The separator is an essential component of sodium-ion batteries(SIBs)to determine their electrochemical performances.However,the separator with high mechanical strength,good electrolyte wettability and excellent elect...The separator is an essential component of sodium-ion batteries(SIBs)to determine their electrochemical performances.However,the separator with high mechanical strength,good electrolyte wettability and excellent electrochemical performance remains an open challenge.Herein,a new separator consisting of amphoteric nanofibers with abundant functional groups was fabricated through supramolecular assembly of natural polymers for SIB.The uniform nanoporous structure,remarkable mechanical properties and abundant functional groups(e.g.-COOH,-NH_(2)and-OH)endow the separator with lower dissolution activation energy and higher ion migration numbers.These metrics enable the separator to lower the barrier for desolvation of Na^(+),accelerate the migration of Na^(+),and generate more stable solid electrolyte interphase(SEI)and cathode electrolyte interphase(CEI).The battery assembled with the amphoteric nanofiber separator shows higher specific capacity and better stability than that assembled with glass fiber(GF)separator.展开更多
为评估匹配不同动力电池的纯电动汽车(Battery Electric Vehicle,BEV)全生命周期环境影响,以某款已上市纯电动汽车为研究对象,分别匹配4款常用动力电池,基于GaBi软件搭建生命周期评价模型,对其进行2021年与2030年全生命周期能源消耗与...为评估匹配不同动力电池的纯电动汽车(Battery Electric Vehicle,BEV)全生命周期环境影响,以某款已上市纯电动汽车为研究对象,分别匹配4款常用动力电池,基于GaBi软件搭建生命周期评价模型,对其进行2021年与2030年全生命周期能源消耗与环境排放研究,并选取关键参数因子进行敏感性分析。研究表明,匹配钛酸锂电池的纯电动汽车化石能源消耗(ADP(f))与全球变暖潜值(Global Warming Potential,GWP)均为最高;纯电动汽车在运行使用阶段与生产制造阶段具有较高的能耗与排放;到2030年,纯电动汽车全生命周期ADP(f)与GWP将显著降低,同时随着电力结构的优化与动力电池充电效率的提升,匹配不同动力电池的整车ADP(f)与GWP也将随之降低。展开更多
The ecological curriculum system is featured by the subjectivity, systematicness, dynamicness and sustainability. Based on the curriculum theories of pragmatism and humanism, and the experience of universities in Amer...The ecological curriculum system is featured by the subjectivity, systematicness, dynamicness and sustainability. Based on the curriculum theories of pragmatism and humanism, and the experience of universities in America, France and other countries, this paper examines the problems existing in the curriculum in higher education in China. Structural unemployment is caused by the mismatch of the curriculum and the social needs. At the same time, the curriculum fails to cultivate the innovative and entrepreneurial ability of students. Moreover, teacher-student relationship is not as harmonious as expected. Finally, to achieve the goal of curriculum construction, the thesis emphasizes the integrity and coordination of personnel training. Curriculum module design should be diversified and highlight features, to achieve static and dynamic tension interaction of the course content. The reform of teaching methods and means should be student-oriented and eventually form an open curriculum evaluation mechanism.展开更多
Carbon aerogels prepared from renewable nano building blocks are rising-star materials and hold great promise in many fields.However,various defects formed during carbonization at high temperature disfavor the stress ...Carbon aerogels prepared from renewable nano building blocks are rising-star materials and hold great promise in many fields.However,various defects formed during carbonization at high temperature disfavor the stress transfer and thus the fabrication of flexible carbon aerogel from renewable nano building blocks.Herein,a structural defect-reducing strategy is proposed by altering the pyrolysis route of cellulose nanofiber.Inorganic salt that inhibits the generation of tar volatilization during pyrolysis can prevent the formation of various structural defects.Microstructure with fewer defects can reduce stress concentration and remarkably enhance the compressibility of carbon aerogel,thus increasing the maximum stress retention of carbon aerogel.The carbon aerogel also has high stress sensor sensitivity and excellent temperature coefficient of resistance.The structural defect-reducing strategy will pave a new way to fabricate high-strength carbon materials for various fields.展开更多
基金supported by the Outstanding Youth Team Project of Guangdong Natural Science Foundation(2023B1515040013)Guangdong Basic and Applied Basic Research Foundation(2023A1515012215,2023B1515040013,2023A1515012519)+1 种基金State Key Laboratory of Pulp&Paper Engineering(2023C07,2023PY03)Guangdong Col ege Students’Scientific and Technological Innovation(“Climbing Program”Special Fund,Pdjh2022a0026)
文摘The separator is an essential component of sodium-ion batteries(SIBs)to determine their electrochemical performances.However,the separator with high mechanical strength,good electrolyte wettability and excellent electrochemical performance remains an open challenge.Herein,a new separator consisting of amphoteric nanofibers with abundant functional groups was fabricated through supramolecular assembly of natural polymers for SIB.The uniform nanoporous structure,remarkable mechanical properties and abundant functional groups(e.g.-COOH,-NH_(2)and-OH)endow the separator with lower dissolution activation energy and higher ion migration numbers.These metrics enable the separator to lower the barrier for desolvation of Na^(+),accelerate the migration of Na^(+),and generate more stable solid electrolyte interphase(SEI)and cathode electrolyte interphase(CEI).The battery assembled with the amphoteric nanofiber separator shows higher specific capacity and better stability than that assembled with glass fiber(GF)separator.
文摘为评估匹配不同动力电池的纯电动汽车(Battery Electric Vehicle,BEV)全生命周期环境影响,以某款已上市纯电动汽车为研究对象,分别匹配4款常用动力电池,基于GaBi软件搭建生命周期评价模型,对其进行2021年与2030年全生命周期能源消耗与环境排放研究,并选取关键参数因子进行敏感性分析。研究表明,匹配钛酸锂电池的纯电动汽车化石能源消耗(ADP(f))与全球变暖潜值(Global Warming Potential,GWP)均为最高;纯电动汽车在运行使用阶段与生产制造阶段具有较高的能耗与排放;到2030年,纯电动汽车全生命周期ADP(f)与GWP将显著降低,同时随着电力结构的优化与动力电池充电效率的提升,匹配不同动力电池的整车ADP(f)与GWP也将随之降低。
基金supported by the Tianjin Education Research Project (Grant No. HE3053)
文摘The ecological curriculum system is featured by the subjectivity, systematicness, dynamicness and sustainability. Based on the curriculum theories of pragmatism and humanism, and the experience of universities in America, France and other countries, this paper examines the problems existing in the curriculum in higher education in China. Structural unemployment is caused by the mismatch of the curriculum and the social needs. At the same time, the curriculum fails to cultivate the innovative and entrepreneurial ability of students. Moreover, teacher-student relationship is not as harmonious as expected. Finally, to achieve the goal of curriculum construction, the thesis emphasizes the integrity and coordination of personnel training. Curriculum module design should be diversified and highlight features, to achieve static and dynamic tension interaction of the course content. The reform of teaching methods and means should be student-oriented and eventually form an open curriculum evaluation mechanism.
基金the National Natural Science Foundation of China(Nos.32201499,22208069 and 32071714)Guangdong Basic and Applied Basic Research Foundation(No.2021A1515110205)+1 种基金Fundamental Research Funds for the Central Universities(No.2022ZYGXZR019)the State Key Laboratory of Pulp&Paper Engineering(No.2022C01).
文摘Carbon aerogels prepared from renewable nano building blocks are rising-star materials and hold great promise in many fields.However,various defects formed during carbonization at high temperature disfavor the stress transfer and thus the fabrication of flexible carbon aerogel from renewable nano building blocks.Herein,a structural defect-reducing strategy is proposed by altering the pyrolysis route of cellulose nanofiber.Inorganic salt that inhibits the generation of tar volatilization during pyrolysis can prevent the formation of various structural defects.Microstructure with fewer defects can reduce stress concentration and remarkably enhance the compressibility of carbon aerogel,thus increasing the maximum stress retention of carbon aerogel.The carbon aerogel also has high stress sensor sensitivity and excellent temperature coefficient of resistance.The structural defect-reducing strategy will pave a new way to fabricate high-strength carbon materials for various fields.
