和UDF(user defined functions)编译进行仿真分析,明确了二级缸内天然气的动态压缩过程,并将活塞运动作为压缩机压缩性能的评判指标,得到了二级缸结构参数对压缩机压缩性能的影响。研究表明:工作行程和下气缸出口分布与压缩性能关系不大,而下气缸出口大小的增大对压缩性能有较大提升,范围内最大增幅47.6%。相关研究为液压活塞式压缩机的优化与设计提供一定的参考。
基金supported by the National Natural Science Foundation of China(No.51972162)the Fundamental Research Funds for the Central Universities(No.2024300440).
文摘Lowering the synthesis temperature of boron nitride nanotubes(BNNTs)is crucial for their development.The primary reason for adopting a high temperature is to enable the effective activation of highmelting-point solid boron.In this study,we developed a novel approach for efficiently activating boron by introducing alkali metal compounds into the conventional MgO–B system.This approach can be adopted to form various low-melting-point AM–Mg–B–O growth systems.These growth systems have improved catalytic capability and reactivity even under low-temperature conditions,facilitating the synthesis of BNNTs at temperatures as low as 850℃.In addition,molecular dynamics simulations based on density functional theory theoretically demonstrate that the systems maintain a liquid state at low temperatures and interact with N atoms to form BN chains.These findings offer novel insights into the design of boron activation and are expected to facilitate research on the low-temperature synthesis of BNNTs.
文摘BACKGROUND Due to frequent and high-risk sports activities,the elbow joint is susceptible to injury,especially to cartilage tissue,which can cause pain,limited movement and even loss of joint function.AIM To evaluate magnetic resonance imaging(MRI)multisequence imaging for improving the diagnostic accuracy of adult elbow cartilage injury.METHODS A total of 60 patients diagnosed with elbow cartilage injury in our hospital from January 2020 to December 2021 were enrolled in this retrospective study.We analyzed the accuracy of conventional MRI sequences(T1-weighted imaging,T2-weighted imaging,proton density weighted imaging,and T2 star weighted image)and Three-Dimensional Coronary Imaging by Spiral Scanning(3D-CISS)in the diagnosis of elbow cartilage injury.Arthroscopy was used as the gold standard to evaluate the diagnostic effect of single and combination sequences in different injury degrees and the consistency with arthroscopy.RESULTS The diagnostic accuracy of 3D-CISS sequence was 89.34%±4.98%,the sensitivity was 90%,and the specificity was 88.33%,which showed the best performance among all sequences(P<0.05).The combined application of the whole sequence had the highest accuracy in all sequence combinations,the accuracy of mild injury was 91.30%,the accuracy of moderate injury was 96.15%,and the accuracy of severe injury was 93.33%(P<0.05).Compared with arthroscopy,the combination of all MRI sequences had the highest consistency of 91.67%,and the kappa value reached 0.890(P<0.001).CONCLUSION Combination of 3D-CISS and each sequence had significant advantages in improving MRI diagnostic accuracy of elbow cartilage injuries in adults.Multisequence MRI is recommended to ensure the best diagnosis and treatment.
文摘During the oil production, in order to monitor the working conditions of an electrical submersible pump （ESP）,an electrical current recorder is used to monitor the electric motor current of an ESP. The recorder charts indicate various working conditions of the ESP. Subtle malfunctions or abnormal problems of the ESP can be detected and further analyzed from various features of these current curves on the recording charts. Presently, these current charts are manually read and analyzed in oil fields. In this paper, a diagnosis expert system is presented for automatically analyzing these current recording charts and identifying the working condition of the ESP. This expert system includes an open knowledge base, which can be updated or enriched according to the identified features of the current curves on the recording charts, and a condition monitoring and failure pattern recognition method, which is called ＂pick-up method of feature of the recording chart＂, and can be correctly applied in most cases. It has been shown that this expert system can effectively improve the accuracy and efficiency of failure diagnosis and working condition monitoring of ESPs.
