以化学竞赛思维引领的基础化学实验教学改革

以化学竞赛思维为引领,对两个基础化学实验案例进行教学改革,拟解决教学改革中遇到的深层次问题。教学改革结果表明,相关课程教学目标与专业培养目标能够高度统一;不同任课教师能在同一教学主题中高度统一思想,从而进行深入交流;通过竞赛思维培养方式,可极大地激发学生学习动力,提高他们的学习效率。

Effect of Soil on the Growth and Quality of Pepper during Different Durations of Continuous Planting

With the greenhouse soil that had been planted with cucumber as the control,the greenhouse soil that had been planted with pepper for 3,7,10 and 15 consecutive years was collected,and the effects of continuous cropping on plant height,stem diameter,leaf area,yield,photosynthetic pigment content and fruit quality of pepper were investigated by pot experiment. The results showed that with the extension of continuous cropping duration,the plant height,stem diameter and yield of pepper decreased significantly compared with the control; and the mass fraction of photosynthetic pigments declined,and the mass fractions of chlorophyll a and total chlorophyll were significantly lower than those of the control. Under the condition of continuous cropping,the fruit quality of pepper decreased significantly,and the mass fractions of soluble solids and soluble protein were significantly lower than those of the control.

Geochronology,Geochemistry,and Sr-Nd-Hf Isotopes of the Diorite Porphyrites from the Weining Beishan Area,Ningxia Hui Autonomous Region:Constraints on Their Source and Tectonic Implications

The Weining Beishan area of Ningxia Hui Autonomous Region is located at on the western edge of the Helanshan tectonic belt,which is a tectonic joint among Alxa Block,Ordos Block,and North Qilian orogenic belt.However,the tectonic evolution of this area remains unclear due to the lack of magmatic information.This paper conducted researches on geochronology,geochemistry,and Sr-Nd-Hf isotopes of the diorite porphyrites exposed in the Weining Beishan area.The zircon U-Pb dating yields two ages of 145.0±1.1 and 146.2±1.5 Ma,and the whole-rock geochemical data indicate that the diorite porphyrites are metaluminous to weakly peraluminous and high-K calc-alkaline series.The characteristics of highly initial^(87)Sr/^(86)Sr ratios(0.70816 to 0.71047),negativeε_(Nd)(t)(−8.9 to−8.4),and negativeε_(Hf)(t)(−13.8 to−21.2)indicate that the diorite porphyrites originated from partial melting of the middle-lower ancient crust related to the North China Craton.Combined with the regional geology,we suggested that partial melting was triggered by a tectonic activity of deep faults cutting through the crust under the regional stress transformation from compressing to extension during the Late Jurassic–Early Cretaceous,which is probably related to the westward subduction of the Paleo-Pacific Plate.

Fully Decoupled Branch Energy Balancing Control Method for Modular Multilevel Matrix Converter Based on Sequence Circulating Components

The modular multilevel matrix converter(M3C)is a potential frequency converter for low-frequency AC transmission.However,capacitor voltage control of high-voltage and largecapacity M3C is more difficult,especially for voltage balancing between branches.To solve this problem,this paper defines sequence circulating components and theoretically analyzes the influence mechanism of different sequence circulating components on branch capacitor voltage.A fully decoupled branch energy balancing control method based on four groups of sequence circulating components is proposed.This method can control capacitor voltages of nine branches in horizontal,vertical and diagonal directions.Considering influences of both circulating current and voltage,a cross decoupled control is designed to improve control precision.Simulation results are taken from a low-frequency transmission system based on PSCAD/EMTDC,and effectiveness and precision of the proposed branch energy balancing control method are verified in the case of nonuniform parameters and an unbalanced power system.

Simplified Cluster Voltage Balancing Control Based on Zero-sequence Voltage Injection for Star-connected Cascaded H-bridge STATCOM

The cluster DC voltage balancing control adopting zero-sequence voltage injection is appropriate for the starconnected cascaded H-bridge STATCOM because no zerosequence currents are generated in the three-phase three-wire system.However,as the zero-sequence voltage is expressed in trigonometric form,traditional control methods involve many complicated operations,such as the square-root,trigonometric operations,and inverse tangent operations.To simplify cluster voltage balancing control,this paper converts the zero-sequence voltage to the dq frame in a DC representation by introducing a virtually orthogonal variable,and the DC components of the zero-sequence voltage in the dq frame are regulated linearly by proportional integral regulators,rather than being calculated from uneven active powers in traditional controls.This removes all complicated operations.Finally,this paper presents simulation and experimental results for a 400 V±7.5 kvar star-connected STATCOM,in balanced and unbalanced scenarios,thereby verifying the effectiveness of the proposed control.

A Three-phase Integrated Power Electronic Transformer with the Capability of DC Fault Clearance

This paper presents a three-phase integrated power electronic transformer(PET)topology with the capability of DC fault clearance based on the investigation of PET topology.The proposed PET has three ports of high-voltage AC,high-voltage DC and low-voltage DC,which can achieve the flexible access of distributed energy resources・The power unit of the PET adopts a three-phase integrated topology,and the single-phase fluctuating power in the DC-link capacitor is reduced by a 4-port DC/DC converter,thereby reducing the capacitance of the DC-link capacitor;Meanwhile,the power unit uses the clamp double sub-module(CDSM)to allow for self-clearing of the short-circuit fault on the high-voltage DC side.Finally,this paper verifies the proposed PET through an EMT simulation and experimental prototype.

A series of novel Zn(Ⅱ) and Mn(Ⅱ) metal-organic frameworks constructed by 2,4-bis-oxyacetate-benzoic acid: syntheses, structures and photoluminescence

A new carboxylic acid ligand, 2,4-bis-oxyacetate-benzoic acid(H3BOABA), was designed and introduced to construct novel metal-organic framework materials. [Zn Na(BOABA)(phen)(H2O)]·H2O(1), Zn Na(BOABA)(2), Mn3(BOABA)2(phen)2(3), [Mn2(BOABA)(OH)]·(H2O)2(4)(CCDC: 885138, 885137, 894225, 883094) were hydrothermally synthesized and characterized by elemental analysis, IR spectra and thermal gravimetric analyses. Crystal structures of the complexes were determined by single crystal X-ray diffraction method. Complex 1 is a one dimensional double edges non-interpenetrated framework decorated by the phen ligands on the surface. Complex 2 is an unique three dimensional open framework, consisting of Zn(II) and Na(I). Complex 3 is an unique double edges one dimensional MOF containing a [Mn3(BOABA)2(phen)2]n non-interpenetrated structure. Complex 4 is a two dimensional plane structure containing two Mn atoms in the same coordination environment. The interaction between four complexes and DNA were studied by Et Br fluorescence probe. Meanwhile, photoluminescence studies revealed that these four complexes display strong fluorescent emission bands in the solid state at room temperature.