MnO_(x)-CeO_(2) catalysts are developed by hydrolysis driving redox method using acetate precursor(3 Mn1 Ce-Ac) and nitrate precursor(3 Mn1 Ce-N) for the selective catalytic reduction(SCR) of NO_(x) by NH_(3).A counte...MnO_(x)-CeO_(2) catalysts are developed by hydrolysis driving redox method using acetate precursor(3 Mn1 Ce-Ac) and nitrate precursor(3 Mn1 Ce-N) for the selective catalytic reduction(SCR) of NO_(x) by NH_(3).A counterpart sample(Cop-3 Mn1 Ce) was prepared by the NH_(3)·H_(2) O co-precipitation method for comparison purpose.Combining the results of physicochemical properties characterization and performance test,we find that the 3 Mn1 Ce-Ac catalyst with some nanorod structures is highly active for the deNOx process.The SCR activity of the 3 Mn1 Ce-Ac catalyst is more admirable than the 3 Mn1 Ce-N and the Cop-3 Mn1 Ce catalysts due to plentiful Lewis acid sites,excellent low-temperature reducibility,and superior surface area resulted from O_(2) generation during the pre paration procedure.The 3 Mn1 Ce-Ac still exhibits the greatest performance for the deNO_(x )process when gaseous acetone is in the SCR feed gas.The NOx conversion and N2 selectivity over the 3 Mn1 Ce-Ac are both improved by gaseous acetone above150℃ due to the inhibition of SCR undesired side reactions(NSCR & C-O reactions) and "slow-SCR" process.展开更多
Consider the precision attitude regulation with vibration suppression for an uncertain and disturbed flexible spacecraft.The disturbance at issue is typically any finite superposition of sinusoidal signals with unknow...Consider the precision attitude regulation with vibration suppression for an uncertain and disturbed flexible spacecraft.The disturbance at issue is typically any finite superposition of sinusoidal signals with unknown frequencies and step signals of unknown amplitudes.First we show that the conventional mathematical model for flexible spacecrafts is transformable to a multi-input multi-output(MIMO)strict-feedback nonlinear normal form.Particularly it is strongly minimum-phase and has a well-defined uniform vector relative degree.Then it enables us to develop an adaptive internal model-based controller in the framework of adaptive output regulation to solve the problem.It is proved that asymptotic stability can be guaranteed for the attitude regulation task and the vibration of flexible appendages vanishes asymptotically.Hence,the present study explores a new idea for control of flexible spacecraft in virtue of its system structures.展开更多
基金supported by the Key Laboratory of Water and Air Pollution Control of Guangdong province,China (No.2017A030314001)the National Key Research and Development Plan (No.2019YFC0214303)+1 种基金Central Public-Interest Scientific Institution Basal Research Fund (No.PM-zx703-202002-015)the National Natural Science Foundation of China (No.22076224)。
文摘MnO_(x)-CeO_(2) catalysts are developed by hydrolysis driving redox method using acetate precursor(3 Mn1 Ce-Ac) and nitrate precursor(3 Mn1 Ce-N) for the selective catalytic reduction(SCR) of NO_(x) by NH_(3).A counterpart sample(Cop-3 Mn1 Ce) was prepared by the NH_(3)·H_(2) O co-precipitation method for comparison purpose.Combining the results of physicochemical properties characterization and performance test,we find that the 3 Mn1 Ce-Ac catalyst with some nanorod structures is highly active for the deNOx process.The SCR activity of the 3 Mn1 Ce-Ac catalyst is more admirable than the 3 Mn1 Ce-N and the Cop-3 Mn1 Ce catalysts due to plentiful Lewis acid sites,excellent low-temperature reducibility,and superior surface area resulted from O_(2) generation during the pre paration procedure.The 3 Mn1 Ce-Ac still exhibits the greatest performance for the deNO_(x )process when gaseous acetone is in the SCR feed gas.The NOx conversion and N2 selectivity over the 3 Mn1 Ce-Ac are both improved by gaseous acetone above150℃ due to the inhibition of SCR undesired side reactions(NSCR & C-O reactions) and "slow-SCR" process.
基金This work was supported by the National Natural Science Foundation of China(Nos.61873250,62073168,61871221).
文摘Consider the precision attitude regulation with vibration suppression for an uncertain and disturbed flexible spacecraft.The disturbance at issue is typically any finite superposition of sinusoidal signals with unknown frequencies and step signals of unknown amplitudes.First we show that the conventional mathematical model for flexible spacecrafts is transformable to a multi-input multi-output(MIMO)strict-feedback nonlinear normal form.Particularly it is strongly minimum-phase and has a well-defined uniform vector relative degree.Then it enables us to develop an adaptive internal model-based controller in the framework of adaptive output regulation to solve the problem.It is proved that asymptotic stability can be guaranteed for the attitude regulation task and the vibration of flexible appendages vanishes asymptotically.Hence,the present study explores a new idea for control of flexible spacecraft in virtue of its system structures.
