The glass system xBi2O3-(30 – x)CdO-10B2O3-20Fe2O3-40P2O5 (0 ≤ x ≤ 30 weight %), has been prepared by the melt quenching technique. The thermal stability of the glasses, their hardness as well as their chemical dur...The glass system xBi2O3-(30 – x)CdO-10B2O3-20Fe2O3-40P2O5 (0 ≤ x ≤ 30 weight %), has been prepared by the melt quenching technique. The thermal stability of the glasses, their hardness as well as their chemical durability have been investigated before and after subjecting to different gamma ray doses to insure the validity of this glass system for application to the problem of the permanent disposal for nuclear wastes. The results indicated that the glasses have well to excellent chemical durability, thermal stability and hardness with increasing Bi2O3 content on the expense of CdO, and that the effect of irradiation with gamma doses is very small.展开更多
This work deals with the application of [MERCSF-N] computer program in calculating the macroscopic effective removal cross-section of fast neutrons, ΣR (cm-1), for two different boro phosphate glass systems: (0.5 - x...This work deals with the application of [MERCSF-N] computer program in calculating the macroscopic effective removal cross-section of fast neutrons, ΣR (cm-1), for two different boro phosphate glass systems: (0.5 - x) CdO-x Fe2O3-0.4 P2O5-0.1 B2O3 and (0.5 - x) B2O3-x Fe2O3-0.1 CdO-0.4 P2O5 (with 0.05 ≤ x ≤ 0.5 by mole), to realize from the role of iron in the attenuation process and hence the usefulness of the glass containing iron as neutrons shielding material. The effect of replacing cadmium and boron oxides by iron oxide has been analyzed which proved that iron is more efficient than cadmium in attenuating and removing fast neutrons and that the presence of small amounts of B2O3 at least 0.1 mole fraction, with iron is needed to aid improving the removal cross-section of iron phosphate glasses. Experimental IR results are developed and used to trace the structural change and confirm the role of iron in the removal cross section.展开更多
文摘The glass system xBi2O3-(30 – x)CdO-10B2O3-20Fe2O3-40P2O5 (0 ≤ x ≤ 30 weight %), has been prepared by the melt quenching technique. The thermal stability of the glasses, their hardness as well as their chemical durability have been investigated before and after subjecting to different gamma ray doses to insure the validity of this glass system for application to the problem of the permanent disposal for nuclear wastes. The results indicated that the glasses have well to excellent chemical durability, thermal stability and hardness with increasing Bi2O3 content on the expense of CdO, and that the effect of irradiation with gamma doses is very small.
文摘This work deals with the application of [MERCSF-N] computer program in calculating the macroscopic effective removal cross-section of fast neutrons, ΣR (cm-1), for two different boro phosphate glass systems: (0.5 - x) CdO-x Fe2O3-0.4 P2O5-0.1 B2O3 and (0.5 - x) B2O3-x Fe2O3-0.1 CdO-0.4 P2O5 (with 0.05 ≤ x ≤ 0.5 by mole), to realize from the role of iron in the attenuation process and hence the usefulness of the glass containing iron as neutrons shielding material. The effect of replacing cadmium and boron oxides by iron oxide has been analyzed which proved that iron is more efficient than cadmium in attenuating and removing fast neutrons and that the presence of small amounts of B2O3 at least 0.1 mole fraction, with iron is needed to aid improving the removal cross-section of iron phosphate glasses. Experimental IR results are developed and used to trace the structural change and confirm the role of iron in the removal cross section.
