Mutual effects between a gliding arc discharge and a premixed flame

Mutual effects between a gliding arc(GA)discharge at atmospheric pressure and a premixed CH_(4)/air flame were experimentally investigated.Effects of the flame on the GA were studied using simultaneous measurements of the current,the voltage,and the instantaneous images of the plasma columns.The GA in the flame has a thicker and more diffusive plasma column,and it is more frequently ignited at a smaller breakdown voltage than that in the air.The GA extension velocity and the gliding velocity in the flame are larger than those in the air.The electrode voltage drop of the GA discharge in the flame is about 160 V,whereas that in the air is about 220 V.Compared with the GA in the air,the different features of the GA in the flame can be explained by high-temperature,weakly ionized,and species-abundant environment that are generated by the premixed CH_(4)/air flame.Effects of the gliding arc discharge on the premixed flames were demonstrated using planar laser-induced fluorescence of hydroxyl radicals(OH)and formaldehyde(CH_(2)O).OH and CH_(2)O can be formed in the CH_(4)/air mixture in the presence of the GA due to kinetic effects,and the increase of OH and CH_(2)O shows the great potential of the GA for combustion enhancement.

Separation of methyl linolenate and its analogues by functional mixture of imidazolium based ionic liquid-organic solvent-cuprous salt

Methyl linolenate was separated from its analogues by a new extraction system constructed by solvent,imidazolium based ionic liquids and cuprous salt. Firstly, the effect of ionic liquid on the dissolution of CuCl in acetonitrile, N,N-dimethylformamide(DMF), methanol and water was evaluated by visual observation.[C4Mim][Cl]can improve the dissolution of CuCl in acetonitrile. Then, for the new system as acetonitrile-ILs-CuCl, extraction equilibrium, distribution ratio and selectivity of methyl linolenate and its analogues were determined by gas chromatography analysis and the mass balance. The extraction time, IL structures and CuCl concentrations were investigated. Distribution ratio decreased slightly, but selectivity increased significantly with the addition of CuCl,[C4Mim][Cl] or [C4Vim][NTF2] into acetonitrile.[C4Vim][NTF2] had higher selectivity than [C4Mim][Cl].But the selectivity of the system combining CuCl with [C4Vim][NTF2] was much lower than with [C4 Mim][Cl].For the CuCl-[C4Mim][Cl]-acetonitrile, the extraction efficiency was better than CuCl-acetonitrile, increasing Cu^+ concentration effectively improved the separation selectivity when ratio of CuCl/[C4Mim][Cl] was less than 1. Compared with previous aqueous AgNO3 extractions, the method of using CuCl is a much cheaper and practical way to enrich unsaturated fatty acid.

Mechanism behind Time Dependent Elasticity of Crumb Rubber-Nano-Asphalt Hybrids Using Discrete Relaxation Spectrum

Crumb rubber powder is a successfully used renewable material obtained from waste tire rubber,which has been incorporated into paving asphalt since the 1930s due to its good resistance to deformation and fatigue as well as its eco-friendly performance.In this study,carbon nanotubes and nano silica were incorporated into the terminal blend crumb rubber modified asphalt technology to remedy the issues of excessive desulfurization and degradation of ground tyre rubber with this technology.The mechanism behind the high temperature delayed elastic properties of the crumb rubber-nano-asphalt hybrids was experimentally investigated based on discrete relaxation spectrum.Development of the discrete relaxation spectra was accomplished by fitting on the 60℃ storage modulus data tested by the dynamic shear rheometer using the generalized Maxwell model.Subsequently,the feasibility of characterizing delayed asphalt elasticity using main relaxation time was verified by test results from the 60℃ creep and recovery test.Results indicated that the crumb rubber-nano-asphalt hybrids exhibited arrheodictic behavior and the asphalt elasticity was strengthened by two nano agents.Moreover,the elasticity reinforcement with carbon nanotubes was greater than with nano silica.Additionally,a good correlation was observed between the 60℃ zero shear viscosity and main relaxation time,and greater 60℃ zero shear viscosity was correlated to longer main relaxation times.Furthermore,longer main relaxation time of the asphalt was related to greater average recovery rate in the creep and recovery test.This research is expected to shed some light on the mechanism behind time-dependent elasticity of crumb rubber modified asphalt from the perspective of polymer physics.

Spatiotemporal control of femtosecond laser filament-triggered discharge and its application in diagnosing gas flow fields

Precise control of the discharge in space and time is of great significance for better applications of discharge plasma.Here,we used a femtosecond laser filament to trigger and guide a highvoltage DC pulse discharge to achieve spatiotemporal control of the discharge plasma.In space,the discharge plasma is distributed strictly along the channel generated by the femtosecond laser filament.The breakdown voltage threshold is reduced,and the discharge length is extended.In time,the electrical parameters such as the electrode voltage and the electrode gap affect discharge delay time and jitter.By optimizing the parameters,we can achieve sub-nanosecond jitter of the discharge.Based on the spatiotemporal control of the discharge,we applied filamenttriggered discharge for one-dimensional composition measurements of the gas flow field.Besides,the technique shows great potential in studying the spatiotemporal evolution of discharge plasma.

MCGA-assisted ignition process and flame propagation of a scramjet at Mach 2.0

The ignition process and flame propagation with ethylene fuel in cavity-stabilized scramjet by a Multi-Channel Gliding Arc(MCGA)at Mach 2.0 were investigated.Effects of equivalence ratios on the MCGA-assisted ignition process and flame propagation of the scramjet were recorded by two high-speed cameras from different view angles.The discharge characteristics of MCGA are also collected synchronously with the high-speed cameras.The distributions of temperature,velocity,and equivalence ratios in non-reactive flows of the cavity were simulated by Reynolds Averaged Navier-Stokes(RANS)model.The results show that MCGA can achieve reliable ignition with the Global Equivalence Ratios(GER)between 0.06 and 0.17.The ignition process is composed of flame kernel generation,flame development,and stable combustion.The time from flame kernel generation to the establishment of global flame decreases as GER decreases from 0.17 to 0.08.In the streamwise direction,the flame first develops to the Cavity Leading Edge(CLE)because of the influence of the cavity recirculation zone and then uplifts into the cavity shear layer,and finally develops to the Cavity Trailing Edge(CTE).In the spanwise direction,the flame width is less than 50%of the width of the cavity before developing to CLE and begins to develop towards the two sides of the combustor after reaching CLE,which is affected by the angular recirculation zone on both sides of CLE.The ignition processes by MCGA in the scramjet combustor are significantly affected by local distributions of equivalence ratios and velocity in the cavity.

Scaling effects on combustion modes in a single-side expansion kerosene-fueled scramjet combustor

The combustion modes in two different scramjet combustors with the mass flow rates of 1.8 kg/s and 3.6 kg/s are experimentally investigated to explore the scaling effects on supersonic combustion with a Mach number 2.0 inflow.It is found that the scramjet combustor with a larger scale can broaden the flame rich blowout limit.As the Equivalence Ratio(ER)increases,the combustion in the small-scale combustor maintains in the cavity-stabilized mode,and the flamebase moves downstream along the cavity shear layer;however,the combustion in the large-scale combustor gradually transfers from the cavity-stabilized mode to the jet-wake-stabilized mode.The differences in the cavity residence time,the ignition delay time and the Damkohler number caused by different scales of the scramjet combustor are likely to account for the scaling effects on the combustion modes.