Hypo-peritectic steels are widely used in various industrial fields because of their high strength,high toughness,high processability,high weldability,and low material cost.However,surface defects are liable to occur ...Hypo-peritectic steels are widely used in various industrial fields because of their high strength,high toughness,high processability,high weldability,and low material cost.However,surface defects are liable to occur during continuous casting,which includes depression,longitudinal cracks,deep oscillation marks,and severe level fluctuation with slag entrapment.The high-efficiency production of hypo-peritectic steels by continuous casting is still a great challenge due to the limited understanding of the mechanism of peritectic solidification.This work reviews the definition and classification of hypo-peritectic steels and introduces the formation tendency of common surface defects related to peritectic solidification.New achievements in the mechanism of peritectic reaction and transformation have been listed.Finally,countermeasures to avoiding surface defects of hypo-peritectic steels duiring continuous casting are summarized.Enlightening certain points in the continuous casting of hypo-peritectic steels and the development of new techniques to overcome the present problems will be a great aid to researchers.展开更多
Ensuring food safety is paramount worldwide.Developing effective detection methods to ensure food safety can be challenging owing to trace hazards,long detection time,and resource-poor sites,in addition to the matrix ...Ensuring food safety is paramount worldwide.Developing effective detection methods to ensure food safety can be challenging owing to trace hazards,long detection time,and resource-poor sites,in addition to the matrix effects of food.Personal glucose meter(PGM),a classic point-of-care testing device,possesses unique application advantages,demonstrating promise in food safety.Currently,many studies have used PGM-based biosensors and signal amplification technologies to achieve sensitive and specific detection of food hazards.Signal amplification technologies have the potential to greatly improve the analytical performance and integration of PGMs with biosensors,which is crucial for solving the challenges associated with the use of PGMs for food safety analysis.This review introduces the basic detection principle of a PGM-based sensing strategy,which consists of three key factors:target recognition,signal transduction,and signal output.Representative studies of existing PGM-based sensing strategies combined with various signal amplification technologies(nanomaterial-loaded multienzyme labeling,nucleic acid reaction,DNAzyme catalysis,responsive nanomaterial encapsulation,and others)in the field of food safety detection are reviewed.Future perspectives and potential opportunities and challenges associated with PGMs in the field of food safety are discussed.Despite the need for complex sample preparation and the lack of standardization in the field,using PGMs in combination with signal amplification technology shows promise as a rapid and cost-effective method for food safety hazard analysis.展开更多
The North Qaidam orogenic belt(NQOB) is generally considered to be an early Paleozoic ultrahigh pressure metamorphic belt,but increasing reports of the Neoproterozoic magmatic and metamorphic events indicate that the ...The North Qaidam orogenic belt(NQOB) is generally considered to be an early Paleozoic ultrahigh pressure metamorphic belt,but increasing reports of the Neoproterozoic magmatic and metamorphic events indicate that the NQOB probably also experienced the assembly of the Rodinia.However,the Neoproterozoic evolution of the NQOB is not well constrained due to the sparse records and ambiguous nature of the Neoproterozoic metamorphism.In order to reveal the multi-orogenic history of the NQOB,an integrated study of petrology,phase equilibrium modelling and geochronology was conducted on an epidote eclogite and host garnet mica schist from the Yuka–Luofengpo terrane.New zircon and monazite U–Pb ages show that the protolith of the garnet mica schist was deposited during 994–920 Ma and experienced Neoproterozoic(920–915 Ma) and early Paleozoic(451–447 Ma) polyphase metamorphism together with the enclosed eclogite.Relic omphacite inclusions were first identified in garnet and early Paleozoic zircon domains from the garnet mica schist,which provide solid evidence for the early Paleozoic eclogite facies metamorphism of the mica schist.Similar early Paleozoic peak P–T conditions of >27.4 kbar/613–670 ℃ and 30.2–30.8 kbar/646–655 ℃ were obtained for the garnet mica schist and enclosed eclogite,respectively,indicating that eclogites and their host paragneisses in this region underwent continental deep subduction as a coherent metamorphic terrane in early Paleozoic.The peak P–T conditions of the Neoproterozoic metamorphism were roughly constrained at 7.7–12.0 kbar and 634–680 ℃ for the garnet mica schist,based on stability field of mineral inclusions in Neoproterozoic zircons domains in P–T pseudosection,the relic garnet core composition and Ti-in-zircon thermometer.The high thermal gradients(16–37 ℃/km) defined by presently our and previously reported P–T conditions indicate that the Neoproterozoic metamorphism likely occurred in continental collision setting at >945–890 Ma.Since the Grenvillian syn-orogenic granitic magmatism and metamorphism(ca.1.0–0.9 Ga) in the NQOB are much younger than the Grenvillian orogeny in the central part of Rodinia,the Qaidam Block was probably located at the north margin of Rodinia in Neoproterozoic.展开更多
A monolithic column-based mass spectrometry(MS)analysis kit was prepared for whole blood analysis with MS.The kit is disposable and can be used for purification,storage,transportation and direct analysis of whole bloo...A monolithic column-based mass spectrometry(MS)analysis kit was prepared for whole blood analysis with MS.The kit is disposable and can be used for purification,storage,transportation and direct analysis of whole blood.The kit mainly consists of a capillary for quantitative microsampling,a cation exchange monolithic column for purification and storage,and a syringe for loading sample.This kit is very friendly to various users that one can easily siphon the blood in the kit followed by rapid clean-up.We established a quantitative method using the kit with a limit detection as low as 0.33 nmol/L,and achieved more than five orders of magnitude enhancement in sensitivity compared to direct nanoelectrospray ionization MS analysis.The column can avoid analyte exposure to environment,which helps the storage of the sample for laboratory analysis.The relative standard deviation of immediate blood analysis and storage blood analysis within 10 d was less than 10%.This method has been successfully applied to the quantitative analysis of procainamide hydrochloride in 2μL rat blood.These results indicate that this disposable kit does have the potential to achieve highly sensitive quantitative MS analysis in biological samples,which is expected to become a cost-effective and powerful tool for in vitro diagnostics.展开更多
Wild soybean is a typical short-day plant that begins flowering when the days are shorter than its critical photoperiod, Soybean was domesticated in the temperate region of East Asia at the relatively high latitude, a...Wild soybean is a typical short-day plant that begins flowering when the days are shorter than its critical photoperiod, Soybean was domesticated in the temperate region of East Asia at the relatively high latitude, and the breeding and release of soybean varieties have historically centered on mid- and high-latitude temperate regions. Low-latitude areas with tropical and sub- tropical climates were previously considered unsuitable for soy- bean production because most temperate soybean varieties ex- hibited precocious flowering and early maturity and suffered from low yields.展开更多
基金financially supported by the Fundamental Research Funds for the Central Universities(No.FRF-TP-19-017A3)the National Natural Science Foundation of China(No.51874026)。
文摘Hypo-peritectic steels are widely used in various industrial fields because of their high strength,high toughness,high processability,high weldability,and low material cost.However,surface defects are liable to occur during continuous casting,which includes depression,longitudinal cracks,deep oscillation marks,and severe level fluctuation with slag entrapment.The high-efficiency production of hypo-peritectic steels by continuous casting is still a great challenge due to the limited understanding of the mechanism of peritectic solidification.This work reviews the definition and classification of hypo-peritectic steels and introduces the formation tendency of common surface defects related to peritectic solidification.New achievements in the mechanism of peritectic reaction and transformation have been listed.Finally,countermeasures to avoiding surface defects of hypo-peritectic steels duiring continuous casting are summarized.Enlightening certain points in the continuous casting of hypo-peritectic steels and the development of new techniques to overcome the present problems will be a great aid to researchers.
基金supported by the Natural Science Foundation of Shandong Province(Grant No.:ZR2020QC250)China Agriculture Research System(Grant No.:CARS-38)+1 种基金Modern Agricultural Technology Industry System of Shandong Province(Grant No.:SDAIT10-10)Key Technology Research and Development Program of Shandong(Grant Nos.:2021CXGC010809 and 2021TZXD012).
文摘Ensuring food safety is paramount worldwide.Developing effective detection methods to ensure food safety can be challenging owing to trace hazards,long detection time,and resource-poor sites,in addition to the matrix effects of food.Personal glucose meter(PGM),a classic point-of-care testing device,possesses unique application advantages,demonstrating promise in food safety.Currently,many studies have used PGM-based biosensors and signal amplification technologies to achieve sensitive and specific detection of food hazards.Signal amplification technologies have the potential to greatly improve the analytical performance and integration of PGMs with biosensors,which is crucial for solving the challenges associated with the use of PGMs for food safety analysis.This review introduces the basic detection principle of a PGM-based sensing strategy,which consists of three key factors:target recognition,signal transduction,and signal output.Representative studies of existing PGM-based sensing strategies combined with various signal amplification technologies(nanomaterial-loaded multienzyme labeling,nucleic acid reaction,DNAzyme catalysis,responsive nanomaterial encapsulation,and others)in the field of food safety detection are reviewed.Future perspectives and potential opportunities and challenges associated with PGMs in the field of food safety are discussed.Despite the need for complex sample preparation and the lack of standardization in the field,using PGMs in combination with signal amplification technology shows promise as a rapid and cost-effective method for food safety hazard analysis.
基金Final support for this study was jointly provided by the National Natural Science Foundation of China (Grant Nos.41802056,41972058,42030307)the China Postdoctoral Science Foundation (Grant2018M633554)+2 种基金the MOST Special Fund from the State Key Laboratory of Continental Dynamics (Grant 201210133)Young Talent fund of University Association for Science and Technology in Shaanxi,China (Grant20200703)China Geological Survey (Grant DD20190376).
文摘The North Qaidam orogenic belt(NQOB) is generally considered to be an early Paleozoic ultrahigh pressure metamorphic belt,but increasing reports of the Neoproterozoic magmatic and metamorphic events indicate that the NQOB probably also experienced the assembly of the Rodinia.However,the Neoproterozoic evolution of the NQOB is not well constrained due to the sparse records and ambiguous nature of the Neoproterozoic metamorphism.In order to reveal the multi-orogenic history of the NQOB,an integrated study of petrology,phase equilibrium modelling and geochronology was conducted on an epidote eclogite and host garnet mica schist from the Yuka–Luofengpo terrane.New zircon and monazite U–Pb ages show that the protolith of the garnet mica schist was deposited during 994–920 Ma and experienced Neoproterozoic(920–915 Ma) and early Paleozoic(451–447 Ma) polyphase metamorphism together with the enclosed eclogite.Relic omphacite inclusions were first identified in garnet and early Paleozoic zircon domains from the garnet mica schist,which provide solid evidence for the early Paleozoic eclogite facies metamorphism of the mica schist.Similar early Paleozoic peak P–T conditions of >27.4 kbar/613–670 ℃ and 30.2–30.8 kbar/646–655 ℃ were obtained for the garnet mica schist and enclosed eclogite,respectively,indicating that eclogites and their host paragneisses in this region underwent continental deep subduction as a coherent metamorphic terrane in early Paleozoic.The peak P–T conditions of the Neoproterozoic metamorphism were roughly constrained at 7.7–12.0 kbar and 634–680 ℃ for the garnet mica schist,based on stability field of mineral inclusions in Neoproterozoic zircons domains in P–T pseudosection,the relic garnet core composition and Ti-in-zircon thermometer.The high thermal gradients(16–37 ℃/km) defined by presently our and previously reported P–T conditions indicate that the Neoproterozoic metamorphism likely occurred in continental collision setting at >945–890 Ma.Since the Grenvillian syn-orogenic granitic magmatism and metamorphism(ca.1.0–0.9 Ga) in the NQOB are much younger than the Grenvillian orogeny in the central part of Rodinia,the Qaidam Block was probably located at the north margin of Rodinia in Neoproterozoic.
基金financially supported by the National Natural Science Foundation of China(No.22104112)the startup foundation of Wuhan University(No.600460076).
文摘A monolithic column-based mass spectrometry(MS)analysis kit was prepared for whole blood analysis with MS.The kit is disposable and can be used for purification,storage,transportation and direct analysis of whole blood.The kit mainly consists of a capillary for quantitative microsampling,a cation exchange monolithic column for purification and storage,and a syringe for loading sample.This kit is very friendly to various users that one can easily siphon the blood in the kit followed by rapid clean-up.We established a quantitative method using the kit with a limit detection as low as 0.33 nmol/L,and achieved more than five orders of magnitude enhancement in sensitivity compared to direct nanoelectrospray ionization MS analysis.The column can avoid analyte exposure to environment,which helps the storage of the sample for laboratory analysis.The relative standard deviation of immediate blood analysis and storage blood analysis within 10 d was less than 10%.This method has been successfully applied to the quantitative analysis of procainamide hydrochloride in 2μL rat blood.These results indicate that this disposable kit does have the potential to achieve highly sensitive quantitative MS analysis in biological samples,which is expected to become a cost-effective and powerful tool for in vitro diagnostics.
文摘Wild soybean is a typical short-day plant that begins flowering when the days are shorter than its critical photoperiod, Soybean was domesticated in the temperate region of East Asia at the relatively high latitude, and the breeding and release of soybean varieties have historically centered on mid- and high-latitude temperate regions. Low-latitude areas with tropical and sub- tropical climates were previously considered unsuitable for soy- bean production because most temperate soybean varieties ex- hibited precocious flowering and early maturity and suffered from low yields.