为降低六硝基六氮杂异伍兹烷(CL-20)的感度,通过溶剂-非溶剂法制备了CL-20和1,1′-二羟基-5,5′-联四唑二羟胺盐(TKX-50)共晶炸药;通过Materials Studio 5.0软件分析了CL-20和TKX-50分子的表面静电势,并预测了共晶分子间可能的非共价键...为降低六硝基六氮杂异伍兹烷(CL-20)的感度,通过溶剂-非溶剂法制备了CL-20和1,1′-二羟基-5,5′-联四唑二羟胺盐(TKX-50)共晶炸药;通过Materials Studio 5.0软件分析了CL-20和TKX-50分子的表面静电势,并预测了共晶分子间可能的非共价键作用;采用扫描电镜(SEM)、X射线衍射(XRD)、红外(IR)和拉曼光谱(Raman)对其形貌和结构进行了表征;采用DSC测试了其热性能,并测试了其撞击感度,预测了其爆轰性能。结果表明,制备的CL-20/TKX-50共晶呈扁平的片状形貌;XRD、IR和Raman谱图中出现峰的生成、消失、偏移和强度的改变,证明有新的晶格结构形成;升温速率8℃/min下,CL-20/TKX-50共晶的主要热分解峰温为222.8℃,与CL-20、TKX-50的热分解峰温240.3、234.9℃相比,分别提前了17.5℃和12.1℃,明显区别于具有两个放热过程的CL-20/TKX-50混合物的热分解行为;CL-20/TKX-50共晶炸药的感度显著低于原料CL-20,同时也优于β-HMX,说明其具有良好的安全性能;CL-20/TKX-50共晶的预测爆速和爆压分别为9264m/s和43.8GPa,较CL-20均略微下降,但和β-HMX相比,爆轰性能明显提高。表面静电势能和建模分析均表明,CL-20中—NO2的O与TKX-50中—NH+3的H之间易于形成氢键。展开更多
The loss of metal in a pipe due to corrosion usually results in localized thinned areas with various depths and an irregular shape on its surface. In this paper, a number of numerical models of pipes with different si...The loss of metal in a pipe due to corrosion usually results in localized thinned areas with various depths and an irregular shape on its surface. In this paper, a number of numerical models of pipes with different size defects are established. The limit loads of these pipes are researched using the nonlinear finite element method. The effect of defect parameters of the local wall-thinning pipes on the limit load is discussed. The results show that limit loads decrease obviously when the depths and lengths of the defect increase. However, when the defect length reaches a certain value, the effect of defect length on limit loads is not significant. These results are compared with the results of the method of API 579. When the defect length is adequately small, the results of FEM are in good agreement with the ones of APl 579, but when the defect depth and length is adequately large, the API 579 is not suitable.展开更多
In this paper, using Hamilton principle, the control equation of fluid-structure interaction vibration of a pipe conveying fluid under simple harmonic excitation was established and a novel method, Galerkin-Modality＇...In this paper, using Hamilton principle, the control equation of fluid-structure interaction vibration of a pipe conveying fluid under simple harmonic excitation was established and a novel method, Galerkin-Modality＇ s method was proposed to solve this equation. The influence of the damp, the flow velocity, the pressure and the length of the pipe supported by simple supports on the piping＇ s first two natural frequencies was discussed. The criti- cal pressure and the critical length of the pipe were obtained. The influence of the flow velocity and pressure on the piping＇s maximal relative displacements were analyzed.展开更多
文摘为降低六硝基六氮杂异伍兹烷(CL-20)的感度,通过溶剂-非溶剂法制备了CL-20和1,1′-二羟基-5,5′-联四唑二羟胺盐(TKX-50)共晶炸药;通过Materials Studio 5.0软件分析了CL-20和TKX-50分子的表面静电势,并预测了共晶分子间可能的非共价键作用;采用扫描电镜(SEM)、X射线衍射(XRD)、红外(IR)和拉曼光谱(Raman)对其形貌和结构进行了表征;采用DSC测试了其热性能,并测试了其撞击感度,预测了其爆轰性能。结果表明,制备的CL-20/TKX-50共晶呈扁平的片状形貌;XRD、IR和Raman谱图中出现峰的生成、消失、偏移和强度的改变,证明有新的晶格结构形成;升温速率8℃/min下,CL-20/TKX-50共晶的主要热分解峰温为222.8℃,与CL-20、TKX-50的热分解峰温240.3、234.9℃相比,分别提前了17.5℃和12.1℃,明显区别于具有两个放热过程的CL-20/TKX-50混合物的热分解行为;CL-20/TKX-50共晶炸药的感度显著低于原料CL-20,同时也优于β-HMX,说明其具有良好的安全性能;CL-20/TKX-50共晶的预测爆速和爆压分别为9264m/s和43.8GPa,较CL-20均略微下降,但和β-HMX相比,爆轰性能明显提高。表面静电势能和建模分析均表明,CL-20中—NO2的O与TKX-50中—NH+3的H之间易于形成氢键。
基金supported by the National High Technol-ogy Research and Development Program of China(2007AA04Z404)Natural Science Basic Research Plan in Shaanxi Province of China (SJ08A17)the Technical Innovation Foundation of NWPU(2008KJ02019)
文摘The loss of metal in a pipe due to corrosion usually results in localized thinned areas with various depths and an irregular shape on its surface. In this paper, a number of numerical models of pipes with different size defects are established. The limit loads of these pipes are researched using the nonlinear finite element method. The effect of defect parameters of the local wall-thinning pipes on the limit load is discussed. The results show that limit loads decrease obviously when the depths and lengths of the defect increase. However, when the defect length reaches a certain value, the effect of defect length on limit loads is not significant. These results are compared with the results of the method of API 579. When the defect length is adequately small, the results of FEM are in good agreement with the ones of APl 579, but when the defect depth and length is adequately large, the API 579 is not suitable.
基金supported by National High Technology Research and Development Program of China Under Grant No.2007AA04Z404Natural Science Basic Research Plan in Shaanxi Province of China Under Grant No.SJ08A17+1 种基金Technical Innovation Foundation of Northwestern Polytechnical University(NWPU) Under Grant No.2008KJ02019the "111" Project of NWPU Under Grant No.B07050
文摘In this paper, using Hamilton principle, the control equation of fluid-structure interaction vibration of a pipe conveying fluid under simple harmonic excitation was established and a novel method, Galerkin-Modality＇ s method was proposed to solve this equation. The influence of the damp, the flow velocity, the pressure and the length of the pipe supported by simple supports on the piping＇ s first two natural frequencies was discussed. The criti- cal pressure and the critical length of the pipe were obtained. The influence of the flow velocity and pressure on the piping＇s maximal relative displacements were analyzed.
