In recent years,local community detection algorithms have developed rapidly because of their nearly linear computing time and the convenience of obtaining the local information of real-world networks.However,there are...In recent years,local community detection algorithms have developed rapidly because of their nearly linear computing time and the convenience of obtaining the local information of real-world networks.However,there are still some issues that need to be further studied.First,there is no local community detection algorithm dedicated to detecting a seed-oriented local community,that is,the local community with the seed as the core.The second and third issues are that the quality of local communities detected by the previous local community detection algorithms are largely dependent on the position of the seed and predefined parameters,respectively.To solve the existing problems,we propose a seed-oriented local community detection algorithm,named SOLCD,that is based on influence spreading.First,we propose a novel measure of node influence named k-core centrality that is based on the k-core value of adjacent nodes.Second,we obtain the seed-oriented local community,which is composed of the may-members and the must-member chain of the seed,by detecting the influence scope of the seed.The may-members and the must-members of the seed are determined by judging the influence relationship between the node and the seed.Five state-of-art algorithms are compared to SOLCD on six real-world networks and three groups of artificial networks.The experimental results show that SOLCD can achieve a high-quality seed-oriented local community for various real-world networks and artificial networks with different parameters.In addition,when taking nodes with different influence as seeds,SOLCD can stably obtain high-quality seed-oriented local communities.展开更多
Nitrogenization is an effective method for improving the capacitive deionization(CDI)performance of porous carbon materials.In particular,polymer organic frameworks with heteroatom doping,containing an ordered pore st...Nitrogenization is an effective method for improving the capacitive deionization(CDI)performance of porous carbon materials.In particular,polymer organic frameworks with heteroatom doping,containing an ordered pore structure and excellent electrochemical stability,are ideal precursors for carbon materials for high-performance CDI.In this study,a nitrogen-enriched micro-mesoporous carbon(NMC)electrode was fabricated by carbonizing a Schiff base network-1 at 500,600,and 700℃.Scanning electron microscopy,Fourier transform infrared spectroscopy,X-ray diffraction,N_(2) adsorption-desorption,the contact angle of water,cyclic voltammetry,and electrochemical impedance spectroscopy were used to characterize the morphological structure,wettability,Brunauer–Emmett–Teller surface areas,and electrochemical performance of the NMCs.The results showed that the NMC carbonized at 600℃ achieved the best specific capacitance(152.33 F/g),as well as a high electrosorption capacity(25.53 mg/g)because of its chemical composition(15.57%N)and surface area(312 m^(2)/g).These findings prove that NMC is viable as an electrode material for desalination by high-performance CDI applications.展开更多
Ion-exchange polymer and modified carbonization bacterial cellulose(CBC)electrodes were fabricated using varying amounts of cation-exchange polymers(glutaric acid(GA)and sulfosuccinic acid(SSA))and assembled within an...Ion-exchange polymer and modified carbonization bacterial cellulose(CBC)electrodes were fabricated using varying amounts of cation-exchange polymers(glutaric acid(GA)and sulfosuccinic acid(SSA))and assembled within an asymmetric capacitive deionization unit(p-CDI).The performance of selective NO2-electro-adsorption was studied.The AC/CBCSSA group showed a better salt adsorption capacity(14.56 mg/g)and nitrite removal efficiency(71.01%)than the AC/CBC-GA(10.72 mg/g,47.83%)and AC/AC(4.81 mg/g,12.74%)groups.It was confirmed that the CBC-SSA/GA electrodes enhanced nitrite selectivity and increased the adsorption capacity,and the total amounts of adsorbed anions increased when the applied voltage was increased from 0.8 to 1.2 V,while the molar fraction of nitrate decreased.The competitive and preferential adsorption of anions was further investigated using different binary solutions of anions and occurred in the following sequence:NO2->SO42->NO3->F-≈Cl-.Furthermore,the p-CDI units were applied to remove nitrite in real wastewater samples,and the results showed that they had excellent reusability and application for use in dyeing wastewater treatment.展开更多
基金National Natural Science Foundation of China(Nos.61672179,61370083,61402126)Heilongjiang Province Natural Science Foundation of China(No.F2015030)+1 种基金Science Fund for Youths in Heilongjiang Province(No.QC2016083)Postdoctoral Fellowship in Heilongjiang Province(No.LBH-Z14071).
文摘In recent years,local community detection algorithms have developed rapidly because of their nearly linear computing time and the convenience of obtaining the local information of real-world networks.However,there are still some issues that need to be further studied.First,there is no local community detection algorithm dedicated to detecting a seed-oriented local community,that is,the local community with the seed as the core.The second and third issues are that the quality of local communities detected by the previous local community detection algorithms are largely dependent on the position of the seed and predefined parameters,respectively.To solve the existing problems,we propose a seed-oriented local community detection algorithm,named SOLCD,that is based on influence spreading.First,we propose a novel measure of node influence named k-core centrality that is based on the k-core value of adjacent nodes.Second,we obtain the seed-oriented local community,which is composed of the may-members and the must-member chain of the seed,by detecting the influence scope of the seed.The may-members and the must-members of the seed are determined by judging the influence relationship between the node and the seed.Five state-of-art algorithms are compared to SOLCD on six real-world networks and three groups of artificial networks.The experimental results show that SOLCD can achieve a high-quality seed-oriented local community for various real-world networks and artificial networks with different parameters.In addition,when taking nodes with different influence as seeds,SOLCD can stably obtain high-quality seed-oriented local communities.
基金supported by the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(No.2017BT01Z032)the National Natural Science Foundation of China(No.21577027)the 2017 Central Special Fund for Soil,Preliminary Study on Harmless Treatment and Comprehensive Utilization of Tailings in Dabao Mountain(No.18HK0108)。
文摘Nitrogenization is an effective method for improving the capacitive deionization(CDI)performance of porous carbon materials.In particular,polymer organic frameworks with heteroatom doping,containing an ordered pore structure and excellent electrochemical stability,are ideal precursors for carbon materials for high-performance CDI.In this study,a nitrogen-enriched micro-mesoporous carbon(NMC)electrode was fabricated by carbonizing a Schiff base network-1 at 500,600,and 700℃.Scanning electron microscopy,Fourier transform infrared spectroscopy,X-ray diffraction,N_(2) adsorption-desorption,the contact angle of water,cyclic voltammetry,and electrochemical impedance spectroscopy were used to characterize the morphological structure,wettability,Brunauer–Emmett–Teller surface areas,and electrochemical performance of the NMCs.The results showed that the NMC carbonized at 600℃ achieved the best specific capacitance(152.33 F/g),as well as a high electrosorption capacity(25.53 mg/g)because of its chemical composition(15.57%N)and surface area(312 m^(2)/g).These findings prove that NMC is viable as an electrode material for desalination by high-performance CDI applications.
基金supported by the Special Applied Technology Research and Development of Guangdong Province(major project)(No.2015B020235013)the National Natural Science Foundation of China(No.21577027)the 2017 Central Special Fund for Soil,Preliminary Study on HarmlessTreatment and Comprehensive Utilization of Tailings in Dabao Mountain(No.18HK0108)
文摘Ion-exchange polymer and modified carbonization bacterial cellulose(CBC)electrodes were fabricated using varying amounts of cation-exchange polymers(glutaric acid(GA)and sulfosuccinic acid(SSA))and assembled within an asymmetric capacitive deionization unit(p-CDI).The performance of selective NO2-electro-adsorption was studied.The AC/CBCSSA group showed a better salt adsorption capacity(14.56 mg/g)and nitrite removal efficiency(71.01%)than the AC/CBC-GA(10.72 mg/g,47.83%)and AC/AC(4.81 mg/g,12.74%)groups.It was confirmed that the CBC-SSA/GA electrodes enhanced nitrite selectivity and increased the adsorption capacity,and the total amounts of adsorbed anions increased when the applied voltage was increased from 0.8 to 1.2 V,while the molar fraction of nitrate decreased.The competitive and preferential adsorption of anions was further investigated using different binary solutions of anions and occurred in the following sequence:NO2->SO42->NO3->F-≈Cl-.Furthermore,the p-CDI units were applied to remove nitrite in real wastewater samples,and the results showed that they had excellent reusability and application for use in dyeing wastewater treatment.