Effects of different iron sources on the performance of LiFePO_4/C composite cathode materials

Olivine LiFePO4/C composite cathode materials were synthesized by a solid state method in N2 ＋ 5vol% H2 atmosphere. The effects of different iron sources, including Fe（OH）3 and FeC2O4·2H2O, on the performance of as-synthesized cathode materials were investigated and the causes were also analyzed. The crystal structure, the morphology, and the electrochemical performance of the prepared samples were characterized by X-ray diffractometry （XRD）, scanning electron microscopy （SEM）, laser particle-size distribution measurement, and other electrochemical techniques. The results demonstrate that the LiFePO4/C materials obtained from Fe（OH）3 at 800℃ and FeC2O4·2H2O at 700℃ have the similar electrochemical performances. The initial discharge capacities of LiFePO4/C synthesized from Fe（OH）3 and FeC2O4·2H2O are 134.5 mAh.g^-1 and 137.4 mAh.g^-1 at the C/5 rate, respectively. How- ever, the tap density of the LiFePO4/C materials obtained from Fe（OH）3 are higher, which is significant for the improvement of the capacity of the battery.

Teleconnected Influence of the Boreal Winter Antarctic Oscillation on the Somali Jet： Bridging Role of Sea Surface Temperature in Southern High and Middle Latitudes

The teleconnection impact of the boreal winter Antarctic Oscillation（AAO） on the Somali Jet（SMJ） intensity in the following spring and summer is examined in this paper.The variability of the boreal winter AAO is positively related to the SMJ intensity in both spring and summer.The analyses show that the SST in southern high and middle latitudes seems to serve as a bridge linking these two systems.When the AAO is in strong positive phase,SST over the Southern Ocean cools in the high latitudes and warms in the middle latitudes,which persists into summer;however,the variability of SST in southern high and middle latitudes is also closely correlated to SMJ intensity.A possible mechanism that links SST variability with the AAO-SMJ relationship is also discussed.The AAO in boreal winter produces an SST anomaly pattern in southern high and middle latitudes through the air-sea coupling.This AAOrelated SST anomaly pattern modulates the local Ferrel cell anomaly in summer,followed by the regional Hadley cell anomaly in tropics.The anomalous vertical motion in tropics then changes the land-sea thermal contrast between the tropical Indian Ocean and the Asian continent through the variability of low cloud cover and downward surface longwave radiation flux.Finally,the land-sea thermal contrast anomaly between the tropical Indian Ocean and the Asian continent changes the SMJ intensity.The results from Community Atmosphere Model experiments forced by the SST anomaly in southern high and middle latitudes also confirm this diagnostic physical process to some extent.

Pharmacokinetics of gene recombined angiogenesis inhibitor Kringle 5 in vivo using 131I specific markers and SPECT/CT

The previous pharmacokinetic methods can be only limited to drug analysis in vitro, which provide less information on the distribution and metabolismof drugs, and limit the interpretation and assessment of pharmacokinetics, the determination of metabolic principles, and evaluation of treatment effect. The objective of the study was to investigate the pharmacokinetic characteristics of gene recombination angiogenesis inhibitor Kringle 5 in vivo. The SPECT/CT and specific^(131)I-Kringle 5 marked by Iodogen method were both applied to explore the pharmacokinetic characteristics of^(131)I-Kringle 5 in vivo, and to investigate the dynamic distributions of^(131)I-Kringle 5 in target organs. Labeling recombinant angiogenesis inhibitor Kringle 5 using131 I with longer half-life and imaging in vivo using SPECT instead of PET,could overcome the limitations of previous methods. When the doses of^(131)I-Kringle 5 were 10.0, 7.5 and5.0 g/kg, respectively, the two-compartment open models can be determined within all the metabolic process in vivo. There were no significant differences in t1/2α, t1/2β, apparent volume of distribution and CL between those three levels. The ratio of AUC(0 1)among three different groups of 10.0, 7.5 and 5.0 g/kg was 2.56:1.44:1.0, which was close to the ratio(2:1.5:1.0). It could be clear that in the range of 5.0–10.0 g/kg, Kringle 5 was characterized by the first-order pharmacokinetics. Approximately 30 min after^(131)I-Kringle 5 was injected,^(131)I-Kringle 5 could be observed to concentrate in the heart, kidneys, liver and other organs by means of planar imaging and tomography. After 1 h of being injected, more radionuclide retained in the bladder, but not in intestinal. It could be concluded that^(131)I-Kringle 5 is mainly excreted through the kidneys. About 2 h after the injection of^(131)I-Kringle 5, the radionuclide in the heart, kidneys,liver and other organs was gradually reduced, while more radionuclide was concentrated in the bladder.The radionuclide was completely metabolized within 24 h, and the distribution of radioactivity in rats was similar to normal levels. In our study, the specific marker^(131)I-Kringle 5 and SPECT/CT were successfully used to explore pharmacokinetic characteristics of Kringle 5 in rats. The study could provide a new evaluation platform of the specific, in vivo and real-time functional imaging and pharmacokinetics for the clinical application of^(131)I-Kringle 5.

Recent Progress of Electrospun Nanofbers for Zinc–Air Batteries

As a potential electrochemical energy storage device,zinc–air batteries(ZABs)received considerable interest in the feld of energy conversion and storage due to its high energy density and eco-friendliness.Nevertheless,the sluggish kinetics of the oxygen reduction and oxygen evolution reactions limit the commercial development of ZABs,so it is of great signifcance to develop efcient,low-cost and non-noble metal bifunctional catalysts.Electrospun one-dimensional nanofbers with unique properties such as high porosity and large surface area have great advantages on possessing more active sites,shortening the difusion pathways for ions/electrons,and improving the kinetics via intercalation/de-intercalation processes,which endow them with promising application in the feld of energy storage devices,especially ZABs.This review frstly introduces the electrospinning technique.Then,the oxygen reduction/evolution reaction triggered by electrospun nanofbers with selfsupported structures are presented,followed by the application of electrospun nanofbers for liquid and fexible solid-state ZABs.Finally,the remaining challenges and research directions of ZABs based on electrospun nanofbers electrocatalysts are briefy discussed.

Polar WRF V4.1.1.simulation and evaluation for the Antarctic and Southern Ocean

A recent version of the Polar Weather Research and Forecasting model(Polar WRF)has been upgraded to the version 4.X era with an improved NoahMP Land Surface Model(LSM).To assess the model performance over the Antarctic and Southern Ocean,downscaling simulations with different LSM(NoahMP,Noah),WRF versions(Polar WRF 4.1.1 and earlier version 4.0.3,WRF 4.1.1),and driving data(ERA-Interim,ERA5)are examined with two simulation modes:the short-term that consists of a series of 48 h segments initialized daily at 0000 UTC with the first 24 h selected for model spin-up,whereas the long-term component used to evaluate long-term prediction consists of a series of 38-41 day segments initialized using the first 10 days for spin-up of the hydrological cycle and planetary boundary layer structure.Simulations using short-term mode driven by ERA-Interim with NoahMP and Noah are selected for benchmark experiments.The results show that Polar WRF 4.1.1 has good skills over the Antarctic and Southern Ocean and better performance than earlier simulations.The reduced downward shortwave radiation bias released with WRF 4.1.1 performed well with PWRF411.Although NoahMP and Noah led to very similar conclusions,NoahMP is slightly better than Noah,particularly for the 2 m temperature and surface radiation because the minimum albedo is set at 0.8 over the ice sheet.Moreover,a suitable nudging setting plays an important role in long-term forecasts,such as reducing the surface temperature diurnal cycle near the coast.The characteristics investigated in this study provide a benchmark to improve the model and guidance for further application of Polar WRF in the Antarctic.