A good Ti-based joint implant should prevent stress shielding and achieve good bioactivity and anti-infection performance.To meet these requirements,the low-elastic-modulus alloy—Ti–35Nb–2Ta–3Zr—was used as the s...A good Ti-based joint implant should prevent stress shielding and achieve good bioactivity and anti-infection performance.To meet these requirements,the low-elastic-modulus alloy—Ti–35Nb–2Ta–3Zr—was used as the substrate,and functional coatings that contained bioceramics and Ag ions were prepared for coating on TiO_(2)nanotubes(diameter:(80±20)nm and(150±40)nm)using anodization,deposition,and spin-coating methods.The effects of the bioceramics(nano-β-tricalcium phosphate,microhydroxyapatite(micro-HA),and meso-CaSiO_(3))and Ag nanoparticles(size:(50±20)nm)on the antibacterial activity and the tribocorrosion,corrosion,and early in vitro osteogenic behaviors of the nanotubes were investigated.The tribocorrosion and corrosion results showed that the wear rate and corrosive rate were highly dependent on the features of the nanotube surface.Micro-HA showed great wear resistance with a wear rate of(1.26±0.06)×10^(−3)mm^(3)/(N·m)due to adhesive and abrasivewear.Meso-CaSiO_(3)showed enhanced cell adhesion,proliferation,and alkaline phosphatase activity.The coatings that contained nano-Ag exhibited good antibacterial activity with an antibacterial rate of≥89.5%against Escherichia coli.These findings indicate that hybrid coatings may have the potential to accelerate osteogenesis.展开更多
首先介绍简单生物圈模式版本3(Simple Biosphere Model 3,SiB3)相比SiB2的改进之处以及相应的参数化方案。为了检验SiB3模式能否模拟不同下垫面的地气之间水分和能量交换,本文在全球选择3个代表高、中、低纬度的典型实验站点(青藏高原...首先介绍简单生物圈模式版本3(Simple Biosphere Model 3,SiB3)相比SiB2的改进之处以及相应的参数化方案。为了检验SiB3模式能否模拟不同下垫面的地气之间水分和能量交换,本文在全球选择3个代表高、中、低纬度的典型实验站点(青藏高原安多站点、亚马逊流域的Km34站点和美国中西部的WLEF站点),利用SiB3进行模拟分析和实验验证。研究结果表明,SiB3能够较好地模拟出不同下垫面的地表感热通量、潜热通量和净辐射通量随时间的变化率以及变化趋势,模式模拟值和测量值的相关系数达到0.80左右。但与实测相比,SiB3模拟的感热通量值仍偏高。在安多站点,模式模拟的地表土壤水分比较干燥,且模拟的地表温度较测量值偏高。展开更多
The tribological behavior of a Zr-based bulk metallic glass（BMG） was investigated using pin-on-disk sliding measurements in two different environments,i.e.,air and argon,against an yttria-stabilized zirconia counter...The tribological behavior of a Zr-based bulk metallic glass（BMG） was investigated using pin-on-disk sliding measurements in two different environments,i.e.,air and argon,against an yttria-stabilized zirconia counterface.It was found that the wear of the Zr-based BMG was reduced by more than 45% due to the removal of oxygen from the test environment at two different loads,i.e.,16 N and 23 N.The wear pins were examined using X-ray diffractometry,differential scanning calorimetry,scanning electron microscopy and optical surface profilometry.A number of abrasive particles and grooves presented on the worn surface of the pin tested in air,while a relatively smooth worn surface was observed in the specimens tested in argon.The wear mechanism of the pin worn in air was dominated by abrasive wear compared with an adhesive wear controlled process in the tests performed in argon.展开更多
The present study investigated the microstructure,nanomechanics,and corrosion behavior of AlCoCuFeNi high entropy alloys fabricated by selective laser melting(SLM)and laser metal deposition(LMD).The microstructure of ...The present study investigated the microstructure,nanomechanics,and corrosion behavior of AlCoCuFeNi high entropy alloys fabricated by selective laser melting(SLM)and laser metal deposition(LMD).The microstructure of SLM-processed specimens was mainly composed of columnar-grained BCC matrix(^90μm in width)and Cu-rich twinned FCC phase.The columnar grains grew epitaxially along the building direction and exhibited a strong{001}texture.In comparison,a coarse columnar-grained BCC matrix(^150μm in width)with a stronger<001>texture,rod-like B2 precipitates,and large core-shell structured FCC phases were formed in the LMD-processed specimens due to the higher heat accumulation effect.Consequently,the LMD-processed specimens showed a lower hardness,wear resistance,and corrosion resistance,but higher creep resistance and reduced Young's modulus than the SLM-processed specimens.Hot cracks occurred in both types of specimens,which could not be completely suppressed due to Cu segregation.展开更多
基金supported by the National Natural Science Foundation of China(Nos.52071346,52111530193,and 52274387)the Natural Science Foundation of Hunan Province for Distinguished Young Scholars(No.2023JJ10075)+3 种基金the Hunan Provincial Natural Science Foundation of China(No.2021JJ30846)the Central South University Research Program of Advanced Interdisciplinary Studies(No.2023QYJC038)the Funding for the Medical Engineering Cross Disciplinary Project at Shanghai Jiao Tong University,and the Fundamental Research Funds for the Central Universities of Central South University(No.2022ZZTS0402)The authors would also thank Sinoma Institute of Materials Research(Guangzhou)Co.,Ltd.for the assistance with the TEM characterization.
文摘A good Ti-based joint implant should prevent stress shielding and achieve good bioactivity and anti-infection performance.To meet these requirements,the low-elastic-modulus alloy—Ti–35Nb–2Ta–3Zr—was used as the substrate,and functional coatings that contained bioceramics and Ag ions were prepared for coating on TiO_(2)nanotubes(diameter:(80±20)nm and(150±40)nm)using anodization,deposition,and spin-coating methods.The effects of the bioceramics(nano-β-tricalcium phosphate,microhydroxyapatite(micro-HA),and meso-CaSiO_(3))and Ag nanoparticles(size:(50±20)nm)on the antibacterial activity and the tribocorrosion,corrosion,and early in vitro osteogenic behaviors of the nanotubes were investigated.The tribocorrosion and corrosion results showed that the wear rate and corrosive rate were highly dependent on the features of the nanotube surface.Micro-HA showed great wear resistance with a wear rate of(1.26±0.06)×10^(−3)mm^(3)/(N·m)due to adhesive and abrasivewear.Meso-CaSiO_(3)showed enhanced cell adhesion,proliferation,and alkaline phosphatase activity.The coatings that contained nano-Ag exhibited good antibacterial activity with an antibacterial rate of≥89.5%against Escherichia coli.These findings indicate that hybrid coatings may have the potential to accelerate osteogenesis.
文摘首先介绍简单生物圈模式版本3(Simple Biosphere Model 3,SiB3)相比SiB2的改进之处以及相应的参数化方案。为了检验SiB3模式能否模拟不同下垫面的地气之间水分和能量交换,本文在全球选择3个代表高、中、低纬度的典型实验站点(青藏高原安多站点、亚马逊流域的Km34站点和美国中西部的WLEF站点),利用SiB3进行模拟分析和实验验证。研究结果表明,SiB3能够较好地模拟出不同下垫面的地表感热通量、潜热通量和净辐射通量随时间的变化率以及变化趋势,模式模拟值和测量值的相关系数达到0.80左右。但与实测相比,SiB3模拟的感热通量值仍偏高。在安多站点,模式模拟的地表土壤水分比较干燥,且模拟的地表温度较测量值偏高。
基金Project(DE-FG02-07ER46392) supported by U.S.Department of Energy,Office of Basic Energy ScienceProject(2011JQ002) supported by the Fundamental Research Funds for the Central Universities,ChinaProject supported by the Open-End Fund for the Valuable and Precision Instruments of Central South University,China
文摘The tribological behavior of a Zr-based bulk metallic glass（BMG） was investigated using pin-on-disk sliding measurements in two different environments,i.e.,air and argon,against an yttria-stabilized zirconia counterface.It was found that the wear of the Zr-based BMG was reduced by more than 45% due to the removal of oxygen from the test environment at two different loads,i.e.,16 N and 23 N.The wear pins were examined using X-ray diffractometry,differential scanning calorimetry,scanning electron microscopy and optical surface profilometry.A number of abrasive particles and grooves presented on the worn surface of the pin tested in air,while a relatively smooth worn surface was observed in the specimens tested in argon.The wear mechanism of the pin worn in air was dominated by abrasive wear compared with an adhesive wear controlled process in the tests performed in argon.
基金financially supported by the National Natural Science Foundation of China(Nos.52111530193 and 52020105013)the Key Research and Development Program of Hunan Province(No.2022SK2006)+1 种基金the Fundamental Research Funds for the Central University of Central South University(No.2021ZZTS0098)the HK Research Grants Council(ECS 25202719 and GRF 15227121)。
文摘The present study investigated the microstructure,nanomechanics,and corrosion behavior of AlCoCuFeNi high entropy alloys fabricated by selective laser melting(SLM)and laser metal deposition(LMD).The microstructure of SLM-processed specimens was mainly composed of columnar-grained BCC matrix(^90μm in width)and Cu-rich twinned FCC phase.The columnar grains grew epitaxially along the building direction and exhibited a strong{001}texture.In comparison,a coarse columnar-grained BCC matrix(^150μm in width)with a stronger<001>texture,rod-like B2 precipitates,and large core-shell structured FCC phases were formed in the LMD-processed specimens due to the higher heat accumulation effect.Consequently,the LMD-processed specimens showed a lower hardness,wear resistance,and corrosion resistance,but higher creep resistance and reduced Young's modulus than the SLM-processed specimens.Hot cracks occurred in both types of specimens,which could not be completely suppressed due to Cu segregation.
